The specific enthalpy of fracture due to ductile crack propagation in commercial polycarbonate sheet is calculated as * =A1c/R1c, whereA1c is the critical energy release rate associated with the onset of unstable crack propagation andR1c is the corresponding amount of damage (yielded material) formed per unit crack extension.A1c andR1c are determined from fatigue crack propagation experiments conducted at different maximum loads, load ratios and frequencies. The value of * obtained from all experiments is found to be 9.8±1.4 cal g–1 (1cal = 4.184 J) which indicates that * is a material constant. This finding substantiates predictions of the crack layer theory. 相似文献
The effectiveness of ammonium (NH4+) adsorption was investigated, using spray-dried, pH-treated bentonite, and kaolin as adsorbents. Each powder's adsorption capacity towards NH4+ was examined after up to 120 min of sample exposure, and results were compared. The zeta potential values for bentonite samples were between ?1.1 and ?19.4 mV, while for kaolin samples, they were between ?35.7 and ?40.9 mV (pH range examined was 2–10). The adsorption isotherm for bentonite showed a fit with the Langmuir model. The pH 10-treated bentonite and as-received bentonite (dispersed as pH 10 in distilled water) showed the highest adsorption capacity towards NH4+. Meanwhile, for kaolin, the adsorption capacity was low and observed only at low NH4+ concentration (100 mg/L and 200 mg/L), with pH 10-treated kaolin showed the highest adsorption capacity. 相似文献
This paper presents the engine performance and optimum injection timing for 4-cylinder direct injection hydrogen fueled engine. The 4-cylinder direct injection hydrogen engine model was developed utilizing the GT-Power commercial software. This model employed one dimensional gas dynamics to represent the flow and heat transfer in the components of engine model. Sequential pulse injectors are adopted to inject hydrogen gas fuel within the compression stroke. Injection timing was varied from 110° before top dead center (BTDC) until top dead center (TDC) timing. Engine speed was varied from 2000 rpm to 6000 rpm, while the equivalence ratio was varied from 0.2 to 1.0. The validation was performed with the existing previous experimental results. The negative effects of the interaction between ignition timing and injection duration was highlighted and clarified. The results showed that optimum injection timing and engine performance are related strongly to the air fuel ratio and engine speed. The acquired results show that the air fuel ratio and engine speed are strongly influence on the optimum injection timing and engine performance. It can be seen that the indicated efficiency increases with increases of AFR while decreases of engine speed. The power and torque increases with the decreases of AFR and engine speed. The indicated specific fuel consumption (ISFC) decreases with increases of AFR from rich conditions to lean while decreases of engine speed. The injection timing of 60° BTDC was the overall optimum injection timing with a compromise. 相似文献
Effect of heat generation and absorption on mixed convection flows in a sinusoidal heated lid-driven square cavity filled with a porous medium is investigated numerically. Both the vertical walls of the enclosure are insulated while the bottom wall is uniformly heated or cooled. The top wall is moving at a constant speed and is heated sinusoidally. The governing equations and boundary conditions are non-dimensionalized and solved numerically by using finite volume method approach along with SIMPLE algorithm together with non-uniform grid system. The effect of Darcy and heat generation parameters are investigated in terms of the flow, heat transfer, and Nusselt number. The results for stream function and isotherm are plotted and it is found that there have significant influence with the presence of heat generation and porous medium.
The feasibility of using palm oil fractions as cheap and abundant sources of raw material for the synthesis of amino acid surfactants was investigated. Of a number of enzymes screened, the best results were obtained with the immobilized enzyme, Lipozyme. The effects of temperature, solvent, incubation period, fatty substrate/amino acid molar ratio, enzyme amount, and water removal on the reactions were analyzed and compared to those on reactions with free fatty acids and pure triglycerides as fatty substrates. All reactions were most efficient when carried out at high temperatures (70-80 degrees C) in hexane as a solvent. However, while reactions with free fatty acids proceeded better when a slight excess of the free fatty acids over the amino acids was used, reactions with triglycerides and palm oil fractions were best performed at equimolar ratios. Also, the addition of molecular sieves slightly enhanced reactions with free fatty acids but adversely affected reactions with triglycerides and palm oil fractions. Although reactions with palm oil fractions took longer (6 d) to reach equilibrium compared to reactions with free fatty acids (4 d) and pure triglycerides (4 d), better yields were obtained. Such lipase-catalyzed transacylation of palm oil fractions with amino acids is potentially useful in the production of mixed medium- to long-chain surfactants for specific applications. 相似文献
The ability of Leuconostoc mesenteroides DU15 to produce antifungal peptides that inhibit growth of Aspergillus niger was evaluated under optimum growth conditions of 30 °C for 48 h. The cell‐free supernatant showed inhibitory activity against A. niger. Five novel peptides were isolated with the sequences GPFPL, YVPLF, LLHGVPLP, GPFPLEMTLGPT, and TVYPFPGPL as identified by de novo sequencing using PEAKS 6 software. Peptide LLHGVPLP was the only positively charged (cationic peptides) and peptide GPFPLEMTLGPT negatively charged (anionic), whereas the rest are neutral. The identified peptides had high hydrophobicity ratio and low molecular weights with amino acids sequences ranging from 5 to 12 residues. The mode of action of these peptides is observed under the scanning electron microscope and is due to cell lysis of fungi. This work reveals the potential of peptides from L. mesenteroides DU15 as natural antifungal preservatives in inhibiting the growth of A. niger that is implicated to the spoilage during storage. 相似文献