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41.
Material properties and operating configurations of membrane reactors for propane dehydrogenation 下载免费PDF全文
Seung‐Won Choi Christopher W. Jones Sankar Nair David S. Sholl Jason S. Moore Yujun Liu Ravindra S. Dixit John G. Pendergast 《American Institute of Chemical Engineers》2015,61(3):922-935
A modeling‐based approach is presented to understand physically realistic and technologically interesting material properties and operating configurations of packed‐bed membrane reactors (PBMRs) for propane dehydrogenation (PDH). PBMRs composed of microporous or mesoporous membranes combined with a PDH catalyst are considered. The influence of reaction and membrane transport parameters, as well as operating parameters such as sweep flow and catalyst placement, are investigated to determine desired “operating windows” for isothermal and nonisothermal operation. Higher Damköhler (Da) and lower Péclet (Pe) numbers are generally helpful, but are much more beneficial with highly H2‐selective membranes rather than higher‐flux, lower‐selectivity membranes. H2‐selective membranes show a plateau region of conversion that can be overcome by a large sweep flow or countercurrent operation. The latter shows a complex trade‐off between kinetics and permeation, and is effective only in a limited window. H2‐selective PBMRs will greatly benefit from the fabrication of thin (~1 µm or less) membranes. © 2014 American Institute of Chemical Engineers AIChE J, 61: 922–935, 2015 相似文献
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K. N. Remani E. Nirmala S. R. Nair 《The International journal of environmental studies》2013,70(4):285-295
One of the striking features of Kerala state is the continuous chain of lagoons or backwaters existing along the coastal region. The backwaters support rich and diverse life forms and provide crucial nurseries for shrimps and fishes as well as habitat for oysters, clams and mussels which later enrich the ocean and make Kerala the principal exporter of marine products amongst the states of India. The shallow fringes of the backwaters and the channels drawn from them are used for retting of coconut husk. It adversely affects the productivity of the backwaters and is harmful to marine fisheries. The retting of coconut husks in backwaters is brought about by the pectinolytic activity of micro organisms especially bacteria fungi and yeasts degrading the fibre binding materials of the husk and liberating large quantities of organic matter and chemicals into the environment, including pectin, pentosan, tannins, polyphenols, etc. Consequently hydrogen sulphide, phosphate and nitrate contents increase while dissolved oxygen and community diversity of plankton decrease in the ambient waters during the retting process. The present study is to evaluate pollution due to coir retting activity and its influence on quality of water and estuarine flora and fauna. 相似文献
44.
Cassava starch‐graft‐polymethacrylamide copolymers as flocculants and textile sizing agents 下载免费PDF全文
Cassava starch‐graft‐polymethacrylamide (PMAM) copolymers were synthesized by a free‐radical‐initiated polymerization reaction, and the products were tested for their efficiency as flocculants and textile sizing agents. The highest percentages of grafting and monomer conversion were 79.9 and 78.0%, respectively. The grafted starches were characterized by Fourier transform infrared spectroscopy, X‐ray diffraction analysis, scanning electron microscopy, differential scanning calorimetry, and thermogravimetric analysis. The average molecular weight of PMAM chains in the grafted starches ranged from 15.9 to 30.8 × 105 g/mol. The grafted starches exhibited a higher peak viscosity and paste stability in comparison to the native starch (NS). Dynamic mechanical analysis showed that grafting provided fairly shear‐stable hydrogels, and the highest storage modulus obtained was 17,900 Pa compared to 1879 Pa for NS. The flocculation studies demonstrated the superiority of starch‐g‐PMAM over cassava starch and PMAM as an efficient flocculant. The tensile strength of cotton yarns sized with the starch‐grafted copolymer was significantly higher (104 MPa) compared to that sized with NS (34 MPa). © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 39810. 相似文献
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The effect of phenol end functional shape memory oligomers on the shape memory properties of an epoxy‐cyanate ester resin system was examined. The basic resin system consisted of diglycidyl ether of bisphenol A (DGEBA) cured with bisphenol A dicyanate (BADC). For conferring the shape memory properties, the switching segment (SS) components selected are α, ω‐phenol‐terminated poly(tetramethyleneoxide) (PPTMO), poly(ε‐caprolactone) (PPCL), and poly(propylene glycol) (PPPG). Epoxy‐cyanate ester blend of defined composition was analyzed for thermal, mechanical, thermo‐mechanical, and shape memory properties at two concentrations of the three SSs. The transition temperature of heavily SS loaded matrix increased in the order: PPTMO < PPCL < PPPG commensurate with crystallizability of SS segments at ambient. For same reason flexural property showed an increasing trend. This is in league with the increased crystallizability of the shape memory polymer components. The shape fixity, recovery extent, and recovery time followed a reverse order: PPPG < PPCL < PPTMO. In contrast to the alcohol terminated shape memory components, phenol terminal groups were helpful in integrating the shape memory segments into the matrix by way of reaction with both epoxy and cyanate groups. The coreaction was conducive for achieving better shape memory properties and decreasing the transition temperature. A direct relation existed between the modulus ratio and the shape recovery property. Higher concentration of the SSs caused a diminution in transition temperature but enhanced the shape memory properties, though the mechanical properties were adversely affected. The shape recovery increased with increase in temperature. All polymers possessed good mechanical properties and thermal stability. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41196. 相似文献
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Pranab Dey Kinsuk Naskar Golok B. Nando Biswaranjan Dash Sujith Nair G. Unnikrishnan 《应用聚合物科学杂志》2014,131(23)
Thermoplastic vulcanizates (TPVs), which are a special class of elastomer alloy, prepared by dynamic vulcanization possess unique morphology of finely dispersed micron‐size cross‐linked elastomeric particles in a continuous thermoplastic matrix. The present study investigates the microstructure formation of elastomeric phase and its associated morphological changes during reprocessing of TPVs based on poly[styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene] triblock co‐polymer (S‐EB‐S) and solution polymerized styrene butadiene elastomer (S‐SBR) by scanning electron microscopy and atomic force microscopy. Semi‐efficient and efficient sulfur‐based curing systems have been adopted to cure the elastomeric phase and a comparative study has been made to demonstrate and explain the effect of reprocessing on the melt rheology and dynamic viscoelasticity of the TPVs. The present work also provides a better insight and guidance to control the microstructure of the cross‐linked elastomeric phase to prepare selectively co‐continuous or dispersed phase morphology. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41182. 相似文献
47.
The formation of polymer networks polymerized with the Copper (I) – catalyzed azide – alkyne cycloaddition (CuAAC) click reaction is described along with their accompanying utilization as shape memory polymers. Due to the click nature of the reaction and the synthetic accessibility of azide and alkyne functional-monomers, the polymer architecture was readily controlled through monomer design to manipulate crosslink density, ability for further functionalization, and the glass transition temperature (55–114 °C). Free strain recovery is used to quantify the shape memory properties of a model CuAAC network resulting in excellent shape fixity and recovery of 99%. The step growth nature of this polymerization results in homogenous network formation with narrow glass transitions ranges having half widths of the transition close to 15 °C for these materials resulting in shape recovery sharpness of 3.9%/°C in a model system comparable to similarly crosslinked chain growth polymers. Utilization of the CuAAC reaction to form shape memory materials opens a range of possibilities and behaviors that are not readily achieved in other shape memory materials such as (meth) acrylates, thiol-ene, thiol-Michael, and poly(caprolactone) based shape memory materials. 相似文献
48.
The nature and extent of the modification of starch in quinoa, caused by various processes like cooking and autoclaving of the seeds, drum drying of the flour and extrusion of the grits was investigated by measuring the physico-chemical properties - the water absorption, water solubility, swelling power, viscosity and degree of gelatinisation - of the processed samples. Autoclaved samples showed the lowest degree of gelatinisation (32.5% by DSC) of the starch, while the degree of gelatinisation of the precooked/drum dried samples was found to be 97.4% by DSC method. Higher polymer degradation was observed in cooked samples than in autoclaved samples as seen in the gel chromatographic separation. The water solubility in cooked samples (5.44 to 15.58) and in autoclaved samples (7.02 to 9.64) increased with the process time. In the extrusion process, the moisture content as well as the compression ratio was found to affect the degree of starch modification significantly (p <0.01). 相似文献
49.
Mukil V. Ayyasamy Jeroen A. Deijkers Haydn N.G. Wadley Prasanna V. Balachandran 《Journal of the American Ceramic Society》2020,103(8):4489-4497
Density functional theory (DFT) calculations and machine learning (ML) methods are used to establish a relationship between the crystal structures of rare-earth (RE) disilicates (RE2Si2O7) and their coefficient of thermal expansion (CTE). The DFT total energy data predict the presence of several energetically competing crystal structures, which is rationalized as one of the reasons for observing polymorphism. An ensemble of support vector regression models is trained to rapidly predict the CTE as a function of RE2Si2O7 crystal chemistry. Experiments subsequently validated the structure and CTE predictions for Sm2Si2O7. 相似文献
50.
Sathi Rajachandran Nair Ram Dayal Purohit Avesh Kumar Tyagi Pankaj Kumar Sinha Beant Prakash Sharma 《Journal of the American Ceramic Society》2008,91(1):88-91
Ultrafine La(Ca)CrO3 (LCC) powder was prepared through the glycine–nitrate gel combustion process. It was shown for the first time that the use of relatively inexpensive CrO3 as a starting material for chromium has potential for the bulk preparation of sinter-active LCC powder. As-prepared powder, when calcined at 700°C, resulted in LCC along with a small amount of CaCrO4 . The calcined powder was found to be composed of soft agglomerates with a particle size of ≈70–290 nm. The cold pressing and sintering of the calcined powder at 1200°C resulted in the mono-phasic La0.7 Ca0.3 CrO3 with density ≈98% of its theoretical value. This is the lowest sintering temperature ever reported for La0.7 Ca0.3 CrO3 . The conductivity of the sintered La0.7 Ca0.3 CrO3 at 1000°C was found to be ≈57 S/cm in air. The sintering and electrical behavior achieved for La0.7 Ca0.3 CrO3 may find application as an interconnect material for high-temperature solid oxide fuel cells if problems with chemical expansion and poor conductivity in fuel can be overcome. 相似文献