A Composite Formation Route to Well‐Crystalline Manganese Oxide Nanocrystals: High Catalytic Activity of Manganate–Alumina Nanocomposites

Manganese oxide nanocrystals are combined with aluminum oxide nanocrystals to improve their crystallinity via calcination without a significant increase of crystal size. A nanocomposite, consisting of two metal oxides, can be synthesized by the reaction between permanganate anions and aluminum oxyhydroxide keggin cations. The as‐prepared manganese oxide–aluminum oxide nanocomposite is X‐ray amorphous whereas heat‐treatment gives rise to the crystallization of an α‐MnO₂ phase at 600 °C and Mn₃O₄/Mn₂O₃ and γ‐Al₂O₃ phases at 800 °C. Electron microscopy and N₂ adsorption‐desorption‐isotherm analysis clearly demonstrate that the as‐prepared nanocomposite is composed of a porous assembly of monodisperse primary particles with a size of ～20 nm and a surface area of >410 m² g^?1. Of particular interest is that the small particle size of the as‐prepared nanocomposite is well‐maintained up to 600 °C, a result of the prevention of the growth of manganate grains through nanoscale mixing with alumina grains. The calcined nanocomposite shows very‐high catalytic activity for the oxidation of cyclohexene with an extremely high conversion efficiency of >95% within 15 min. The present results show that the improvement of the crystallinity without significant crystal growth is very crucial for optimizing the catalytic activity of manganese oxide nanocrystals.     

6σ管理在炼钢质量管理中的实践与应用

介绍了6σ管理的特征、DMAIC改进模式,6σ管理在莱钢炼钢厂钢水成分、氧含量等质量控制中的应用及取得的效果。     

孙村煤矿矿井废弃物处理及综合利用

为降低孙村煤矿开采对环境的污染,充分利用地热,采用水源热泵机组取代传统的燃煤锅炉,满足了冬季立井井口、生产车间和办公室的采暖要求;矿井废水经净水器、石英砂过滤器、活性炭过滤器、反渗透设备处理后,矿井水质达到国家Ⅰ类饮水标准;采用仰斜似膏体充填开采技术,将水泥、粉煤灰、煤矸石加水配制成质量分数72%～75%的胶结充填料浆,在采场进行充填,整个充填系统的充填能力达到100～120m3/h,提高了煤炭资源采出率,减少了地面矸石山。以上措施不仅显著改善了地面环境,而且实现了能源的再利用。     

认真履行安全保障义务自觉承担企业社会责任

<正>1企业肩负的社会责任企业社会责任,是指企业在创造社会财富的同时,要承担的维护、实现和发展社会及相关者利益的责任。2010年3月5日,温家宝总理在第十一届人大第三次会议上作政府工作报告时强调:我们所做的一     

不同浓度的LAS的多角度偏振反射光谱研究

本文以十二烷基苯磺酸钠(SDBS)作为主要实验样品,利用偏振二向性反射光度计探究不同浓度的直链烷基苯磺酸盐(LAS)的偏振反射光谱特性与探测方位角、光线入射天顶角、探测天顶角、偏振角、波段间的关系,并与一种家用洗衣粉及蒸馏水的偏振反射光谱曲线作比较．结果表明,LAS溶液的浓度、观测时的几何条件和波段是影响LAS溶液偏振反射光谱特性的主要因子,而且不同LAS浓度间的偏振反射光谱特性会随着观测时的几何条件与波段的变化而出现明显差异,这为偏振遥感在环境上的应用奠定了实验基础．     

中间段光折变晶体材料参数的测量原理

提出了中间段光折变晶体材料参数的测量原理。利用公开报道的关于Ce:KNSBN双光束耦合的实验数据计算了该晶体的材料参数。实验与理论结果相吻合。     

同步CDMA系统带后端自适应的线性去相关多用户检测算法

本文提出了一种在后端附加自适应的线性去相关多用户检测算法,详细分析了该算法的性能并进行了仿真。分析与仿真结果均表明,这种算法既具有优良的抗远近效应能力又具有较低的误码率     

An efficient solver for the three-dimensional capacitance of theinterconnects in high speed digital circuit by the multiresolutionmethod of moments

The computation of the equivalent capacitances for three-dimensional (3-D) interconnects features large memory usage and long computing time. In this paper, a matrix sparsification approach based on multiresolution representation is applied with the method of moments (MoM) to calculate 3-D capacitances of interconnects in a layered media. Instead of direct expansion of the charge distribution by the orthogonal wavelet basis functions, the large full matrix resulting from discretization of the integral equations is taken as a discrete image and sparsified by two-dimensional (2-D) multiresolution representations. The inverse of the obtained sparse matrix is efficiently implemented by Schultz's iterative approach. Several numerical examples are given and the results obtained show that the proposed method significantly sparsifies the matrix equation and the capacitance parameters computed by the matrix equation with high sparsity agree well with the results of other reports and those computed by an established capacitance extractor FASTCAP     

一种采用NSPUDT结构的新型滤波器

利用自然单相单向换能器,可以制作低损耗的声表面波器件。因自然单相单向换能器基片的单向性依赖于晶体的取向,用常规的单指结构就可以获得单向性。为了得到低损耗的滤波器,在相对方向上的接受换能器也设计成单向传输。文中介绍了一种使自然单相单向换能器基片单向性反向传输的新型滤波器结构,并给出采用这种结构设计制作 的声表面波滤波器的结果。     

Perovskite‐Induced Ultrasensitive and Highly Stable Humidity Sensor Systems Prepared by Aerosol Deposition at Room Temperature

A new capacitive‐type humidity sensor is proposed using novel materials and fabrication process for practical applications in sensitive environments and cost‐effective functional devices that require ultrasensing performances. Metal halide perovskites (CsPbBr₃ and CsPb₂Br₅) combined with diverse ceramics (Al₂O₃, TiO₂, and BaTiO₃) are selected as sensing materials for the first time, and nanocomposite powders are deposited by aerosol deposition (AD) process. A state‐of‐the‐art CsPb₂Br₅/BaTiO₃ nanocomposite humidity sensor prepared by AD process exhibits a significant increase in humidity sensing compared with CsPbBr₃/Al₂O₃ and CsPbBr₃/TiO₂ sensors. An outstanding humidity sensitivity (21426 pF RH%^?1) with superior linearity (0.991), fast response/recovery time (5 s), low hysteresis of 1.7%, and excellent stability in a wide range of relative humidity is obtained owing to a highly porous structure, effective charge separation, and water‐resistant characteristics of CsPb₂Br₅. Notably, this unprecedented result is obtained via a simple one‐step AD process within a few minutes at room temperature without any auxiliary treatment. The synergetic combination of AD technique and perovskite‐based nanocomposite can be potentially applied toward the development of multifunctional sensing devices.