Adapting maize production to climate change in sub-Saharan Africa

Given the accumulating evidence of climate change in sub-Saharan Africa, there is an urgent need to develop more climate resilient maize systems. Adaptation strategies to climate change in maize systems in sub-Saharan Africa are likely to include improved germplasm with tolerance to drought and heat stress and improved management practices. Adapting maize systems to future climates requires the ability to accurately predict future climate scenarios in order to determine agricultural responses to climate change and set priorities for adaptation strategies. Here we review the projected climate change scenarios for Africa’s maize growing regions using the outputs of 19 global climate models. By 2050, air temperatures are expected to increase throughout maize mega- environments within sub-Saharan Africa by an average of 2.1°C. Rainfall changes during the maize growing season varied with location. Given the time lag between the development of improved cultivars until the seed is in the hands of farmers and adoption of new management practices, there is an urgent need to prioritise research strategies on climate change resilient germplasm development to offset the predicted yield declines.     

Electrochemical characterization of Cu dissolution and chemical mechanical polishing in ammonium hydroxide–hydrogen peroxide based slurries

Chemical mechanical polishing (CMP) of copper in ammonium hydroxide based slurry in the presence of hydrogen peroxide was investigated. The polishing trend was found to be similar to that exhibited by other slurries containing hydrogen peroxide and various complexing agents used for Cu CMP. When the hydrogen peroxide concentration is increased, the polish rate increases, reaches a maximum and then decreases. The location and the magnitude of the maximum depend on the ammonium hydroxide concentration. The dissolution of copper in the NH₄OH–hydrogen peroxide solution was probed by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) experiments. Electrical equivalent circuit (EEC) and reaction mechanism analysis (RMA) were employed to determine the mechanistic reaction pathway of Cu dissolution in NH₄OH–hydrogen peroxide system. Based on the RMA analysis, a four step catalytic mechanism with two adsorbed intermediate species is proposed.     

Developmental Outcome of Drug-Exposed Children Through 30 Months: A Comparison of Bayley and Bayley-II.

This study examined the effects of the Bayley Scales of Infant Development (BSID) version on developmental outcomes among drug-exposed children, some of whom received an intervention. Developmental outcome was evaluated with the BSID at 12 and 18 months and with the BSID-II at 24 and 30 months. In the repeated measures analyses, children scored higher on the BSID Mental Developmental Index (MDI; p     

Polyelectrolyte screening effects on the dissolution of whey protein gels at high pH conditions

The literature reports an optimum NaOH concentration for the alkaline cleaning of whey deposits or gels; at NaOH concentrations higher than this optimum, cleaning proceeds much more slowly. Although this phenomenon is of great importance in the cleaning of dairy equipment, no conclusive physical explanation has yet been presented. In this study, we present strong evidence that the dissolution rate is affected by the equilibrium-swelling ratio in β-lactoglobulin (βLg) gels. The swelling ratio is greatly reduced in the presence of salts due to the polyelectrolyte screening effect of the cations. This has been observed in free-swelling βLg gels using gravimetrical analysis and in the uniaxial swelling of WPC gel deposits using fluid dynamic gauging. At high dissolution pH (>13.3), the high Na⁺ concentration reduces swelling in spite of the high surface charge of the protein. It is proposed that the reduction of the free volume inside the gel impedes the transport of the protein aggregates out of the NaOH penetration zone. We have also observed that the final dissolution rate of gels pre-soaked in 1 M NaOH or NaCl is similar, despite the difference in pH, and much lower than for untreated gels: the high Na⁺ concentration in the soaked gels hinders swelling, inhibiting the disentanglement of the protein clusters regardless of the high pH.     

Diagnosis of Wireless Sensor Networks in Presence of Permanent and Intermittent Faults

In this paper we consider the problem of distributed fault diagnosis in Wireless Sensor Networks (WSNs). The proposed Fault Diagnosis Algorithm (FDA) aims to handle both permanent and intermittent faults. The sensor nodes with permanent communication faults can be diagnosed by using the conventional time-out mechanism. In contrast, it is difficult to detect intermittent faults due to their inherent unpredictable behavior. The FDA is based on the comparison of sensor measurements and residual energy values of neighboring sensor nodes, exploiting their spatial correlations. To handle intermittent faults, the comparisons are made for \(r\) rounds. Two special cases of intermittent faults are considered: one, when an intermittently faulty node sends similar sensor measurement and similar residual energy value to some of its neighbors in all \(r\) rounds; another, when it sends these values, either or both of which deviates significantly from that of some neighbors in all \(r\) rounds. Through extensive simulation and analysis, the proposed scheme is proved to be correct, complete, and efficient to handle intermittent faults and hence, well suited for WSNs.     

Visibility of dichalcogenide nanolayers

Dichalcogenides with the common formula MX(2) are layered materials with electrical properties that range from semiconducting to superconducting. Here, we describe optimal imaging conditions for the optical detection of ultrathin, two-dimensional dichalcogenide nanocrystals containing single, double and triple layers of MoS(2), WSe(2) and NbSe(2). A simple optical model is used to calculate the contrast for nanolayers deposited on wafers with varying thicknesses of SiO(2). The model is extended for imaging using the green channel of a video camera. Using AFM and optical imaging we confirm that single layers of MoS(2) and WSe(2) can be detected on 90 and 270 nm SiO(2) using optical means. By measuring contrast under broadband green illumination we are also able to distinguish between nanostructures containing single, double and triple layers of MoS(2) and WSe(2.) We observe and discuss discrepancies in the case of NbSe(2).     

Fracture toughness of foams with tetrakaidecahedral unit cells using finite element based micromechanics

Fracture toughness of open-cell foams consisting of tetrakaidecahedral unit cells is predicted by simulating crack propagation using a finite element (FE) based micromechanical model. The inputs to the model are the geometric parameters required to model the repeating unit cell and tensile strength of the foam ligament or strut. Cracks are created by removing certain number of cells pertaining to a crack length. The FE model consists of a local micro-scale region surrounding the crack tip. For an assumed stress intensity factor, the displacements along the boundary of the local model are calculated based on linear elastic fracture mechanics for orthotropic materials. The stresses in the ligaments ahead of the crack tip calculated from this micro-model in conjunction with the tensile strength of the strut material are used to predict fracture toughness. A parametric study with different micro-model sizes and different crack lengths is performed to check for convergence of predicted Mode-I, Mode-II and mixed mode fracture toughness values. The effect of applying rotations as additional boundary conditions along with translational displacement boundary conditions on the predicted fracture toughness values is also studied.     

Optimization of cooling load for a lecture theatre in a composite climate in India

A lecture theatre with dimension 16 m × 8.4 m × 3.6 m located at Roorkee (28.58°N, 77.20°E) in the northern region of India, is selected to calculate the monthly and annual cooling load (kWh) and cooling capacity of air conditioning system by a computer simulation. The paper also presents the results of a study investigating the effect of different glazing systems on windows and the reduction in building cooling load. DesignBuilder software has been used for the computer simulation for calculating the cooling load. The paper aims to investigate the reduction in thermal gains and cooling load requirements by varying the U-values of different glazing types, insulating the ceiling, providing cool roofs, interior and exterior insulation on walls, and replacing the conventional fluorescent tube lamp (FTL) by energy efficient compact fluorescent lamp (CFL). Installation of false ceiling, wall insulation, different glazing types and lighting systems are cost effective with normalized annual saving ranging from 17% to 19.8% from this retrofitting project. Furthermore, the study also highlights the potential of reducing the emission of CO₂ and equivalent carbon credit. Retrofitting techniques strongly influence the level of energy saving, although the payback period is generally quite long of order 8 years.