IEA joint trials: New lessons from old plantations

Two international trials of potential biomass species families and clones planted in 1985 have been analyzed to determine changing patterns in growth, diseases, and insects. In the Swedish trial, with close spacing and short rotations, Salix viminalis clones gave the best average yield of 17.4 Mg/Ha/yr on the first coppice rotation. In the Minnesota, USA trial, with wider spacings and a longer rotation Populus alba hybrid clones gave the best average yields of 5.5 Mg/Ha/yr. The most important disease and insect problems encountered were Septoria musiva stem cankers on some Populus clones; frost die back in some Salix clones; and the leaf blotch miner, Fenusa dohrnii, on most Alnus families. Recommendations for future international cooperation in field trials are presented.     

A storage heat pump using an ‘ozone-friendly’ refrigerant

The paper describes the integration of a chemical and a vapour-compression heat pump for energy storage applications. The vapour-compression system is designed to operate using the UK cheap rate ‘Economy 7’ electricity tariff. The system is characterized thermodynamically using various refrigerant/absorbent pairs in the chemical storage circuit and an ozone-friendly refrigerant, R134a, in the vapour-compression circuit. Results indicate that the H₂O/Na₂S pair provides a high energy storage density and is the most suitable for use in this system. The paper also describes the design features of a domestic-sized version of this heat pump system. Air in the sunspace (conservatory) of a house was used as a heat source for the heat pump.     

A method to estimate local deposition conditions using film profiles in features

A method to estimate the local partial pressures and temperature during low pressure chemical vapor deposition (LPCVD) proceses using film profile data is demonstrated using the chemistry of blanket tungsten deposition by the hydrogen reduction of tungsten hexafluoride. EVREST, the computer program which performs the estimates, uses EVOLVE, a physically based process simulator for ballistic transport and heterogeneous reactions in features on patterned wafers, to compute film profiles for a given set of deposition conditions. In order to validate the estimation method and to demonstrate EVREST, test calculations are performed using film profiles generated by EVOLVE instead of experimental scanning electron microscopy cross-sections. Calculated films profiles are compared with the generated film profiles (the data) and the simulated deposition conditions are adjusted using an algorithm based on Marquardt's method to minimize the sum of squared differences between points on the calculated and generated profiles. Test calculations confirm that film profiles in more than one feature can be used to improve the reliability of the partial pressure and temperature estimates.     

Investigation of solar selective and microstructural properties of molybdenum black immersion coatings on cobalt substrates

Molybdenum black solar selective coatings have been produced on cobalt by immersion in a solution of ammonium paramolybdate and nickel sulphate. The cobalt was electroplated on nickel-plated copper prior to immersion in the paramolybdate solution. The maximum solar absorptance of the resulting molybdenum black coating was about 0.91. The minimum emittance was about 0.1 for coatings on cobalt deposited with an addition agent and about 0.23 for coatings on cobalt deposited without addition agent in the 60 °C plating solution. These differences have been related to the coating morphology determined by scanning electron microscopy. The emittance of coatings on cobalt deposited without addition agent decreases (or remains unchanged) during short-term heat treatment while that of coatings deposited on cobalt plated with addition agent increases somewhat. Reduction of the cobalt plating bath temperature to 45 °C can also lead to good initial coating properties but without the requirement for an addition agent in the cobalt plating bath. XPS studies show that the oxidation state of molybdenum in the coatings is approximately + 5 corresponding to Mo₄O₁₁. This reduces to + 4 after argon ion bombardment. Some cobalt may be present in the coatings in the form of CoO.     

Pressure indicators for measurements in wind tunnels

The results of an investigation of new materials sensitive to air pressure in a given pressure range are reported. Examples of their application to wind tunnels are given.Central Aero-Hydrodynamics Institute, Moscow. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 63, No. 2, pp. 183–187, August, 1992.     

Use of inverse gas chromatography to quantify interactions in amine cured epoxy resins

Flory–Huggins interaction parameters, λ, were determined for a series of probes in an amine cured epoxy resin matrix (433–493 K) and its precursors (324–363 K) by inverse gas chromatography (IGC). Hildebrand–Scatchard theory was combined with Flory–Huggins theory in order to estimate infinte dilution solubility parameters (δ₂) for the matrix and its precursors at 298 K. It was shown that the value of the solubility parameter for the cured resin matrix lies between those of its precursors. Compared to the majority of published work, an unusual aspect of this application of IGC is that solubility parameters have been determined when the stationery phases are (i) small molecules and (ii) a highly crosslinked polymer. Moreover, all possible attempts have been made to ensure equilibrium conditions between probe and stationary phase, and compensation for asymmetry of peak profile has been applied in determining δ₂. The solubility parameters estimated by IGC are in good agreement with those calculated by other methods.     

Analysis of electromagnetic forces in a levitated short rotor LIM.II. Lateral stabilization

For pt.I see ibid., vol.17, no.1, p.95-101 (2002). This paper proposes a method for lateral stabilization of the levitated linear induction motor and also gives the analysis for calculating the stabilizing force in detail. The calculated force has been experimentally verified using the laboratory prototype described previously     

UTD multiple-edge transition zone diffraction

The uniform theory of diffraction (UTD) is applied to multiple absorbing screens, which are in the transition zones near shadow boundaries. The theory includes the application of slope diffraction, which is a first-order effect in transition zone diffraction. By choosing length parameters independently for amplitude and slope diffraction, it is ensured that the solution has continuity of amplitude and slope at each point. The solution is compared with known solutions with good results except when two screens are very near each other. The study is of particular interest to radio propagation over terrain in mobile radio systems