VO2 nanostructures based chemiresistors for low power energy consumption hydrogen sensing

Mott-type VO₂ oxide nanobelts are demonstrated to be effective hydrogen gas sensors at room temperature. These nanobelts, synthesized by hydrothermal process and exhibiting the VO₂ (A) crystallographic phase, display room temperature H₂ sensitivity as low as 0.17 ppm. The nanobelts (ultralong belt-like) nanostructures could be an ideal system for fully understanding dimensionally confined transport phenomena in functional oxides and for building functional devices based on individual nanobelts.     

Analysis of electrical and thermal responses of n-doped silicon to an impinging electron beam and joule heating

A detailed numerical simulation for electron-beam heating of n-doped silicon is presented. Electron-beam penetration is modeled using electron-beam transport equation (EBTE). The EBTE is solved by using a Monte Carlo (MC) method to determine the electron deposition distributions, including electron density deposition and optical phonon generation. Electron and phonon temperatures of the film are then determined using electron–phonon hydrodynamic equations (EPHDEs) coupled with the deposition distributions obtained from the MC simulation. The combined EBTE and EPHDEs results indicate that an electron beam creates a depletion region near the surface of incidence and causes non-equilibrium between electron and phonon temperatures.     

Difference equation matrix model (DEMM) for the control of wind turbines

In this paper, a new algorithm, difference equation matrix model (DEMM), in the framework of model predictive control (MPC) is introduced. Instead of the standard dynamic matrix control (DMC), which is based upon step response method that has been used in most research works, we propose a new approach based upon a DEMM for model prediction. It has shown that DEMM has proven to be less computational and thus faster than the original DMC for real time applications. Thus, the drawbacks of DMC for online identification or adaptive design could be avoided. The control of wind turbines is carried out in order to decrease the cost of wind energy by increasing the efficiency, and thus the energy capture, or by reducing structural loading and increasing the lifetimes of the components and turbine structures. Modeling of wind turbine has been carried out. Effect of noise and disturbance on the system has been also studied. The results obtained show that the proposed DEMM minimizes the effect of the disturbance and produces an accurate and smooth control. Significant improvements in the regulation of rotor speed at high wind speeds are obtained from the proposed DEMM, where control set points are obtained ahead of the disturbance, saving the turbine of the negative effects of them and thus increasing its lifetime. Copyright © 2012 John Wiley & Sons, Ltd.     

Parasitic noise on the output of a CW YAG:Nd+3laser

An experimental investigation was conducted to reduce the parasitic noise appearing on the output of a 6-W CW YAG:Nd⁺³laser. Initially, low-frequency fluctuations as high as 30 percent and relaxation oscillation bursts exceeding 80 percent of the CW power level were present. Low-frequency modulation was reduced by the addition of an active feedback loop to control lamp current. Relaxation oscillations were determined to be influenced by laser rod cooling, pump-lamp aging, vibration, and intracavity optical interface quality. At the conclusion of the program, low-power fluctuations and relaxation oscillation excursions did not exceed 2 percent.     

Cost and Land Functions for Wastewater Treatment Projects: Typical Simple Linear Regression versus Fuzzy Linear Regression

This paper analyzes cost data pertinent to the municipal wastewater treatment plants (MWTP) in Greece. First, data have been collected with onsite visits and contain the land size necessary for a MWTP, the construction cost, and the operation and maintenance cost of existing wastewater treatment facilities. Second, they come from analytical budgeting of natural wastewater treatment system units. Twelve equations of the form ln?Yi = A0i+A1i?ln?Xi are estimated both with ordinary least squares (OLS) and fuzzy linear regression (FLR). The root mean square error and the mean absolute error are used as fitting measures for the comparison of the OLS with the fuzzy estimations. It is shown that the FLR did produce very similar estimates but slightly inferior to those of OLS in most of the cases for these particular datasets.     

Aerosol characteristics over Delhi national capital region: a satellite view

Multi-sensor aerosol data sets are analysed to examine the aerosol characteristics over the Delhi national capital region. Both the Multiple-angle Imaging Spectroradiometer (MISR) and Moderate Resolution Imaging Spectroradiometer (MODIS) capture the seasonal cycle of aerosol optical depth (AOD) as observed by ground-based measurements. However, AOD from MISR shows a low bias relative to AOD from MODIS, which increases linearly at high AOD conditions. A large difference (by >25 W m^–2 per unit AOD) in the top-of-atmosphere direct radiative forcing efficiency derived from MODIS and MISR-retrieved AOD is observed during the winter and pre-monsoon seasons relative to the other seasons. The ubiquitous presence of dust (as indicated by non-spherical particle fraction to AOD and linear depolarization ratio values) is observed throughout the year. The aerosol layer is mostly confined to within 2 km of surface in the winter and post-monsoon seasons, while it expands beyond 6 km in the pre-monsoon and monsoon seasons. Columnar AOD is found to be highly sensitive to aerosol vertical distribution. The applicability of multi-sensor data sets and climatic implications are discussed.     

An Intrinsically Fluorescent Recognition Ligand Scaffold Based on Chaperonin Protein and Semiconductor Quantum‐Dot Conjugates

Genetic engineering of a novel protein–nanoparticle hybrid system with great potential for biosensing applications and for patterning of various types of nanoparticles is described. The hybrid system is based on a genetically modified chaperonin protein from the hyperthermophilic archaeon Sulfolobus shibatae. This chaperonin is an 18‐subunit double ring, which self‐assembles in the presence of Mg ions and ATP. Described here is a mutant chaperonin (His‐β‐loopless, HBLL) with increased access to the central cavity and His‐tags on each subunit extending into the central cavity. This mutant binds water‐soluble semiconductor quantum dots, creating a protein‐encapsulated fluorescent nanoparticle. The new bioconjugate has high affinity, in the order of strong antibody–antigen interactions, a one‐to‐one protein–nanoparticle stoichiometry, and high stability. By adding selective binding sites to the solvent‐exposed regions of the chaperonin, this protein–nanoparticle bioconjugate becomes a sensor for specific targets.     

Mode of action of a minor xylanase from Thermoascus aurantiacus on polysaccharides and model substrates

The mode of action of a minor xylanase on a variety of polysaccharides and model substrates was investigated. The enzyme was excreted by Thermoascus aurantiacus grown in solid state fermentation (SSF). The purified enzyme had a molecular mass of 33,000. Thin layer chromatography analysis showed that the endoxylanase liberated short fragments from polysaccharides. The enzyme hydrolysed aryl-β- -cellobioside and the chromogenic (fluorogenic) 4-methylumbelliferyl-β-glycosides of xylobiose (MeUmbXyl₂) and xylotriose (MeUmbXyl₃) at the agluconic linkage. The results suggested that the endoxylanase belonged to family 10.     

Providing and verifying advanced IP services in hierarchical DiffServ networks‐the case of GEANT

The differentiated services (DiffServ) framework is widely proposed as an efficient method for providing advanced IP services to large‐scale networks, with QoS requirements. However, the provisioning of such services in production networks has proved to be more difficult than initially expected, in defining, setting and verifying appropriate Service Level Agreements (SLAs). GEANT, the Gigabit core pan‐European research network, on a pilot basis introduced ‘Premium IP’ service, offering bounded delay and negligible packet loss to the European National Research & Education Networks (NRENs) that it interconnects. However, large scale provisioning of this new service requires the definition of efficient interaction procedures between administrative domains involved and methods for SLA monitoring. This paper focuses on these issues and presents the experience acquired from the early experiments in GEANT, as an example of hierarchical Gigabit multi‐domain environment, enabled with QoS provisioning to its constituent NRENs. This model scales more efficiently than the common peering Internet Service provider (ISP) commercial paradigm. Finally, we outline other options that promise QoS, such as Layer 2 VPNs in MPLS backbones, with non‐standard (yet) mechanisms. Copyright © 2004 John Wiley & Sons, Ltd.     

Molecular structure and charge distribution in organometallics of the 4f and 5f elements V: crystal and molecular structure of tetrakis(ν-cyclopentadienyl)-thorium(IV) and the temperature dependence of its electrical dipole moment

The crystal and molecular structure of Th(C₅H₅)₄, was investigated by single crystal X-ray diffraction. The compound crystallizes tetragonal with a = 868.3(1), C = 1064.4(3) pm with two molecules per unit cell. The average Th—Cp distance of 260.6 pm is in good agreement with the predicted distance of 258.8 pm, and is larger than the corresponding distance of the uranium compound (253.8 pm). The temperature dependence of the dipole moment of the title compound, of thorium tetramethylcyclopentadienide (Cp′,Th), and of the homologous uranium compound in benzene solution is discussed with respect to their molecular structure.