Stability of black carrot anthocyanins in various fruit juices and nectars

Fruit juices (apple, grape, orange, grapefruit, tangerine and lemon) and nectars (apricot, peach and pineapple) were coloured with black carrot juice concentrate and stability of black carrot anthocyanins in these matrices was studied during heating at 70–90 °C and storage at 4–37 °C. Anthocyanin degradation, in all coloured juices and nectars, followed first-order reaction kinetics. During heating, black carrot anthocyanins in apple and grape juices showed higher stability than those in citrus juices at 70 and 80 °C. High stability was also obtained for the anthocyanins in peach and apricot nectars at these temperatures. Black carrot anthocyanins were the least stable in orange juice during both heating and storage. During storage, degradation of anthocyanins was very fast at 37 °C, especially in pineapple nectar. Refrigerated storage (4 °C) markedly increased the stability in all samples. Activation energies for the degradation of black carrot anthocyanins in coloured juices and nectars ranged from 42.1 to 75.8 kJ mol⁻¹ at 70–90 °C and 65.9–94.7 kJ mol⁻¹ at 4–37 °C.     

The Annealing Effects in the Iron-Based Superconductor FeTe0.8Se0.2 Prepared by the Self-Flux Method

FeTe_0.8Se_0.2 single crystals as-cast and post-annealed were prepared by the self-flux method. We have investigated the structural properties of samples by using the XRD, scanning electron microscope (SEM), energy dispersive X-ray (EDX), and magnetic techniques. The SEM results clearly demonstrate that Te ions are quite well substituted for Se ions in the FeSe lattice for the samples. From the XRD and EDX spectra of the both samples, it has been concluded that the post-annealing causes no change in the tetragonal structure of FeTe_0.8Se_0.2. According to M–H measurements, the perfect diamagnetism has been observed only in low field at 5 and 10 K temperatures. The trend of the magnetization versus temperature curves, measured under a magnetic field of 10 Oe, also support our conclusion about diamagnetic contribution in FeTe_0.8Se_0.2 single crystal explored in this study. The as-cast and post-annealed samples show the onset of diamagnetism at temperatures, \(T_{\mathrm {c.on}}^{\text {mag}}\) , 12.45 and 13.27 K, respectively. In addition, those curves indicate that the high field value and some impurities reveal ferromagnetic interactions.     

Effect of (Ta/Nb) co-doping on the magnetoresistivity and flux pinning energy of the BPSCCO superconductors

In the present work, the effect of co-doping of Ta and Nb with nominal composition of (BiPb)₂Ta_xSr₂Ca₃Cu_4?yNb_yO_12+δ where x = 0.1 and y = 0.0, 0.025, 0.05, 0.075, and 0.1 were investigated. The samples were prepared by using the well-known conventional standard solid-state reaction method. The magnetoresistance measurements were studied for different values of the applied magnetic field. The activation energies, irreversibility fields (H _irr ), upper critical fields (H _c2 ) and coherence lengths at 0 K (ζ(0)) were calculated from the resistivity versus temperature (ρ-T) curves, under DC magnetic fields up to 6 T. The thermally activated flux flow (TAFF) model has been applied in order to calculate the flux pinning energies. The results have shown that the upper critical magnetic field, H _c2 (0), and the flux pinning energies vary from ~113 to 74 T and ~384 to 101 meV at 0 T, with the Nb-content, respectively.     

Thermal Stabilities of Peroxidases from Fresh Pinto Beans

Heat stabilities of crude and partially purified soluble (SPOX), ionically bound (IPOX) and total peroxidase (TPOX) from fresh pinto beans were investigated at 55–90°C. Heat inactivation of peroxidase (POX) followed first-order reaction kinetics. Each inactivation curve consisted of two linear parts: initial rapid inactivation (heat-labile) followed by slower inactivation (heat-stable). IPOX showed activation during heat treatment with a highly heat-stable isoenzyme (D₉₀=40 min) which was more heat-stable than SPOX. Activation energies for heat-stable parts of crude IPOX and SPOX were, respectively, 12.1 and 36.4 kcalmol-1 with z values 45.4 and 14.1C°. Heat stable SPOX isoenzymes (D₇₀=22.6) were obtained by 65–95% (NH₄)₂SO₄ precipitation from crude SPOX. Two POX fractions (F1 and F2) were separated from TPOX by ion-exchange chromatography.     

A spin wave resonance study on reentrant Au77Fe23 films

Thin films prepared by both flash and slow evaporation of the bulk Au₇₇Fe₂₃ alloy have been studied by electron spin resonance (ESR) technique at the temperature range between 77–300 K. A series of spin wave resonance (SWR) peaks were observed at all temperatures when the external de magnetic field is applied along the directions lying in a small angular interval with respect to the film normal. The classical spin wave model has been used to analyze the experimental data. The magnetic parameters, such as exchange stiffness constant, the effective bulk and the surface anisotropy energy parameters of the system have been derived as a function of temperature. While the easy plane surface anisotropy almost remains constant, considerable increments were found in the exchange parameter, the magnetization and the linewidth with decreasing temperature. The SWR linewidths for the films obtained by slow evaporation at higher substrate temperatures are noticeably smaller compared to those of the film prepared by flash evaporation technique.     

Zu Grundproblemen der räumlichen Getriebelehre und der Lösungsweg

Zusammenfassung Die Invarianten einer Regelfl?che, die durch die Raumbewegung einer Geraden entsteht, werden mit Hilfe der anschaulichen kinematischen Methoden hergeleitet. Die Zusammenh?nge zwischen diesen Invarianten der Rast- und Gangaxoide werden aufgezeigt. Die Anwendung der genannten Invarianten führen dann zur L?sung von drei Grundaufgaben der r?umlichen Getriebelehre.     

Properties of autoclaved lightweight aggregate concrete

Many researches have been carried out on production and properties of pre-cast concretes. Currently, most of them have focused on normal concrete, and are unable to completely represent the behavior of lightweight concrete (LWC). In this study, physical and mechanical properties of LWC produced with diatomite and pumice lightweight aggregates after autoclave curing were investigated. In the production of LWC, 0–4 mm maximum sizes of aggregates were used. Cement content and water/cement ratio were kept at 300 kg/m³ and 0.20, respectively. The specimens were prepared in 50×100 mm cylindrical shape, and after 24 h of demoulding exposed to autoclave curing for 2, 4, 6, 8 and 10 h. Besides, two different cures were applied on the specimens as in water and in air at 20 °C±2, respectively. At the end of autoclaving and environmental cure, compressive strength in 7, 28 and 590 d, unit weight, specific porosity, thermal conductivity and water absorption were tested. Also, microstructures of LWC produced with diatomite and pumice aggregate were investigated. As a result, it is concluded that by autoclaving of specimens in 8–10 h, especially, compressive strength of specimens have increased 75% of strength of 28 aged specimens cured in water.     

Design and development of a self-microemulsifying drug delivery system of olmesartan medoxomil for enhanced bioavailability

Olmesartan medoxomil (OM) is a hydrophobic antihypertensive drug with low bioavailability (26%) and is known to have adverse effects such as celiac disease and enteropathy. The purpose of this study was to develop SMEDDS to increase bioavailability and decrease potential side effects of OM. Hydrophilic lipophilic balance was calculated by testing solubility of OM in different oils, surfactants, and cosurfactants to obtain the most suitable combination of SMEDDS. Pseudoternary phase diagram was used to select the better oil/water formulation of SMEDDS. After a test for 3-month stability, dissolution tests and parallel artificial membrane permeability assay (PAMPA) were conducted to investigate drug solubility and permeability. Biodistribution of fluorescent marked SMEDDS was observed by using in vivo imaging system. The pharmacodynamics of the drug were determined by measuring blood pressure from tails of rats. At the end of the experiment, intestines were examined for adverse effects of OM. Compared with tablet formulation according to the dissolution study, SMEDDS formulation showed 1.67 times improvement in solubility of OM. PAMPA studies suggested a much faster permeability rate for OM SMEDDS compared to the suspension form. Labeled SMEDDS gave 3.96 times stronger fluorescent emission than control dye administered mice in in vivo imaging system (IVIS^®) studies, indicating an increased bioavailability. Treating effect of SMEDDS was 3.1 times more efficient compared to suspension in hypertensive rats. It caused neither celiac-like enteropathy nor diarrhea, during 21-day noninvasive blood pressure system (NIBP) assay. Our results suggest that SMEEDS formulation improves dissolution and oral bioavailability of OM while reducing its adverse effects.     

Laser Cutting of Holes in Inconel 803 Alloy and Analysis of Thermal Stress Field

Laser circular cutting of Inconel 803 alloy is carried out. Temperature and stress fields are predicted in the cutting section using ABAQUS finite element code mimicking the experimental conditions. To examine the influence of the hole diameter size on the thermal stress field developed in the cutting section, 2?mm and 10?mm hole diameters are considered in the experiments and analysis. Temperature predictions are validated through the thermocouple data. Morphological and elemental changes in the cutting section are examined incorporating the analytical tools. It is found that laser cut holes are free from large size asperities such as cracks and excessive sideways burnings. However, few small dross attachments are observed at the kerf exit for the small diameter (2?mm) hole. The maximum temperature is higher for small diameter hole than that of the large diameter hole (10?mm) prior to cutting ceases, which is attributed to heat transfer rates from kerf site to its neighborhood. von Mises stress remains low in the region where temperature remains high in the cooling period. This is associated with the elastic modulus of the substrate material, which reduces with increasing temperature. von Mises stress becomes almost same for small and large diameter holes after the cooling period ends and it is in the order of 0.45?GPa.     

Solar Cells with Enhanced Photocurrent Efficiencies Using Oligoaniline‐Crosslinked Au/CdS Nanoparticles Arrays on Electrodes

Different configurations of CdS nanoparticles (NPs) are linked to Au electrodes by electropolymerization of thioaniline‐functionalized CdS NPs onto thioaniline‐functionalized Au‐electrodes. In one configuration, thioaniline‐functionalized CdS NPs are electropolymerized in the presence of thioanline‐modified Au NPs to yield an oligoaniline‐crosslinked CdS/Au NPs array. The NP‐functionalized electrode generates a photocurrent with a quantum yield that corresponds to ca. 9%. The photocurrent intensities are controlled by the potential applied on the electrode, and the redox‐state of the oligoaniline bridge. In the oxidized quinoide state of the oligoaniline units, the bridges act as electron acceptors that trap the conduction‐band electrons that are transported to the electrode and lead to high quantum yield photocurrents. The reduced π‐donor oligoaniline bridges act as π‐donor sites that associate N,N′‐dimethyl‐4,4′‐bipyridinium, MV²⁺, by donor/acceptor interactions, K_a = 5270 M^?1. The associated MV²⁺ acts as an effective trap of the conduction‐band electrons, and in the presence of triethanolamine (TEOA) as an electron donor, high photocurrent values are measured (ca. 12% quantum yield). The electropolymerization of thioaniline‐functionalized Au NPs and thioaniline‐modified CdS NPs in the presence of MV²⁺ yields a MV²⁺‐imprinted NP array. The imprinted array exhibits enhanced affinities toward the association of MV²⁺ to the oligoaniline π‐donor sites, K_a = 2.29 × 10⁴ M^?1. This results in the effective trapping of the conduction‐band electrons and an enhanced quantum yield of the photocurrent, ca. 34%. The sacrificial electron donor, TEOA, was substituted with the reversible donor I₃^?. A solar cell consisting of the imprinted CdS/Au NPs array, with MV²⁺ and I₃^?, was constructed. The cell generated a photocurrent with a quantum yield of 4.7%.