Gelatin as a promising printable feedstock for microbial fuel cells (MFC)

The microbial fuel cell (MFC) is an energy transducer that can directly produce electricity from bacterial oxidation of organic matter. MFCs consist of two reaction chambers (anode and cathode) separated by a semipermeable membrane. This study describes the work carried out towards the optimization of critical MFC components, with 3D fabricated materials. The response of the optimized fuel cells, which were fed with soft materials such as gelatin, alginate and Nafion?, is also reported. The optimised components were the membrane and the cathode electrode. A conventional Nafion membrane was substituted with a custom made terracotta sheet and the electrode used was a single sheet of carbon veil coated with an activated carbon paste. The results showed that among the soft materials tested within the anodic chamber, gelatin performed the best; it also revealed that even after a 10-day starvation period gelatin demonstrated better longevity. These results show that MFCs have the potential to be 3D-printed monolithically using the EVOBOT platform.     

Hydrogen adsorption characteristics of magnesium combustion derived graphene at 77 and 293 K

Bulk graphene was prepared by the method of magnesium combustion in a CO₂ atmosphere, producing large quantities of material which had a different morphology and importantly, a more ordered carbon lattice than reduced graphene oxide and other bulk graphene synthetic methodologies. Despite a low surface area of 235.5 m²/g and ca 9 at.% of magnesium and its oxides which do not contribute to hydrogen adsorption, we observe 0.85 wt.% of H₂ at 65 bar and 77 K, and 0.9 wt.% of H₂ at 300 bar and 293 K. As this methodology readily produces many-gram quantities with cheap starting materials, we anticipate that with further enhancements to the synthetic methodology, improving both surface area and reducing reaction by-products, this material will provide a robust platform for further H₂ adsorption investigations.     

Hydrophilic monolith with ethylene glycol-based grafts prepared via surface confined thiol-ene click photoaddition

Macroporous polymeric monolith bearing thiol-reactive surface functionalities was prepared within micrometer-sized fused silica capillary column by photochemically-driven free radical copolymerization of N-acryloxysuccininimide and ethylene dimethacrylate in the presence of toluene as porogenic solvent, hereafter poly(NAS-co-EDMA), and subsequent surface grafting of allylamine through nucleophilic substitution reaction. The pore surface with pendant allyl moieties was further functionalized via a two-step thiol-ene click reaction with thiol-containing oligo(ethylene glycol) and mercaptoethanol, successively. The surface hydration ability, i.e. hydrophilic character, of the as-obtained monolith was evaluated as a function of the water-content of the liquid fluid environment through electrochromatographic evaluation of the retention properties of the -(O-CH₂-CH₂)-like surface-functionalized capillary monolith. A major result was that the so called hydrophilic interaction electrochromatographic mode was observed at a given mobile phase composition. An example is given for the separation of phenol-derivatives, with the most hydrophilic one being the most retained. In addition, the hydrophilic interaction based separation allowed for reduced analysis time as compared to the separation observed under reversed-phase separation mode using analogous monolithic stationary phase. Finally, the versatility of the thiol-ene photoaddition approach is demonstrated with an example of C18-like monolith for reversed-phase separation application.     

Pathways to posttraumatic growth: The contributions of forgiveness and importance of religion and spirituality.

Posttraumatic growth may follow the experience of being significantly hurt by another person. This study examines the roles of forgiveness and the importance of religion and spirituality in posttraumatic growth after a significant interpersonal transgression among a diverse sample of 146 adults. Results demonstrated that transgression severity was negatively related to forgiveness: the more distressing the event, the more revenge and avoidance were endorsed in response to the offender. Regression analyses revealed that benevolence toward the offender predicted growth in the area of relating to others. The positive relationship between forgiveness and posttraumatic growth was mediated by importance of religion and spirituality; however, the relationship between unforgiveness and lack of growth was not similarly mediated. Results suggest that religious and spiritual variables influence how individuals respond to significant interpersonal transgressions through positive processes. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Discrimination of vegetation strata in a multi-layered Mediterranean forest ecosystem using height and intensity information derived from airborne laser scanning

Height and intensity information derived from Airborne Laser Scanning (ALS) was used to obtain a quantitative vertical stratification of vegetation in a multi-layered Mediterranean ecosystem. A new methodology for the separation of different vegetation strata was implemented using supervised classification of a two-dimensional feature space spanned by ALS return height (terrain corrected) and intensity. The classification was carried out using Gaussian mixture models tuned on a control plot. The approach was validated using extensive field measurements from treated plots, ranging from single vegetation strata to a more complex multi-layered ecosystem. Plot-level canopy profiles derived from ALS and from a geometric reconstruction based on field measurements were in very good agreement, with correlation coefficients ranging from 0.73 (for complex, 3-layered) to 0.96 (simple, single-layered). In addition, it was possible to derive plot-level information on layer height, vertical extent and coverage with absolute accuracies of some decimetres (simple plots) to a meter (complex plots) for both height and vertical extent and about 10 to 15% for layer coverage. The approach was then used to derive maps of the layer height, vertical extent and percentage of ground cover for a larger area, and classification accuracy was evaluated on a per-pixel basis. The method performed best for single-layered plots or dominant layers on multi-layered plots, obtaining an overall accuracy of 80 to 90%. For subdominant layers in the more complex plots, accuracies obtained were as low as 48%.Our results demonstrate the possibility of deriving qualitative (presence and absence of specific vegetation layers) and quantitative, physical data (height, vertical extent and ground cover) describing the vertical structure of complex multi-layered forest ecosystems using ALS-based height and intensity information.     

Exploring the hypothetical limits to a nuclear and renewable electricity future

This article evaluates whether the world can transition to a future global electricity system powered entirely by nuclear power plants, wind turbines, solar panels, geothermal facilities, hydroelectric stations, and biomass generators by 2030. It begins by explaining the scenario method employed for predicting future electricity generation, drawn mostly from tools used by the International Energy Agency. The article projects that the world would need to build about 7744 Gigawatts (GW) of installed electricity capacity by 2030 to provide 37.2 thousand terawatt‐hours (TWh). Synthesizing data from the primary literature, the article argues that meeting such a projection with nuclear and renewable power stations will be difficult. If constructed using commercially available and state‐of‐the‐art nuclear and renewable power stations today, the capital cost would exceed $40 trillion, anticipated negative externalities would exceed $1 trillion per year, and immense strain would be placed on land, water, material, and human resources. Even if nuclear and renewable power technologies were much improved, trillions of dollars of investment would still be needed, millions of hectares of land set aside, quadrillions of gallons of water used, and material supplies of aluminum, concrete, silicon, and steel heavily utilized or exhausted. Because of these constraints, the only true path towards a more sustainable electricity system appears to be reducing demand for electricity and consuming less of it. Copyright © 2009 John Wiley & Sons, Ltd.     

Integrative factory, technology, and product planning-systemizing the information transfer on the operational level

These days, competitive advantages for manufacturing companies cannot be achieved through a detached configuration of specific processes but only through an integrative configuration of the factory as a complete system. The technologies deployed and the products manufactured have a significant influence on the configuration of a factory. In order to allow better coordination between technology, product, and factory planning, a method for integrative factory coordination has been developed at the Hanover Center for Production Technology (PZH). This approach is based on the general roadmapping idea and permits the systematization of the information transfer concerning content and time between factory, technology, and product planning.