Degradation behaviors of linear low‐density polyethylene and poly(L‐lactic acid) blends

In this study, the degradability of linear low‐density polyethylene (LLDPE) and poly(L ‐lactic acid) (PLLA) blend films under controlled composting conditions was investigated according to modified ASTM D 5338 (2003). Differential scanning calorimetry, X‐ray diffraction, and Fourier transform infrared spectroscopy were used to determine the thermal and morphological properties of the plastic films. LLDPE 80 (80 wt % LLDPE and 20 wt % PLLA) degraded faster than grafted low‐density polyethylene–maleic anhydride (M‐g‐L) 80/4 (80 wt % LLDPE, 20 wt % PLLA, and 4 phr compatibilizer) and pure LLDPE (LLDPE 100). The mechanical properties and weight changes were determined after composting. The tensile strength of LLDPE 100, LLDPE 80, and M‐g‐L 80/4 decreased by 20, 54, and 35%, respectively. The films, as a result of degradation, exhibited a decrease in their mass. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Imaging Cancer Cells Expressing the Folate Receptor with Carbon Dots Produced from Folic Acid

Development of new imaging tools for cancer cells in vitro and in vitro is important for advancing cancer research, elucidating drug effects upon cancer cells, and studying cellular processes. We showed that fluorescent carbon dots (C‐dots) synthesized from folic acid can serve as an effective vehicle for imaging cancer cells expressing the folate receptor on their surface. The C‐dots, synthesized through a simple one‐step process from folic acid as the carbon source, exhibited selectivity towards cancer cells displaying the folate receptor, making such cells easily distinguishable in fluorescence microscopy imaging. Biophysical measurements and competition experiments both confirmed the specific targeting and enhanced uptake of C‐dots by the folate receptor‐expressing cells. The folic acid‐derived C‐dots were not cytotoxic, and their use in bioimaging applications could aid biological studies of cancer cells, identification of agonists/antagonists, and cancer diagnostics.     

Block truncation coding using pattern fitting

Block truncation coding (BTC) divides an image into blocks having given size and then encodes each block by two representative gray levels and a bit-pattern. In this work a modified scheme of BTC is proposed where the computed representative gray levels are the bias and the contrast in each block. Secondly, instead of determining bit-pattern for each block, an optimum bit-pattern is selected from a pattern-book. Thus the index of the optimum pattern is used to encode in lieu of the explicit pattern. Thirdly, if the contrast is low the block is assumed to be smooth and bit-pattern is not required to reconstruct the block. This leads to significant reduction in bit-rate (bpp). Finally, the contrast component and the predictive residual of the bias component are entropy coded to achieve further reduction in bpp. Performance of the proposed scheme is measured in terms of peak-signal-to-noise ratio and bpp, and is compared with other recently reported methods.     

Enantioselective N‐Heterocyclic Carbene‐Catalyzed Annulations of 2‐Bromoenals with 1,3‐Dicarbonyl Compounds and Enamines via Chiral α,β‐Unsaturated Acylazoliums

The N‐heterocyclic carbene (NHC)‐catalyzed generation of chiral α,β‐unsaturated acylazoliums from 2‐bromoenals followed by their interception with 1,3‐dicarbonyl compounds or enamines, the formal [3+3] annulation reaction, is reported. The reaction results in the enantioselective synthesis of synthetically and medicinally important dihydropyranones and dihydropyridinones, and tolerates a wide range of functional groups. It is noteworthy that the reaction takes place under mild reaction conditions utilizing relatively low catalyst loadings. In addition, based on DFT calculations, a mechanistic scenario involving the attack of the nucleophile from below the plane of the α,β‐unsaturated acylazoliums, and the mode of enantioinduction is presented.     

Emulsion Stabilized with Starch Octenyl Succinate Prolongs Nisin Activity Against Listeria Monocytogenes in a Cantaloupe Juice Model

Food safety related to fresh and fresh‐cut produce, such as cantaloupe, is a great challenge in the food industry. Various processing technologies, including the use of antimicrobial materials, have been applied to reduce pathogens. Nisin, an antimicrobial peptide, shows strong inhibitory activity against Listeria monocytogenes (LM); however, it suffers from quick depletion in foods. In this study, the protective effect of starch octenyl succinate (starch‐OS) stabilized emulsion on nisin was evaluated in a cantaloupe juice model. Results showed that the proteolytic enzyme in cantaloupe juice caused nisin depletion, and the adsorption of nisin in emulsion led to considerable protection of antimicrobial activity. After 1, 3, and 6 d of incorporation with cantaloupe juice, the size of LM inhibitory ring were 7.64, 7.60, and 2.97 mm, respectively for emulsion formulations, whereas it reduced from 3.60 mm to a negligible level for nisin‐alone. This study showed the potential of using carbohydrate colloidal systems to prolong the efficacy of antimicrobial materials.     

Process engineering for stable power recovery from dairy wastewater using microbial fuel cell

Microbial fuel cells (MFCs) are one of the sustainable technologies that can effectively treat wastewater with concomitant generation of electricity. The present study investigated the treatment of real dairy wastewater (RDW) using Shewanella algae (MTCC-10608) within a single chamber microbial fuel cell (SCMFC). The study was conducted in both batch and fed-batch modes with initial chemical oxygen demand (COD) of 4000 mg/L and 2000 mg/L, respectively, in 0.2 L working volume of RDW for 15 days. However, the fed-batch strategy involved subsequent feeding of dairy wastewater with 6000 mg/L and 8000 mg/L COD on the 5th and 10th day, respectively. This two-step feeding strategy resulted in a maximum open-circuit voltage of 666 mV at 286 h of incubation with a COD removal efficiency of 92.21% and a columbic efficiency of 27.45%. The kinetic studies predicted the saturation constant of 55.83 mg COD/L and current density of 143.3 mA/m², which are similar to the findings from the experiments and polarization curve obtained. The maximum current density and power density from experiments were found to be 141 mA/m² and 50 mW/m² respectively. Thus, this study successfully indicates the utilization of dairy wastewater as a potential substrate for the sustainable power generation using Shewanella algae as a biocatalyst in the microbial fuel cell.     

A low-cost PC-based virtual oscilloscope

The integration of personal computers (PCs) with the present-day measurement and instrumentation world has opened up the door for "virtual instrumentation." This paper describes the development of a low-cost, PC-based, virtual digital oscilloscope. A data acquisition device using the computer parallel port has been fabricated with full analog interface and 8-b analog-to-digital converter with associated control-logic and timing circuitries. A software package aimed at managing the acquisition process and displaying the acquired signal has also been developed. This device has been conceived as a simple plug-in board to be incorporated to any IBM PC parallel port-thus, in many cases, eliminating the requirements of multiple, expensive, digital oscilloscopes. The project, initially designed as an undergraduate thesis, is currently being used for laboratory instructional purposes. The features of this device make it suitable for implementing as an educational resource for undergraduate students from Electrical, Electronics, Instrumentation, and Computer Science faculties.     

Performance Improvement of a Power Conversion Module by Liquid Micro-Jet Impingement Cooling

Liquid micro-jet array impingement cooling of a power conversion module with 12 power switching devices (six insulated gate bipolar transistors and six diodes) is investigated. The 1200-V/150-A module converts dc input power to variable frequency, variable voltage three-phase ac output to drive a 50HP three-phase induction motor. The silicon devices are attached to a packaging layer [direct bonded copper (DBC)], which in turn is soldered to a metal base plate. DI water micro-jet array impinges on the base plate of the module targeted at the footprint area of the devices. Although the high heat flux cooling capability of liquid impingement is a well-established finding, the impact of its practical implementation in power systems has never been addressed. This paper presents the first one-to-one comparison of liquid micro-jet array impingement cooling (JAIC) with the traditional methods, such as air-cooling over finned heat sink or liquid flow in multi-pass cold plate. Results show that compared to the conventional cooling methods, JAIC can significantly enhance the module output power. If the output power is maintained constant, the device temperature can be reduced drastically by JAIC. Furthermore, jet impingement provides uniform cooling for multiple devices placed over a large area, thereby reducing non-uniformity of temperature among the devices. The reduction in device temperature, both its absolute value and the non-uniformity, implies multi-fold increase in module reliability. The results thus illustrate the importance of efficient thermal management technique for compact and reliable power conversion application     

Coordinating a supply chain under uncertain demand and random yield in presence of supply disruption

A two-echelon supply chain involving one manufacturer and one retailer for a single product is considered in this paper. The end customers’ demand is assumed to be random. The production of the manufacturer is subject to random yield, and there is a possibility of supply disruption in which case no item from her can reach the retailer. The retailer has a backup supplier who is costlier but perfectly reliable, and is having a limit up to which he may deliver. In addition to placing an order to the manufacturer, the retailer is allowed to reserve a quantity from the backup supplier in the ordering period; he may buy up to the reserved quantity after realising actual market demand in the trading period. Aiming at studying the effects of the various uncertainties involved in the chain on the optimal decisions, we develop and analyse centralised and decentralised models. We also propose a contract mechanism to coordinate the chain and find threshold conditions for which the coordinated model would collapse. Numerical examples are provided to illustrate the developed model.