Error analysis in hybrid computer simulation of dynamic systems

A state-space oriented approach to analyze dynamic errors in a hybrid computer simulation loop is presented. The approach helps to predict the value of the sampling interval that achieves stable simulation with a prescribed accuracy. A pre-perturbation technique to compensate for the serious digital execution time delay error is then developed. It has the advantages that it does not require additional computer hardware and/or software and its utilization does not result in generation of any extraneous modes.The approach points out the contribution of each individual error source in the hybrid computer loop to the overall simulation accuracy.     

Behavior of Bond-Critical Regions Wrapped with Fiber-Reinforced Polymer Sheets in Normal and High-Strength Concrete

This paper reports on the third phase of a multiphase study undertaken at the American University of Beirut (AUB) to examine the effect of fiber-reinforced polymer (FRP) sheets in confining tension lap splice regions in reinforced concrete beams. Results of the first two phases showed that glass and carbon fiber-reinforced polymer (GFRP and CFRP) sheets were effective in increasing the bond strength and improving the ductility of the mode of failure of tension lap splices in high-strength concrete (HSC) beams with nominal concrete strength of 70 MPa. The experimental results of the two phases were used to propose a new FRP confinement parameter, Ktr,f, that accounts for the bond strength contribution of FRP sheets wrapping tension lap splice regions in HSC beams. In this third phase of the AUB study, the trend of the results of phases 1 and 2 and the validity of the analytical model proposed were verified if normal-strength concrete (NSC) is used instead of HSC. Seven beams with nominal concrete strength of 27.58 MPa (4 ksi) were tested in positive bending. Each beam was designed with a tension lap splice in a constant moment region in the midspan of the beam. The main test variables were the configuration (1 strip, 2 strips, or a continuous strip) and the number of layers (1 layer or 2 layers) of the CFRP sheets wrapping the splice region. The test results demonstrated that CFRP sheets were effective in enhancing the bond strength and ductility of failure mode of tension lap splices in NSC in a very similar way to HSC. In addition, the FRP confinement index proposed earlier for HSC was proven to be valid in the case of NSC.     

Optimized structure and electrochemical properties of sulfonated carbon nanotubes/Co–Ni bimetallic layered hydroxide composites for high-performance supercapacitors

Technical development in electronic devices is frequently stifled by their insufficient capacity and cyclic stability of energy-storage devices. The nano-structured materials have sensational importance for providing novel and optimized combination to overcome exiting boundaries and provide efficient energy storage systems. Metal hydroxide materials with high capacity for pseudo-capacitance properties have grabbed special attention. Lately, the blend of nickel and cobalt hydroxides has been considered as a favorable class of metallic hydroxide materials owing to their comparatively high capacitance and exceptional redox reversibility. The sulfonated carbon nanotube fluid (SCNTF) was prepared by the ion exchange method to be utilized as the exceptional templates due to astonishing specific surface area, ensuring the maximum utilization of the active material. The CoNi-layered double hydroxides (LDHs)/SCNTF core-shell nanocomposite was prepared by the simple solvothermal method. Structural analysis showed that the composite material had the high conductance of carbon materials, the pseudo-capacitance characteristics of metal hydroxides, and porous structure, which facilitates the ion shuttle when the electrolyte reacts with the active material. Electrochemical analysis results showed that CoNi-LDHs/SCNTF had excellent rate performance, reversible charge-discharge properties and cycle stability. It exhibited an extreme specific capacity of 1190.5 F g^?1 at a current density of 1 A g^?1; whereas specific capacity remained 953.7 F g^?1 at the current density was 10 A g^?1. In addition, the capacity retention rate after 5000 charge-discharge cycles at a current density of 20 A g^?1 was 81.0%. The results indicated that the CoNi-LDHs/SCNTF core-shell nanocomposite material is cost efficient and an effective substitute in energy storage applications.     

Halogenation effect promoted low bandgap polymers based on asymmetric isoindigo unit with low energy loss

To optimize the energy levels of the structural framework of isoindigo polymers, a series of asymmetric isoindigo based low bandgap polymers with chlorine, fluorine and thiazole substituents was constructed and their optical, electrochemical and photovoltaic properties were comparatively evaluated for the impact of different substitutions. In comparison with the polymer based on 2,2'‐bithiophene and isoindigo unit (PTi) with non‐substituted bithiophene as the donor moiety, the highest occupied molecular orbital energy level for the newly synthesized polymers is significantly decreased, and in turn an improvement of the open‐circuit voltage (V_OC) is noted in the corresponding photovoltaic devices. More importantly, combined with a low bandgap of 1.32 eV, the energy losses (E_loss) could be reduced to 0.61 eV for polymer based on chlorinated 2,2'‐bithiophene and isoindigo unit (PCl). In addition, the halogen moieties are observed to be superior in device fabrication and give better values than the thiazole substituent. Both fluorinated and chlorinated polymer donors exhibited improved performance compared with the original polymer PTi. Consequently, this work not only presents the influence of different electron withdrawing substituents on the physicochemical and photovoltaic performance, but also backs the concept of how to reduce the energy loss via the heteroatom effect. © 2020 Society of Chemical Industry     

Switchable Fluorescence of Doxorubicin for Label-Free Imaging of Bioorthogonal Drug Release

Monitoring the release and activation of prodrug formulations provides essential information about the outcome of a therapy. While the prodrug delivery can be confirmed by using different imaging techniques, confirming the release of active payload by using imaging is a challenge. Here, we have discovered that the switchable fluorescence of doxorubicin can validate drug release upon its uncaging reaction with a highly specific chemical partner. We have observed that the conjugation of doxorubicin with a trans-cyclooctene (TCO) diminishes its fluorescence at 595 nm. This quenched fluorescence of the doxorubicin prodrug is recovered upon its bond-cleaving reaction with tetrazine. Clinically assessed iron oxide nanoparticles were used to formulate a doxorubicin nanodrug. The release of doxorubicin from the nanodrug was studied under various experimental conditions. A fivefold increase in doxorubicin fluorescence is observed after complete release. The studies were carried out in vitro in MDA-MB-231 breast cancer cells. An increase in Dox signal was observed upon tetrazine administration. This switchable fluorescence mechanism of Dox could be employed for fundamental studies, that is, the reactivity of various tetrazine and TCO linker types under different experimental conditions. In addition, the system could be instrumental for translational research where the release and activation of doxorubicin prodrug payloads can be monitored by using optical imaging systems.     

Modeling and operation optimization of RE integrated microgrids considering economic,energy, and environmental aspects

Microgrids provide promising solution for integration of renewable energy sources in the electrical grid. To exploit the key benefits, achieving the economical operation of renewable aided microgrids has become necessary and is a challenging task. This paper presents an efficient optimization model to minimize the operational cost of a solar integrated microgrid. We formulate a joint optimization mixed integer problem for appropriate modeling of the system under various practical constraints. An efficient solution is obtained with a distributed approach such that the original problem is solved in two stages. Dual decomposition approach is adopted for cost, emissions, and solar share optimization. Lagrange relaxation, Lambda iteration method, and binary integer programming are employed to obtain the joint optimization solution. Finally, the performance of the proposed model is validated through simulations that show that an overall cost reduction of 4.2070e+04 $ and emission reduction of 7.2001e+03 kg are achieved with the proposed model.