紫外光固化聚合物涂层的原位光稳定化研究

选用实验室制备的四种新型反应型受阻胺类光稳定剂(r-HALS):4-甲基丙烯酰氧基-2,2,6,6-四甲基哌啶醇酯(MTMP)、4-丙烯酰氧基-2,2,6,6-四甲基哌啶醇酯(ATMP)、4-甲基丙烯酰氧基-1,2,2,6,6-五甲基哌啶醇酯(MPMP)和4-丙烯酰氧基-1,2,2,6,6-五甲基哌啶醇酯(APMP),实现了紫外光固化聚合物涂层(膜)的原位(in situ)光稳定化。通过室内人工光老化实验和在光氧化过程中黄度指数(Yellowness Index,YI)的监测,再与典型的商用HALS(Tinuvin770和Tinuvin292)进行平行实验对比,考察了r-HALS对紫外光固化聚合物涂层的光防护效果,探索一条紫外光固化聚合物涂层原位(in situ)光稳定化的新途径。     

鞍钢3200m3高炉矿槽施工

介绍了鞍钢新1号高炉(3200m3)矿槽结构的设计原理及其所包含的钢结构、混凝土结构施工技术要点和质量控制,并作出了技术经济效果评述.     

Effect of H_2 dilution on the structure and properties of nc-CrC/a-C:H coatings deposited by a hybrid beams system

Nanocomposite Cr C/hydrogenated amorphous carbon(nc-CrC/a-C:H) coatings were deposited by a hybrid beams system comprised of a hollow cathode ion source and a cathodic arc ion-plating unit with varying H_2 flow rates. The influences of H_2 flow rates on the morphologies, microstructures, and properties of the coatings were systematically studied. The morphologies and microstructures of the coatings were characterized by SEM, AFM, XPS, Raman spectroscopy, GIXRD, and HRTEM. The mechanical and tribological properties were measured by a nano-indenter, scratch tester, and ball-ondisk tribometer. The wear tracks were evaluated using 3D profilometer, optical microscope, and EDS analysis. It has been found that a moderate H_2 flow rate can effectively smooth the surface, enlarge the fraction of a sp~3 bond, and improve the properties. The coating exhibits the highest hardness and elastic modulus at the H_2 flow rate of 40 sccm. A superior combination of adhesion strength,friction coefficient, and wear resistance can be achieved at the H_2 flow rate of 80 sccm.     

空气污染排放视角下中国核电的健康效益

核电在改善空气质量方面具有重要的作用。本文对比了核电与煤电的空气污染物排放系数,根据空气污染物引起的死亡率与人均燃煤发电量的负指数幂关系,评估了中国通过发展核电在改善空气质量方面对居民的健康效益,并对未来的健康效益进行了分析。结果显示,发展核电能够避免的死亡人数在增加。据估算,1995—2018年,中国核电累计可避免约4.7万人因空气污染物死亡,可避免约22.6万人因空气污染物患病。2020—2030年,预计会避免8.3万~9.4万人死亡,避免39.7万~45.1万人患病。     

离子束技术应用于腐蚀科学

离子束技术(包括离子注入、离子束混合、离子束分析等)在腐蚀科学领域中的应用是近十年来一个引人注目的新发展。 据工业发达国家估计,每年因材料、设备腐蚀造成的直接损失约为当年国民经济总产值的2—4％,例如美国1982年全国因腐蚀而造成的经济损失就高达1260亿美元,我国在1980年估算的腐蚀损失约200亿人民币。随着我国四化建设的迅速发展,金属腐蚀与防护的研究已成为当前一个急待进行的重要课题。     

一种大动态检测输入前端设计

一种基于小信号处理、无源网输入、数字化处理、智能化操作的方法,以求获得较好的灵敏度和极大的测量动态范围的测量前端电路设计。     

余热处理高强度钢筋中冷却模型的研究

本文通过研究余热处理高强度钢筋的控制冷却原理和低碳钢相变规律,建立控制冷却的数学模型。研究表明,建立的数学模型实用可靠,冷却强度可以随化学成分、终轧速度、终轧温度、自回火温度等生产条件的变化而进行逻辑分析,进而确定控冷工艺参数,生产性能合格稳定的钢筋。此外,根据生产条件的不同,冷却程序具有可移植性。     

Structural scheme and theory behind feedback compensation of new parallel machine tools

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飞行器与机器人的区域目标搜索最优控制

描述了飞行器导航或移动机器人的区域搜索控制问题.为了使该问题得到优化解决,首先建立了基于区域搜索控制问题的模型,将最优控制原理运用于此模型上,得到其伴随方程和控制方程,后基于此分析了该问题,且讨论了此方法的可行性.然后,通过解出问题的规范方程,使飞行器导航或移动机器人的区域搜索控制问题最终得以解决,进而推导得到了飞行器导航或移动机器人的区域目标搜索最优控制以及最优轨线.最后,通过计算仿真结果表明,该方法是有效的,故为飞行器导航与移动机器人的区域目标搜索最优控制提供了依据.     

Rapid growth of angle-confined large-domain graphene bicrystals

In the chemical vapor deposition growth of large-area graphene polycrystalline thin films,the coalescence of randomly oriented graphene domains results in a high density of uncertain grain boundaries (GBs).The structures and properties of various GBs are highly dependent on the misorientation angles between the graphene domains,which can significantly affect the performance of the graphene films and impede their industrial applications.Graphene bicrystals with a specific type of GB can be synthesized via the controllable growth of graphene domains with a predefined lattice orientation.Although the bicrystal has been widely investigated for traditional bulk materials,no successful synthesis strategy has been presented for growing two-dimensional graphene bicrystals.In this study, we demonstrate a simple approach for growing well-aligned large-domain graphene bicrystals with a confined tilt angle of 30° on a facilely recrystallized single-crystal Cu (100) substrate.Control of the density of the GBs with a misorientation angle of 30° was realized via the controllable rapid growth of subcentimeter graphene domains with the assistance of a cooperative catalytic surface-passivation treatment.The large-area production of graphene bicrystals consisting of the sole specific GBs with a tunable density provides a new material platform for fundamental studies and practical applications.