Transparent,Highly Stretchable,Rehealable, Sensing,and Fully Recyclable Ionic Conductors Fabricated by One‐Step Polymerization Based on a Small Biological Molecule

To date, various stretchable conductors have been fabricated, but simultaneous realization of the transparency, high stretchability, electrical conductivity, self‐healing capability, and sensing property through a simple, fast, cost‐efficient approach is still challenging. Here, α‐lipoic acid (LA), a naturally small biological molecule found in humans and animals, is used to fabricate transparent (>85%), electrical conductivity, highly stretchable (strain up to 1100%), and rehealable (mechanical healing efficiency of 86%, electrical healing efficiency of 96%) ionic conductor by solvent‐free one‐step polymerization. Furthermore, the ionic conductors with appealing sensitivity can be served as strain sensors to detect and distinguish various human activities. Notably, this ionic conductor can be fully recycled and reprocessed into new ionic conductors or adhesives by a direct heating process, which offers a promising prospect in great reduction of electronic wastes that have brought acute environmental pollution. In consideration of the extremely facile preparation process, biological available materials, satisfactory functionalities, and full recyclability, the emergence of LA‐based ionic conductors is believed to open up a new avenue for developing sustainable and wearable electronic devices in the future.     

C+注入Si形成SiC/Si异质结构的椭偏光谱

用椭偏光谱法测量了(35keV,1.0×10118cm-2)和(65keV,1. 0×1018cm-2)C+注入Si形成的SiC/Si异质结构.应用多层介质膜模型和有效介质近似,分析了这些样品的SiC/Si异质结构的各层厚度及主要成份.研究结果表明:注35keV C+的样品在经1200 C、2h退火后形成的SiC/Si异质结构,其β-SiC埋层上存在一粗糙表面层,粗糙表面层主要由β-SiC、非晶Si和SiO2组成,而且β-SiC埋层与体硅界面不同于粗糙表面层与β-SiC埋层界面;注65keV C+的样品在经1250 C、10h退火后形成的SiC/Si异质结构,其表层Si是较完整的单晶Si,埋层B-SiC分成三层微结构,表层Si与β-SiC埋层界面和β-SiC埋层与体硅界面亦不相同.这些结果与X射线光电子谱(XPS)和横截面透射电子显微镜(TEM)的分析结果一致.     

相位干涉仪全数字化测向方法分析

传统干涉仪测向采用模拟鉴相器,鉴相误差较大,而数字化鉴相器也仅仅是对输出相位差数字化,精度提高有限.本文提出了一种基于数字接收机的全数字化鉴相器进行测向的方法.经理论分析和仿真实验,该方法测向精度有很大提高,且可以实现同时多信号的分辨.     

Low thermal resistance high-speed top-emitting 980-nm VCSELs

Increasing copper plated heatsink radii from 0 to 4 /spl mu/m greater than the mesa in vertical-cavity surface-emitting lasers (VCSELs) reduced the measured thermal resistance for a range of device sizes to values 50% lower than previously reported over a range of device sizes. For a 9-/spl mu/m diameter oxide aperture, the larger heatsink increases output power and bandwidth by 131% and 40%, respectively. The lasers exhibit a 3-dB modulation frequency bandwidth up to 9.8 GHz at 10.5 kA/cm/sup 2/. The functional dependence of thermal resistance on oxide aperture diameter indicates the importance of lateral heat flow to mesa sidewalls.     

Reproducible and Sensitive Plasmonic Sensing Platforms Based on Au-Nanoparticle-Internalized Nanodimpled Substrates

Electromagnetic enhancement effects through localized surface plasmon resonance considerably amplify the intensity of incident light when molecules are positioned in the vicinity of miniscule nanogaps. The aggregation of plasmonic nanoparticles synthesized using bottom-up methods has been extensively used to generate hot spots in solutions. These methods assist in obtaining non-periodic plasmonic signals, because the realization of uniform nanogaps through particle aggregation is difficult. Nanostructured substrates with gaps of 20–100 nm have also been fabricated using the top-down approach. However, the fabrication of smaller nanogap templates using these methods is difficult owing to high costs and low throughput. Therefore, a nanodimple array internalized with AuNPs is developed in this study to mitigate the challenges encountered in the bottom-up and top-down approaches. Precise nanogaps are generated by regularly internalizing AuNPs in the cavities of nanodimples through DNA hybridization. Simulations of the electric field distribution indicate that the incorporation of 80 nm-sized AuNPs into a curved nanodimpled Au substrate generate high-density volumetric hot spots within a detection volume, and result in a high plasmonic enhancement factor of 8.25 × 10⁷. The tremendous potential of the proposed plasmonic platform as an SERS-based biomedical diagnostic device is also verified.     

Tuning the Phase and Microstructural Properties of TiO<Subscript>2</Subscript> Films Through Pulsed Laser Deposition and Exploring Their Role as Buffer Layers for Conductive Films

Titanium oxide (TiO₂) is a semiconducting oxide of increasing interest due to its chemical and thermal stability and broad applicability. In this study, thin films of TiO₂ were deposited by pulsed laser deposition on sapphire and silicon substrates under various growth conditions, and characterized by x-ray diffraction (XRD), atomic force microscopy (AFM), optical absorption spectroscopy and Hall-effect measurements. XRD patterns revealed that a sapphire substrate is more suitable for the formation of the rutile phase in TiO₂, while a silicon substrate yields a pure anatase phase, even at high-temperature growth. AFM images showed that the rutile TiO₂ films grown at 805°C on a sapphire substrate have a smoother surface than anatase films grown at 620°C. Optical absorption spectra confirmed the band gap energy of 3.08 eV for the rutile phase and 3.29 eV for the anatase phase. All the deposited films exhibited the usual high resistivity of TiO₂; however, when employed as a buffer layer, anatase TiO₂ deposited on sapphire significantly improves the conductivity of indium gallium zinc oxide thin films. The study illustrates how to control the formation of TiO₂ phases and reveals another interesting application for TiO₂ as a buffer layer for transparent conducting oxides.     

Mobility management approaches for SDN-enabled mobile networks

The evolving network technologies aim at meeting the envisioned communication demands of future smart cities and applications. Although software-defined networking (SDN) enables flexible network control, its applicability to mobile networks is still in its infancy. When it comes to introducing the SDN vision to mobile networks, handling of wireless events and mobility management operations stand out as major challenges. In this paper, we study the scalability issues of SDNized wireless networks, specifically those relevant to mobility management. We design and implement different mobility management approaches in SDNized wireless networks and investigate the impact of various system variables on the overall handover delays. We also study the improvements in handover delays: (i) when a proposed proactive mobility management algorithm is implemented; (ii) when the controller delegates partial control of mobility management to the forwarding entities. For the implementation of the proposed approaches on the OpenFlow network, the paper also suggests potential extensions to the OpenFlow protocol. The contributed approaches are validated on a full-scale demonstrator, with results showing that proactive outperforms reactive and that the delegated control approach performs better than proactive for smaller topology sizes. Furthermore, a proposal for LTE X2-specific control delegation is discussed as a use case.     

Impact of the Solvation State of Lead Iodide on Its Two‐Step Conversion to MAPbI3: An In Situ Investigation

Producing high efficiency solar cells without high‐temperature processing or use of additives still remains a challenge with the two‐step process. Here, the solution processing of MAPbI₃ from PbI₂ films in N,N‐dimethylformamide (DMF) is investigated. In‐situ grazing incidence wide‐angle X‐ray scattering (GIWAXS) measurements reveal a sol–gel process involving three PbI₂‐DMF solvate complexes—disordered (P₀) and ordered (P₁, P₂)—prior to PbI₂ formation. When the appropriate solvated state of PbI₂ is exposed to MAI (methylammonium Iodide), it can lead to rapid and complete room temperature conversion into MAPbI₃ with higher quality films and improved solar cell performance. Complementary in‐situ optical reflectance, absorbance, and quartz crystal microbalance with dissipation (QCM‐D) measurements show that dry PbI₂ can take up only one third of the MAI taken up by the solvated‐crystalline P₂ phase of PbI₂, requiring additional annealing and yet still underperforming. The perovskite solar cells fabricated from the ordered P₂ precursor show higher power conversion efficiency (PCE) and reproducibility than devices fabricated from other cases. The average PCE of the solar cells is greatly improved from 13.2(±0.53)% (from annealed PbI₂) to 15.7(±0.35)% (from P₂) reaching up to 16.2%. This work demonstrates the importance of controlling the solvation of PbI₂ as an effective strategy for the growth of high‐quality perovskite films and their application in high efficiency and reproducible solar cells.     

Analytic, Simulation, and Empirical Evaluation of Delay/Fault-Tolerant Mobile Sensor Networks

The delay/fault-tolerant mobile sensor network (DFT-MSN) has been proposed for pervasive information gathering. DFT-MSN distinguishes itself from conventional sensor networks by several unique characteristics such as sensor mobility, loose connectivity, and delay/fault tolerability. This paper focuses on the performance evaluation of DFT-MSN. We first introduce a queuing model by using Jackson network theory. While the queuing model is based on a few simplification assumptions for analytic tractability, it provides insights into the queuing behavior of the mobile sensors in DFT-MSN. Extensive simulations are performed under realistic environment and assumptions. Our simulation results show that the dynamic DFT-MSN data delivery scheme achieves the highest message delivery ratio with acceptable delay and transmission overhead, compared with simple schemes such as flooding and direct transmission or other approaches in the literature such as Zebranet. We have also implemented a DFT-MSN testbed by deploying crossbow motes for noise level monitoring in our university library. Though in a small scale, the testbed demonstrates the feasibility of DFT-MSN and provides guidance for future large scale deployment.