Transient strain of high strength concrete at elevated temperatures and the impact of polypropylene fibers

This paper presents the results of an experimental study on the transient strain of high strength concrete (HSC) under heating up to 750°C and the impact of polypropylene (PP) fibers. Concerning this topic only few results are available in the literature and systematic investigations are missing. However, basic knowledge is necessary for the understanding of the internal damage processes in the material as well as for heated structures. The transient strain during heating can be separated in two basic components: the free thermal strain and the mechanical strain. They were experimentally determined exemplarily for one HSC. For the determination of the mechanisms of transient strain and particularly the influence of PP fibers different techniques were applied. In this context the monitoring of the microcracking was done for the first time with acoustic emission analysis in combination with ultrasonic measurements. This new approach helps fundamentally to explain the impact of PP fibers on free thermal strain and mechanical strain during heating up. Furthermore weight loss measurements were carried out to characterize the moisture transport. It was shown that the PP fibers cause an acceleration of the moisture transport in the temperature range from 200 to 250°C which leads to drying shrinkage in opposite direction to the free thermal strain. Hence this paper is a contribution to the general understanding of the impact of PP fibers in HSC at high temperatures and emphasizes the important influence of PP fibers on the thermal and mechanical induced strain of HSC.     

Engineering TM1459 for Stabilisation against Inactivation by Amino Acid Oxidation

Oxidative alkene cleavage is a highly interesting reaction to obtain aldehydes and ketones. The Mn-dependent protein TM1459 from Thermotoga maritima can catalyse alkene cleavage of styrene derivatives in the presence of tert-butyl hydroperoxide. Despite the high thermal stability of the enzyme, it gets inactivated during the reaction. The data reported here indicate that auto-oxidation is responsible for the low stability of TM1459 in the oxidative environment required for the alkene cleavage reaction. By targeting the exchange of residues prone to oxidation, this phenomenon was successfully prevented. Importantly, the stability to oxidation conveyed by the amino acid exchanges led to increased enzyme activity. However, the exchanges resulted in slightly modified positions of two of the four metal-binding amino acids, thereby strongly impacting metal binding.     

Production level,fertility, health traits,and longevity in local and commercial dairy breeds under organic production conditions in Austria,Switzerland, Poland,and Sweden

Our aim was to map the performance of local (native) dairy cattle breeds in Austria, Switzerland, Poland, and Sweden with regard to production, fertility, longevity, and health-associated traits and to compare them with commercial (modern) breeds. For this purpose, we analyzed test-day records (July 1, 2011, to June 30, 2014) and treatment records (Austria, Sweden) of cows managed on organic farms. We performed country-wise comparisons of 123,415 lactations from Original Braunvieh (OB) and Grey Cattle (AL) with Braunvieh (BV; Brown Swiss blood >60%) in Switzerland; AL with BV (Brown Swiss blood >50%) in Austria; Polish Black and White (ZB), Polish Red and White (ZR), and Polish Red (RP) with Polish Holstein Friesian (PHF) in Poland; and Swedish Red (SRB) with Swedish Holstein (SH) in Sweden. Average milk yields were substantially lower for local compared with commercial breeds in all countries; differences ranged from 750 kg (Sweden) to 1,822 kg (Austria), albeit on very different average levels. Local breeds showed a longer productive lifetime by 0.64, 0.83, 1.42, and 0.20 lactations in Switzerland, Austria, Poland, and Sweden, respectively, again on very different levels in each country. Regarding fertility traits, calving interval was shorter in local than in commercial breeds by 13 (Sweden), 14 (Switzerland), and 20 d (Austria, Poland). Insemination index was lower in certain local breeds by 0.15 (Switzerland), 0.14 (Austria), 0.21 (Poland), and 0.13 (Sweden). Several local breeds showed a lower proportion of cows with >100,000 somatic cells/mL. This was the case in Switzerland (OB 24.2%; BV 35.8%), Austria (AL 25.3%; BV 36.9%), and Sweden (SRB 42.4%; SH 43.4%). In contrast, the respective proportion in Poland exceeded 82% in all breeds except the commercial PHF (76.1%). In Sweden, lactations with veterinary treatments were considerably less prevalent in SRB (15.6%) than in SH (21.7%). In Austria, breeds differed only in treatments for udder disorders, which favored AL. In conclusion, the markedly lower milk yields of local breeds are partly counterbalanced by (somewhat inconsistent) advantages in longevity, fertility, and health traits across 4 European countries. This indicates that the robustness of local breeds can contribute to improved sustainability of organic dairy systems.     

Great globe thistle fruit (Echinops sphaerocephalus L.), a potential new oil crop

New plant oil crops are desirable as renewable resources for energy, for food purposes, and as building blocks in chemical synthesis. Fruit oil of Echinops sphaerocephalus was characterized by a high content of linoleic acid (over 70% of total fatty acids) and by a high tocopherol content (530–970 mg/kg oil). The majority was α‐tocopherol. Echinops sphaerocephalus plants may be cultivated in agricultural dimensions, and fruits may be obtained by a combine harvester. Echinops quinoline alkaloids present a useful by‐product of the oil production.     

Desaturation and chain elongation of essential fatty acids in isolated liver cells from rat and rainbow trout

Isolated hepatocytes from rainbow trout and rat were incubated with¹⁴C-labeled linoleic acid, linolenic acid, dihomogammalinolenic acid or eicosapentaenoic acid. The most striking difference in the desaturase activity was the lower level of Δ5 desaturase in trout than in rat. No Δ4 desaturation of 22∶4(n−6) to 22∶5(n−6) was observed in either of the two species, while the conversion of 22∶5(n−3) to 22∶6(n−3) was significant in both groups and highest in rainbow trout. The chain-elongating activity was remarkably similar in the two species, except for the “dead-end” elongation which was distinctly more important in fish.     

Uranium fluoride and metallic uranium as target materials for heavy-element experiments at SHIP

In this contribution we describe the production and application of uranium targets for synthesis of heavy elements. The targets are prepared from uranium fluoride (UF₄) and from metallic uranium with thin carbon foils as backing. Targets of UF₄ were produced by thermal evaporation in a similar way as the frequently applied targets out of Bi, Bi₂O₃, Pb, PbS, SmF₃, and NdF_3, prepared mostly from isotopically enriched material [Birgit Kindler, et al., Nucl. Instr. and Meth. A 561 (2006) 107; Bettina Lommel, et al., Nucl. Instr. and Meth. A 561 (2006) 100]. In order to use more intensive beams and to avoid scattering of the reaction products in the target, metallic uranium is favorable. However, evaporation of metallic uranium is not feasible at a sustainable yield. Therefore, we established magnetron sputtering of metallic uranium. We describe production and properties of these targets. First irradiation tests show promising results.     

An Ionic Liquid as Catalyst Medium for Stereoselective Hydrogenations of Sorbic Acid with Ruthenium Complexes

The ionic liquid 1‐n‐butyl‐3‐methylimidazolium hexafluorophosphate (bmim PF₆) ( 6 ) has been studied as catalyst medium for biphasic homogeneous hydrogenations of sorbic acid ( 1 ). As catalyst we used the Cp*‐ruthenium‐complex [Cp*Ru(η⁴‐CH₃—CHCH—CHCH—COOH) (CF₃SO₃)] which efficiently enables the stereoselective hydrogenation of sorbic acid leading to the formation of cis‐3‐hexenoic acid ( 3 ) in selectivities of up to 90% with turnover frequencies of up to 1100 h^—1. Compared to other biphasic systems the hydrogenation in bmim PF₆ proceeds with enhanced activity. The kinetics can be described with a Michaelis Menten‐equation, and the activation energy for the whole process was determined to be E_A = 78 ± 5 kJ/mol.     

Non‐Racemic Halohydrins via Biocatalytic Hydrogen‐Transfer Reduction of Halo‐Ketones and One‐Pot Cascade Reaction to Enantiopure Epoxides

Biocatalytic hydrogen‐transfer reduction of α‐chloro‐ketones furnished non‐racemic chlorohydrins by employing either Rhodococcus ruber as lyophilized cell catalyst or an alcohol dehydrogenase preparation from Pseudomonas fluorescens DSM 50106 (PF‐ADH). For all substrates investigated, Rhodococcus ruber gave strictly the “Prelog” product, whereas PF‐ADH showed scattered stereopreference. One possibility for a follow‐up reaction of halohydrins is the ring closure to the corresponding epoxide. A novel “one pot‐one step strategy” was employed to obtain the enantiopure epoxide from the α‐chloro‐ketone in a cascade like fashion at pH>12 involving biocatalytic hydrogen transfer reduction and in situ chemo‐catalyzed ring closure.     

Nanoclay‐reinforced poly(butylene adipate‐co‐terephthalate) biocomposites for packaging applications

Increasing generation and inadequate disposal of waste progressively compromise our environment. Solutions are proposed by the development of biodegradable polymers, that is, for short‐term applications like packaging. The present study focuses on the design and characterization of biodegradable poly(butylene adipate‐co‐terephthalate) (PBAT) nanocomposites reinforced by different types of nanoclays. The addition of natural and modified montmorillonite and bentonite to PBAT by melt mixing enhances slightly the thermal stability and increases the crystallization temperature, independently of the fillers' dispersion state. By contrast, storage modulus in dynamic mechanical analysis is increased when adding nanoclay, and improvement is higher for well‐dispersed organomodified fillers. Dispersion states and morphology of the nanocomposites are studied by X‐ray diffraction as well as scanning and transmission electron microscopy. PBAT‐based composites with modified bentonite reveal to show the best performance at room temperature (which is the temperature of interest for potential packaging applications) in comparison with the other investigated nanocomposites.POLYM. COMPOS., 33:2022–2028, 2012. © 2012 Society of Plastics Engineers