印染废水处理工艺研究及实例

本文简要介绍了印染废水水质特征,提出了处理工艺,并利用两个工程实例说明了该工艺的可行性.     

Effects of surfactant/silica and silica/cerium ratios on the characteristics of mesoporous Ce-MCM-41

Using the surfactant CTMABr (cetyltrimethyl ammonium bromide) and cerium(IV) sulfate, mesoporous Ce-MCM-41 molecular sieves were produced under a hydrothermal condition with various surfactant/silica (surfactant/Si) and silica/cerium (Si/Ce) ratios. Changes to the structural traits caused by changing the molar ratios of both surfactant/Si and Si/Ce were investigated. XRD (X-ray diffraction), FT-IR (fourier transform infrared spectroscopy), and SEM (scanning electro microscopy) were used for the characterization of prepared mesoporous samples. Among the tested molar ratios, surfactant/Si ratio of 0.5 and 0.2 showed highest values of d_1 0 0 and intensity, respectively, for the Si-MCM-41. XRD analysis also identified a quintessential hexagonal structure of Ce-MCM-41 for the Si/Ce molar ratio higher than 40 (maintaining the surfactant/Si ratio at 0.2). When cerium content was increased to have the Si/Ce molar ratio of 20, the hexagonal structure of Ce-MCM-41 was collapsed due to the structural stress of substituted cerium. FT-IR results confirmed calcination of Ce-MCM-41 and the incorporation of Ce⁴⁺ ions of cerium sulfate into the silica surface with proper removal of the surfactant. Rod-like shape with rounded edges of the prepared Ce-MCM-41 samples was identified by SEM. These results suggest surfactant/Si ratio of 0.2 and Si/Ce ratio of 40 for the production of Ce-MCM-41 with the highest level of crystallinity.     

市区微蜂窝传播路径损耗模式的比较检验

讨论了几种微蜂窝路径损耗模式,并用我国某城市测量的微蜂窝传播数据对COST231WI,修正COST231WI和Xia模式进行了检验,结果表明修正COST231模式的误差最小,Xia模式次之,COST231WI模式最差。从而得到修正COST231模式比较符合我国实际的微蜂窝传播预测模式。     

氩等离子体辐照反相乳液接枝改性涤纶织物的研究

首次提出了在等离子体辐照后再用反相乳液接枝改性涤纶织物的新方法,探讨了接枝颗粒特征以及织物各项物理力学性能.接枝织物的结构及性能的测试结果表明:接枝物的尺寸远小于纤维的直径,在提高织物吸湿性的同时,对织物透气性能和强力等无明显影响;实验也证实了乳液中未接枝单体可以再次聚合.     

气力输送在烧结电除尘输灰系统中的应用

针对烧结厂烧结电除尘灰的工况特性，介绍了输送烧结电除尘灰的正压气力输灰系统的特点、组成，还对在调试和试运行过程中遇到的故障进行了分析并制订了解决措施。     

Structural study of cubic pyrochlores based on quantum mechanical simulation

In the ideal A₂B₂O₆O′ pyrochlore structure, the x-value of O atom position is a variable parameter. In Bi_1.5ZnNb_1.5−xTa_xO₇ (BZNT) cubic pyrochlores, the x-values alter with the different compositions of Nb/Ta. In this work, a series of initial models for BZNT were established by analyzing X-ray diffraction data. Then three structure modifying methods, including Rietveld refinement, Rietveld refinement with energy and geometry optimization based on quantum mechanics, were employed to obtain the precise models using Materials Studio. Moreover, the reflectivities of BZNT were computed by quantum mechanical simulation based on the refined models. Comparing the simulation results from different modifying models with the experimental results, it is found that Rietveld refinement with energy optimization is the most accurate method for BZNT pyrochlores. According to the simulation results, the different reflectivities correspond well with various x-values of O atom positions in BZNT pyrochlores.     

富氧燃烧技术在梭式窑中的应用

研究了富氧燃烧技术对梭式窑烧成的影响.研究结果表明,随着氧浓度从21%-30%的逐渐增加,CO总浓度和NO总浓度都先明显下降,后缓慢上升;节能效果在初始段较为明显,而后效果不明显;而实际烟气量与氧浓度成反比,与过剩空气系数成正比.     

提高干凝胶强度的途径

干凝胶作为一种新型的轻质多孔材料在工业生产和人们的生活中具有广泛的应用,但是其较低的强度和易碎裂的特点却限制了其实际应用.结合干凝胶的制备过程,总结了几种有效的降低结构破坏的途径,并对其机理做了简要分析,最后对干凝胶的应用前景做了展望.     

汽车漆漆膜质量的改进与提高

通过对车身漆膜质量问题的分析,采取专业清洁公司整体承包车间保洁、工艺方面改进、更换生产外材料、供应商加强对汽车漆使用的监控等一系列措施,漆膜质量水平得以提高.