Groundwater interaction in the coastal environment: hydrochemical,electrical and seismic approaches

The heterogeneous Plio-Quaternary coastal aquifer of the Mamora Basin is the most significant reservoir of Morocco. It is composed of sandstones, conglomerates, limestones and more or less argillaceous sands. The increase in the requirements for water in this area requires further information on the relations between the geometry of the aquifer and the salinity of the water. A hydrochemical analysis was undertaken and highlighted three zones of high mineralization. A geophysical approach allowed the determination of the principal aquifer levels, the localization of the various types of water (fresh, brackish and salt) and the geometry of the aquifer base. The results obtained by these two approaches provide a better image of the phenomena governing the groundwater flows and their interactions      

Thermal behavior and energy saving analysis of a flat with different energy efficiency measures in six climates

This article aims at studying the impact of many construction parameters of a flat on its energy performance and thermal comfort. The studied parameters are: the envelope thermal insulation, the orientation, the floor level, the ground coupling, the roof and the external walls absorption coefficient and the controlled mechanical ventilation. The TRNSYS based numerical study is performed in six different climates ranging from cold to desert one. The numerical model has been validated against experimental results obtained from summer and winter long term monitoring campaigns of the flat located in the Marrakech city, Morocco. The apartment’s heating and cooling loads as well as thermal discomfort indexes are calculated for the possible eleven configurations combining the studied parameters. The results show that high thermal insulation of the walls leads to an apparent summer overheating with an increase in the flat’s total thermal load by up to 18% in all the considered climates, except for the cold one. It was found that the walls’ light thermal insulation resulting from the cavity wall technique is sufficient to reach an acceptable level of thermal comfort thus preventing summer overheating. Similarly, thermal insulation of the slab-on-grade floor was found to perform an increase in thermal load for hot and moderate climates by at least 67%. The best combination of all the studied energy efficiency measures for each climate conditions was evaluated via comparison to a reference case that represents the actual apartment.     

Structural and photoluminescence characterization of vertically aligned multiwalled carbon nanotubes coated with ZnO by magnetron sputtering

Zinc oxide (ZnO) nanostructures are very attractive in various optoelectronic applications such as light emitting devices. A fabrication process of these ZnO nanostructures which gives a good crystalline quality and being compatible with that of micro-fabrication has significant importance for practical application. In this work ZnO films with different thicknesses were deposited by RF-sputtering on vertically aligned multiwalled carbon nanotube (MWCNTs) template in order to obtain ZnO nanorods. The obtained hybrid structures (ZnO/MWCNTs) were characterized by scanning electron microscopy, X-ray diffraction, transmission electron microscopy, and time resolved photoluminescence spectroscopy (PL). Results show that the ZnO/MWCNTs have a nanorod structure like morphology with a good crystalline quality of the deposited ZnO on the MWCNTs. PL measurements reveal an enhancement of the band edge signal of ZnO/MWCNTs which is three times of magnitude higher compared to the ZnO film deposited on silicon. Moreover, the intensity enhancement varies as function of the ZnO thickness. Such hybrid structures are promising for optoelectronic application, such as blue-violet sources.     

A vibrational study of phase transitions in Fe2P2O7 and Cr2P2O7 under high‐pressures

The vibrational properties of synthetic iron diphosphate (Fe₂P₂O₇) and chromium diphosphate (Cr₂P₂O₇) are studied under high‐pressure conditions between ~22 and ~30 GPa, respectively. Each compound's structural response to pressure and pressure‐induced phase transitions are characterized. The chromium‐bearing sample shows coalescence of infrared bands occurring near 6 and 17 GPa: these may be associated with increases in the local symmetry of the P₂O₇ group. The iron sample undergoes a first‐order phase transition near ~9 GPa, and a possible phase transition near 5.5 GPa. At 9 GPa, the initially single, strong symmetric PO₄ stretching mode splits into four modes, and the sole asymmetric PO₄ stretching mode splits into two bands. These changes indicate the presence of multiple tetrahedral environments within a larger volume unit cell, and the relative frequencies of the split vibrations indicate a P₂O₇ environment with a markedly narrowed P–O–P angle. The difference between the behavior of the iron and chromium compounds is probably generated by the smaller iron ion producing a discontinuous decrease in the P–O–P angle at lower pressures than in the analogous chromium compound. Our results demonstrate that the dimerized P₂O₇ group remains stable under compression to over 20‐30 GPa at 300 K.     

Dynamic resource allocation with beamforming for MIMO OFDM systems: performance and effects of imperfect CSI

We propose three different dynamic resource allocation algorithms using adaptive beamforming for multiple-input multiple-output (MIMO) OFDM systems, and investigate their performance over multipath fading channels under perfect and imperfect channel state information (CSI). These approaches involve the use of adaptive modulation, adaptive frequency-domain power allocation, and/or adaptive sub-channel allocation. By employing the proposed approaches in MIMO/OFDM systems, significant performance improvement can be achieved compared to the conventional adaptive antenna array based OFDM. The investigation of the effects of imperfect CSI reveals that the adaptive-modulation based approach is too sensitive to channel estimation errors, and that its performance is worse than the adaptive frequency-domain power allocation and/or adaptive sub-channel allocation approaches. The performance analysis also shows that combining adaptive power allocation with sub-channel allocation yields the best performance under imperfect CSI while being robust to channel estimation errors.     

Maintaining high vitamin A supplementation coverage in children: lessons from Niger

In 1997, the reduction of child mortality became a policy priority for the Government of Niger because Niger's child mortality rate was the highest in the world. The Ministry of Public Health, Helen Keller International (HKI), and UNICEF spearheaded a coalition-building process linking vitamin A deficiency (VAD) control to national child survival goals. An evidence-based advocacy strategy was developed around the child survival benefits of adequate and sustained VAD control with one unambiguous message: "VAD control can avert over 25,000 child deaths per year." As a result, in 1997 Niger became one of the first countries in Africa to effectively integrate vitamin A supplementation into National Immunization Days (NIDs) for polio eradication. The challenge was then to provide children with a second annual dose of vitamin A. This led in 1999 to the first ever National Micronutrient Days (NMDs) in Africa. NMDs are mobilization campaigns in which caregivers are actively encouraged to take their children for the delivery of vitamin A supplements. Since 1999, the combination of NIDs and NMDs has ensured that over 80% of children 6 to 59 months of age receive two vitamin A doses annually. The success of NIDs/NMDs has relied on five pillars: leadership and ownership by the Ministry of Public Health; district-level planning and implementation; effective training and flexible delivery mechanisms; effective social information, communication, and mobilization; and responsiveness and flexibility of Ministry of Public Health and development partners. This successful approach has been widely disseminated, notably through the West African Nutrition Focal Points Network.     

Ultrasound-Assisted Aromatisation with Condiments as an Enabling Technique for Olive Oil Flavouring and Shelf Life Enhancement

Olive oil flavour represents the most important factor that influences customer’s perception for quality. In this study, an innovative aromatisation approach that enhanced quality and shelf life of olive oil is tested by means of in situ ultrasound-assisted extraction of Carum carvi L. seeds in olive oil. After the flavouring process, carvone and limonene, representing 99 % of caraway essential oil, were identified in virgin olive oil as revealed by headspace solid-phase microextraction gas chromatograph coupled to mass spectrometer (HS-SPME gas chromatograph (GC)/mass spectrometer (MS)) analyses. Furthermore, kinetic studies indicate that flavouring rate in ultrasound-assisted system is faster than conventional aromatisation producing very stable aromatised oil with no changes in quality. This fact is attributed to ultrasound contribution to mass transfer intensification of essential oil components from seeds to the bulk medium, confirmed by scanning electron micrograph (SEM) micrographs in which cell damage and exudation of its main content are illustrated. However, it is important to note that ultrasound-treated samples produce higher degrees of conjugated dienes and conjugated trienes compared to conventional maceration. Nevertheless, this increase is not alarming and remains within permitted values of the European Community and the International Olive Oil Council (IOOC). Ultrasound-flavouring system stands as a fast alternative aromatisation method, which allows on top shelf life enhancement and olive oil quality preservation.     

Techno-economic analysis and modelling of a remote photovoltaic water pumping system in the desert of Tunisia

For estimating the performance of a photovoltaic (PV) water pumping system without battery storage, a simple algorithm has been developed. This simulation program uses the hourly global solar radiation, the hourly ambient temperature and the hourly wind speed as the input, moreover the characteristics of region (latitude, longitude, ground albedo) and characteristics of PV water pumping system (orientation, inclination, nominal PV module efficiency, NOCT, PV array area, PV temperature coefficient, miscellaneous power conditioning losses, miscellaneous PV array losses, temperature of reference, moto-pump efficiency and inverter efficiency). This work allows evaluating the economic interest of a remote PV water pumping systems in the desert of Southern Tunisia, which will have to satisfy an average daily volume of 45 m³ throughout the year compared to another very widespread energy system in the area, the diesel genset (DG), by using the method of the life-cycle cost (LCC). The cost per m³ of water was calculated for this system. It is found that the LCC for PV system is 0.500 TND/m³ and the LCC DG is 0.837 TND/m³. The present study indicates economic viability of PV water pumping systems in the desert of Tunisia.