Evaluation of Flexural Behavior and Serviceability Performance of Concrete Beams Reinforced with FRP Bars

Flexural behavior and serviceability performance of 24 full-scale concrete beams reinforced with carbon-, glass-, and aramid-fiber-reinforced-polymer (FRP) bars are investigated. The beams were 3,300?mm long with a rectangular cross section of 200?mm in width and 300?mm in depth. Sixteen beams were reinforced with carbon-FRP bars, four beams were reinforced with glass-FRP bars, two beams were reinforced with aramid-FRP bars, and two were reinforced with steel, serving as control specimens. Two types of FRP bars with different surface textures were considered: sand-coated bars and ribbed-deformed bars. The beams were tested to failure in four-point bending over a clear span of 2,750?mm. The test results are reported in terms of deflection, crack-width, strains in concrete and reinforcement, flexural capacity, and mode of failure. The experimental results were compared to the available design codes.     

Thermal stability of corn oil flavoured with Thymus capitatus under heating and deep-frying conditions

BACKGROUND: The thermal stability of corn oil flavoured with thyme flowers was determined and compared with that of the original refined corn oil (control). The oxidative stability index (OSI) was measured and samples were exposed to heating (30 min at 150, 180 and 200 °C) and deep‐frying (180 °C). Changes in peroxide value (PV), free fatty acid (FFA) content, specific absorptivity values (K₂₃₂ and K₂₇₀), colour and chlorophyll, carotenoid and total phenol contents were monitored. RESULTS: The OSI and heating results showed that thyme incorporation was effective against thermal oxidation based on the increased induction time observed for the flavoured oil (6.48 vs 4.36 h), which was characterised by lower PV, FFA content, K₂₃₂ and K₂₇₀ than the control oil after heating from 25 to 200 °C, with higher red and yellow colour intensities and chlorophyll, carotenoid and total phenol contents. The deep‐frying test showed the accelerated deterioration of both oils in the presence of French fries. CONCLUSION: Compared with the control oil, the thyme‐flavoured oil showed improved thermal stability after heating. This could be attributed to the presence of thyme pigments and antioxidant compounds allowing extended oil thermal resistance. Copyright © 2011 Society of Chemical Industry     

Model‐based design of a plant‐wide control strategy for a continuous pharmaceutical plant

The design of an effective plant‐wide control strategy is a key challenge for the development of future continuous pharmaceutical processes. This article presents a case study for the design of a plant‐wide control structure for a system inspired by an end‐to‐end continuous pharmaceutical pilot plant. A hierarchical decomposition strategy is used to classify control objectives. A plant‐wide dynamic model of the process is used to generate parametric sensitivities, which provide a basis for the synthesis of control loops. Simulations for selected disturbances illustrate that the critical quality attributes (CQAs) of the final product can be kept close to specification in the presence of significant and persistent disturbances. Furthermore, it is illustrated how selected CQAs of the final product can be brought simultaneously to a new setpoint while maintaining the remaining CQAs at a constant value during this transition. The latter result shows flexibility to control CQAs independently of each other. © 2013 American Institute of Chemical Engineers AIChE J, 59: 3671–3685, 2013     

Co0.5TiOPO4: Crystal structure, magnetic and electrochemical properties

The new titanium oxyphosphate Co_0.5TiPO₅ has been prepared by solid state reaction. Its structure has been determined by single crystal X-ray diffraction and was further investigated by FT-IR spectroscopy and magnetic measurements. The compound crystallizes in the monoclinic system, S.G: P2₁/c [a = 7.358(1) Å, b = 7.378(2) Å, c = 7.383(3) Å, β = 119.66(3)°, Z = 4, R₁ = 0.0142, wR₂ = 0.0429]. The structure can be described as a network of very distorted TiO₆ octahedra, in which the Ti⁴⁺ ions are displaced from the centres of the octahedra, and slightly distorted PO₄ tetrahedra. Half of the octahedral cavities are occupied by Co atoms. The other half of octahedral sites is vacant and favourable for the electrochemical insertion of lithium. The insertion of lithium was studied by galvanostatic charging and discharging between different voltage limits.     

纤维聚合物筋混凝土梁正截面性能的试验研究

进行了 6 2根截面尺寸分别为 130mm× 180mm× 180 0mm、2 0 0mm× 30 0mm× 3 30 0mm、2 0 0mm× 45 0mm× 3 30 0mm和 2 0 0mm× 5 5 0mm× 3 30 0mm的纤维聚合物筋混凝土梁的弯曲试验 ,重点研究了纤维聚合物筋类型、配筋率对梁的裂缝间距、宽度和分布 ,弯曲刚度和挠度、破坏形式和承载能力的影响。     

Sensitive and Reversible Detection of Methanol and Water Vapor by In Situ Electrochemically Grown CuBTC MOFs on Interdigitated Electrodes

The in situ electrochemical growth of Cu benzene‐1,3,5‐tricarboxylate (CuBTC) metal–organic frameworks, as an affinity layer, directly on custom‐fabricated Cu interdigitated electrodes (IDEs) is described, acting as a transducer. Crystalline 5–7 µm thick CuBTC layers are grown on IDEs consisting of 100 electrodes with a width and a gap of both 50 µm and a height of 6–8 µm. These capacitive sensors are exposed to methanol and water vapor at 30 °C. The affinities show to be completely reversible with higher affinity toward water compared to methanol. For exposure to 1000 ppm methanol, a fast response is observed with a capacitance change of 5.57 pF at equilibrium. The capacitance increases in time followed diffusion‐controlled kinetics (k = 2.9 mmol s^?0.5 g^?1_CuBTC). The observed capacitance change with methanol concentration follows a Langmuir adsorption isotherm, with a value for the equilibrium affinity K _e = 174.8 bar^?1. A volume fraction f _MeOH = 0.038 is occupied upon exposure to 1000 ppm of methanol. The thin CuBTC affinity layer on the Cu‐IDEs shows fast, reversible, and sensitive responses to methanol and water vapor, enabling quantitative detection in the range of 100–8000 ppm.     

Performance investigation of a hybrid PV‐diesel power system for remote areas

Algeria is in a region with an enormous potential of solar energy for power generation. However, photovoltaic (PV) power plants have not yet been developed sufficiently in the country, and its applications such as PV pumping, solar distillation, and solar heating. The main problem is the high maintenance, operating costs, fossil‐fuel transportation, and CO₂ emission of Bordj Badji Mokhtar's (BBM's) diesel power plant that exhibits a noteworthy issue in south Algeria. This paper presents the results of a theoretical and experimental study for PV/diesel hybrid energy system (HES) considering the load demand profile and the solar radiation in isolated area of south Algeria. Suggested hybridization based on a renewable energy with a view to an improved environment is promising. Study results show the performance of PV/diesel system based on solar radiation. The experiment load curve in this typical area may conduct the diesel generator to operate at 60% to 70% of its nominal power with less fuel consumption, and it has been verified during this study that the implementation of a PV/diesel hybrid system is efficient for higher load and higher solar radiation. Results and discussions are encouraging considering less emission of greenhouse gases and less storage of fuel, which drives the government to draw a political arrangement for the improvement of cleaner forms of electricity generation.     

Preparation and characterization of nano‐enhanced myristic acid using metal oxide nanoparticles for thermal energy storage

Fatty acids have been broadly used as phase change materials (PCMs) for thermal energy storage. However, low thermal conductivity limits their performances. This paper investigates the influence of metal oxide nanoparticle addition on myristic acid (MA) as nano‐enhanced PCM (NEPCM). Stability, chemical, and thermal properties were considered. Four types of nanoaprticles, TiO₂, CuO, Al₂O₃, and ZnO, were dispersed in MA at 0.1, 0.5, 1, and 2 wt%. Stability and dispersion were checked by sediment photograph capturing and scanning electron microscopy/energy‐dispersive spectroscopy. The Fourier‐transformed infrared (FTIR) and X‐ray diffraction analysis confirmed no chemical interaction between the nanoparticles and MA. The results revealed a ratio of thermal conductivity of 1.50, 1.49, 1.45, and 1.37, respectively, for 2 wt% of ZnO, Al₂O₃, CuO, and TiO₂. The T‐history method confirmed this enhancement. The latent heat thermal energy storage (LHTES) properties of the nano‐enhanced MA were evaluated using differential scanning calorimetry. The latent heat capacities of nano‐enhanced MA samples have dropped between 9.64 and 5.01 % compared with pure MA, and phase change temperature range was not affected significantly. The NEPCM was subjected to 500 thermal cycling, it showed a good thermal reliability as LHTES properties remained unchanged, while FTIR analysis showed similar characteristics compared with uncycled samples, indicating a good chemical stability. Based on the results regarding with the LHTES properties, cycling thermal reliability, and higher thermal conductivity improvement, it can be achieved that the MA/Al₂O₃ (2.0 wt%) and MA/ZnO (2.0 wt%) composites could be better PCMs for solar TES applications.     

NMR study of the cation distribution in the systems Li1+5xTa1−xO3 and Li1+xTa1−xTixO3

A ⁷Li NMR study of members of the solid-solution systems Li_1+5xTa_1?xO₃ and Li_1+xTa_1?xTi_xO₃ has indicated that the excess Li⁺ ions occupy interstitial tetrahedral sites in the former. In the latter system, the Li⁺ ions appear to occupy interstitial tetrahedral sites for small values of x, but mostly octahedral sites for x > 0.1. Defect-cluster models are proposed that rationalize these findings as well as the evolution with x of the ferroelectric Curie temperature.