Combining scanning probe microscopy and x-ray spectroscopy

A new versatile tool, combining Shear Force Microscopy and X-Ray Spectroscopy was designed and constructed to obtain simultaneously surface topography and chemical mapping. Using a sharp optical fiber as microscope probe, it is possible to collect locally the visible luminescence of the sample. Results of tests on ZnO and on ZnWO4 thin layers are in perfect agreement with that obtained with other conventional techniques. Twin images obtained by simultaneous acquisition in near field of surface topography and of local visible light emitted by the sample under X-Ray irradiation in synchrotron environment are shown. Replacing the optical fibre by an X-ray capillary, it is possible to collect local X-ray fluorescence of the sample. Preliminary results on Co-Ti sample analysis are presented.     

Kharasch addition of tetrachloromethane to alkenes catalyzed by metal acetylacetonates

Various transition metal acetylacetonates have proven to be efficient catalytic systems for the Kharasch addition of tetrachloromethane to alkenes under mild conditions, providing 1:1 adducts in up to 87% yield, based on internal standard. The nature of metal, solvent, temperature, olefin/CCl₄ ratio and the presence of nucleophilic co-catalysts were tested to evaluate the scope and limitation of the reaction.     

周期性输入组分和扫气在改善钯膜反应器甲烷部分氧化制氢中的作用(英文)

The partial oxidation of methane under periodic operation over Ni/γ-Al2O3 catalyst was investigated in a Pd-membrane reactor.The effects of key parameters such as the inlet composition and the sweeping gas on methane conversion and the hydrogen recovery are numerically established with two periodic input functions.In order to analyze the effect of the inputs modulation,the reaction was performed under low steam to methane ratio at a moderate temperature and pressure.It was obtained that to achieve process intensification is to operate the process in a periodic way.The main results show that the periodic input functions can improve the performance of the process compared to the optimal steady state operation.Moreover,there is an optimum amplitude of manipulated inputs leads to a maximum of hydrogen recovery.It is noteworthy that the comparison between the predicted performance via the sinusoidal and the square ways show that the better average performance was obtained with the square way.     

Synthetic Co-Attractants of the Aggregation Pheromone of the Date Palm Root Borer <Emphasis Type="Italic">Oryctes agamemnon</Emphasis>

Laboratory and field investigations to identify and evaluate plant co-attractants of the aggregation pheromone of the date palm pest Oryctes agamemnon are reported. Volatiles emitted by freshly cut palm core and palm core with feeding males, were collected, analyzed by gas chromatography coupled to mass spectrometry and evaluated in olfactometers alone or combined with synthetic pheromone. A collection of palm odor without male effluvia was attractive alone and enhanced attraction to synthetic pheromone in an olfactometer similar to that to a collection of palm odor emitted with feeding males and containing natural pheromone. Behavioral responses to collections of palm volatiles were correlated to the amount of volatiles material in them. Enhancement of the attractiveness of the pheromone was not correlated to chemicals specific to beetle feeding. The chemicals common to the active collections extracts were benzoate esters, mostly ethyl benzoate, anisole derivatives and sesquiterpenes. Blends of the most abundant components of the extracts were evaluated for enhancement of the attractiveness of pheromone (1 μg) in olfactometers at 1 or 10 μg doses. The mixtures were further evaluated by field trapping in Tunisia at 3–10 mg/day using reference (6 mg/day) or experimental pheromone formulations. A mixture of ethyl benzoate, 4-methylanisole and farnesol (1:1:1 w/w at 6.5 mg/day) enhanced captures in pheromone baited traps in 2014 and 2015 and this mixture was as active as the natural palm bait. The practical prospect of the result for the management for O. agamemnon, and other palm beetles is discussed.     

Surface and Self-Aggregation Properties of Bis-Benzimidazolones Derivatives of <Emphasis Type=SmallCaps>d</Emphasis>-Glucose

The surface and self-aggregation properties in water of a new series of amphiphilic homologues, bis-benzimidazolone derivatives of d-glucose, were investigated. Parameters such as the maximal surface excess concentration, minimal area per molecule at the interface, and critical micelle concentration (CMC) were found to be significantly dependent on the hydrophobic alkyl chain length. The synthesized compounds form micelles at remarkably low concentrations, and CMCs derived from surface tension measurements show a minimum as a function of the alkyl chain length; this unusual trend can be attributed to the formation of submicellar aggregates in compounds with long alkyl chains, as evidenced from fluorescence probe spectroscopy data. At high surfactant concentrations, lyotropic liquid crystalline phases with hexagonal structure are formed. Small angle X-ray scattering measurements indicate that the characteristic nanoscopic lengths increase with water swelling and alkyl chain length.     

The SemSPM approach: fine integration of WS-SecurityPolicy semantics to enhance matching security policies in SOA

The lack of semantics in WS-SecurityPolicy standard hampers the effectiveness of matching security policies. To resolve this problem, we present a semantic approach for matching Web service security policies. The approach consists in the transformation of WS-SP into an OWL-DL ontology and the definition of a set of rules which automatically generate semantic relations that can exist between the provider and requestor security requirements. We show how these relations lead to more correct and refined matching of security policies. We also describe the implementation details of our approach and its validation through a real-world use case.     

Construction and Testing of an Innovative Concrete Bridge Deck Totally Reinforced with Glass FRP Bars: Val-Alain Bridge on Highway 20 East

The Val-Alain Bridge, located in the Municipality of Val-Alain on Highway 20 East, crosses over Henri River in Québec, Canada. The bridge is a slab-on-girder type with a skew angle of 20° over a single span of 49.89?m and a total width of 12.57?m. The bridge has four simply supported steel girders spaced at 3,145?mm. The deck slab is a 225-mm-thick concrete slab, with semi-integral abutments, continuous over the steel girders with an overhang of 1,570?mm on each side. The concrete deck slab and the bridge barriers were reinforced with glass fiber reinforced polymer (GFRP) reinforcing bars utilizing high-performance concrete. The Val-Alain Bridge is the Canada’s first concrete bridge deck totally reinforced with GFRP reinforcing bars. Using such nonmetallic reinforcement in combination with high-performance concrete leads to an expected service life of more than 75?years. The bridge is well instrumented with electrical resistance strain gauges and fiber-optic sensors at critical locations to record internal strain data. Also, the bridge was tested for service performance using calibrated truckloads. Design concepts, construction details, and results of the first series of live load field tests are presented.     

Changes on essential oil composition of coriander (Coriandrum sativum L.) fruits during three stages of maturity

The essential oils composition of coriander (Coriandrum sativum L.) fruits obtained by hydrodistillation was studied at three stages of maturity by GC–FID and GC–MS. Essential oil yields showed marked increase during maturation process and forty one compounds were identified. Geranyl acetate (46.27%), linalool (10.96%), nerol (1.53%) and neral (1.42%) were the main compounds at the first stage of maturity (immature fruits). At the middle stage, linalool (76.33%), cis-dihydrocarvone (3.21%) and geranyl acetate (2.85%) were reported as the main constituents. Essential oils at the final stage of maturity (mature fruits) consist mainly on linalool (87.54%) and cis-dihydrocarvone (2.36%). Additionally, accumulation of monoterpene alcohols and ketones was observed during maturation process of coriander fruit.     

Overview and investigation of the planned dynamic voltage restorer for autonomous electrical grid: Case of Adrar,south of Algeria

This paper provides an overview and study of diesel power plant (DPP) map, configuration and design in Ain-Belbel Adrar (Situated in south of Algeria) which was constructed as basis to feed the costumers by electricity in this isolated village. Its capacity of electrical production is 5 MW; this power covers the energy demand of customers connected to the electrical distribution network. First, a brief introduction of the evolution of Algeria's electrical energy consumption and power plants installed in the south is presented, followed by studies of theoretical and experimental data. Several experimental works based on simulation and primary data from field measurement are presented to show the performance of the interconnection of Diesel power plant through 15 kV distribution line to improve electrical power supply. In power system voltage sag is considered to be the most common and serious power quality issue, Due to electrical disturbances occurred through autonomous networks such as voltage sags, swells and outages in 15 kV Ain-Belbel city feeder distribution system a dynamic voltage restorer is proposed to diminish the impact of voltage perturbation in this area. DVR should inject the equivalent dropped voltage as a reflection of active power and energy into the distribution system. However, the capability of energy storage is considered how the injection energy can be minimized and the load voltage can be close to the pre-fault voltage.