Study of the preparation of ruthenia based catalytic materials by heating their precursors

Thermal behaviour of hydrous ruthenia (RuO₂·nH₂O) and ruthenia containing 10% titania ((RuO₂)_0.9–(TiO₂)_0.1nH₂O) was characterised on heating in air by emanation thermal analysis (ETA), thermogravimetry (TG), differential thermal analysis (DTA) and evolved gas analysis (EGA). The anhydrous ruthenia and ruthenia containing 10% titania samples were prepared by heating their hydrous precursors at 500°C in air. The temperature intervals of the samples dehydration and crystallisation were determined. XRD, TEM and surface area measurements were also used for the characterisation of the samples. The ETA results, evaluated by a mathematical model, brought about new information about surface area and microstructure development of the intermediate products of the oxides under in situ conditions of the heating in air. A good agreement between ETA and the results of other methods was obtained. The NO_x reduction by CO was used to test the catalytic properties of these samples.     

A study on the crystallization of amorphous arsenic

The results of DTA analysis of amorphous arsenic in combination with electron microscopical study of the samples through the whole temperature range reveal that no changes of the initial state of the sample occur on heating up to crystallization temperature. Close above this temperature the spontaneous crystallization starts. It differs markedly from the case of glassy materials, like As₂Te₃, in which case at temperatures as low as the transition region T_g the crystallization nuclei of geometrically defined shapes appear and grow into crystalline grains on further heating.     

Influence of opposite sex on attraction produced by pioneer sex of four bark beetle species cohabiting pine in the Southern United States

Catches ofDendroctonus frontalis andIps avulsus on traps surrounding bolts infested with both sexes of each species in the gallery were not significantly different from catches at bolts infested only with the sex which normally pioneers the host colonization process. In contrast, the presence of the second sex in the gallery significantly reduced catches ofI. grandicollis andI. calligraphus and, additionally, the presence of females in the male galleries ofI. calligraphus significantly reduced the catch ofI. avulsus females as compared with their response to bolts infested with the maleI. calligraphus only.     

Step-growth polymerization of guanamines with unsaturated aldehydes

Summary In acid medium and at temperatures from 50 to 100°C the resins from three different guanamines and three different unsaturated aldehydes were synthesized. The products were red coloured resins, which were soluble in organic solvents and were able to cure with hexamethylenetetramine to form hard and almost insoluble products. Using a combination of NMR and GPC methods it was possible to predict the course and the mechanism of the reactions. The rates of the reactions depend on the reaction conditions and on the type of the monomer.     

GPU-accelerated DXT and JPEG compression schemes for low-latency network transmissions of HD, 2K,and 4K video

Low-latency transmissions of high resolution video such as HD, 2K, or 4K over both Internet and private IP networks have found a foothold in many interactive applications, ranging from collaborative environments in science and medicine to the arts and entertainment industry. In this paper we demonstrate how the power of commodity graphics processing units can be used for efficient implementation of JPEG and DXT compression. We propose an approach to fine-grained parallelization of JPEG compression and the use of auxiliary indexes for efficient decompression, which are backward compatible with the JPEG standard. In-depth performance analysis is provided to show various aspects of the proposed parallelization including the dependency on image content and on various settings of the compression algorithm, as well as the impact of compression for interactive applications in terms of end-to-end latency. The applicability of these compression schemes in medicine and cinematography has also been evaluated using double-blind ABX tests compared with uncompressed video. We describe selected successful real-world deployment use cases based on our open-source implementation within the UltraGrid framework, such as trans-Atlantic 4K interactive video streaming during the CineGrid 2011 workshop. As discussed in the paper, the proposed approaches to parallelization provide sufficient performance even for the future generation of 8K video processing systems, currently limited by availability of camera and display hardware.     

NICE h : a higher-order explicit numerical scheme for integration of constitutive models in plasticity

The article introduces, as a result of further development of the first-order scheme NICE, a simple and efficient higher-order explicit numerical scheme for the integration of a system of ordinary differential equations which is constrained by an algebraic condition (DAE). The scheme is based on the truncated Taylor expansion of the constraint equation with order h of the scheme being determined by the highest exponent in the truncated Taylor series. The integration scheme thus conceived will be named NICE ^h , considering both principal premises of its construction. In conjunction with a direct solution technique used to solve the boundary value problem, the NICE ^h scheme is very convenient for integrating constitutive models in plasticity. The plasticity models are defined mostly by a system of algebraic and differential equations in which the yield criterion represents the constraint condition. To study the properties of the new integration scheme, which, like the forward-Euler scheme, is characterised by its implementation simplicity due to the explicitness of its formulations, a damage constitutive model (Gurson–Tvergaard–Needleman model) is considered. The general opinion that the implicit backward-Euler scheme is much more accurate than the thus-far known explicit schemes is challenged by the introduction of the NICE ^h scheme. The accuracy of the higher-order explicit scheme in the studied cases is significantly higher than the accuracy of the classical backward-Euler scheme, if we compare them under the condition of a similar CPU time consumption.     

The Conceptual Model of Well-Being Management Based on Achieving Requisite Personal Holism

Organizations should look at humans as multilayered, not only as professional entities. In synergy, not only individually, we define humans as: (1) physical, (2) mental, (3) social, (4) spiritual, and (5) economic entities, marked by requisitely holistic patterns of relatively permanent characteristics, due to which individuals differ from each other; they differ also as specialized professionals. All these and other attributes form synergies. On this basis, the behavior of individuals who are willing to practice interdisciplinary cooperation becomes socially responsible and they have a high level of well-being.

Individuals as well as organizations seek requisite personal holism (RPH) on the one hand and psychic well-being (PWB) on the other hand. Thus, individuals implement individual techniques and organizations implement special strategies, programs, and actions in the frame of human resource management (HRM). That is how organizations in the frame of HRM, more specifically in the frame of management well-being, are developing special programs for managing PWB. These programs are based on their RPH and organizations might help employees to feel respected and valued in their work settings, without regard to their culture, religion, ethnicity, gender, age, disability, or other individual differences. The most-often applied programs of the kind include: (1) stress management programs, (2) diversity management programs, (3) wellness programs, (4) employee assistance programs, and (5) programs for personal growth.