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51.
High‐performance shape‐memory polyurethane block copolymers, prepared with two types of poly(tetramethylene glycol) (PTMG) used as soft segments, were investigated for their mechanical properties. Copolymers with a random or block soft‐segment arrangement had higher stresses at break and elongations at break than those with only one kind of PTMG. Random copolymers with fewer interchain interactions showed higher elongation than block copolymers. All the copolymers had shape‐recovery ratios higher than 80%. In dynamic mechanical testing, the glass‐transition behavior clearly depended on the soft‐segment arrangement: random copolymers had only one glass‐transition peak, whereas block copolymers showed two separate glass‐transition peaks. Overall, the control of the soft‐segment arrangement plays a vital role in the development of high‐performance shape‐memory polyurethane. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2410–2415, 2004 相似文献
52.
Water management plays an important role in obtaining high performance from a polymer electrolyte membrane fuel cell (PEMFC).
To reduce the volume and energy consumption of widely-used bubble humidifiers, membrane humidifiers were fabricated by using
an ultrafiltration (UF) membrane and Nafion membranes. The performance of the membrane humidifiers was examined as a function
of gas flow rate and operating temperature. A single cell was operated using the UF membrane humidifiers exhibiting almost
the same performance with that employing bubble humidifiers. 相似文献
53.
Composite membranes were prepared by grafting plasma-polymerized films onto the surface of nonporous poly (dimethylsiloxane)
films. Gas permeabilities of the composite membranes were measured at 35°C, 1 atm for N2, 02, CO2 and CH4. The permeation properties of the composite membrane was analyzed using the series resistance model. There was a great interfacial
resistance to CH4 permeation through the composite membrane. The interfacial resistance was negligible for the other gases. The interfacial
resistance seems to be a result of an interfacial layer caused by the interaction between the bulk two layers. For CH4 gas, the permeation rate through the composite membrane was affected by the direction of flow. The directional dependence
was negligible for the other gases. 相似文献
54.
Unsaturated polyester (UP)/montmorillonite (MMT) nanocomposite was prepared by using hydroxypropylacrylate (HPA) as a reactive diluent instead of conventional styrene monomer and the effect of polarity of reactive diluent on properties of nanocomposite was investigated. X‐ray and mechanical test data indicated that mixing for an extended period of time is essential to enhance the physical properties of nanocomposites in the UP/Cloisite 6A system. This was attributed to the high polarity of HPA that may disturb the preintercalation of UP resin into the galleries of MMT. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 238–242, 2004 相似文献
55.
Dynamic mechanical properties of three different styrene-based ionomer blends containing ca. 5 mol% of ionic repeat units were investigated; the three ionic units were itaconate (ITANa), methacrylate (MANa), and styrenesulfonate (SNa). For SNa-MANa ionomers, it was observed that this ionomer system showed only two loss tangent peaks, implying that this ionomer system resembles a typical miscible system. When the ion content increased, however, the ionomer blend showed two cluster loss tangent peaks, indicating the presence of phase-separated cluster regions. This suggests that, with increasing ion content, the role of ionic units becomes more important than that of host non-ionic units to determine ionomer properties. In the case of ITANa-MANa and ITANa-SNa ionomers, however, it was suggested that the multiplets of the MANa and SNa ionomers might be disrupted upon the addition of the ITANa ionomers. In addition, the SEM images showed that the fracture surfaces of ionomers changed upon blending. 相似文献
56.
Micron‐sized polymer particles were coated with layers of nickel compounds by plating electrolessly in the presence of aqueous solutions of nickel chloride, sodium hypophosphite, sodium citrate, and ammonium chloride at elevated temperature. The uniform functional polymer particle could be obtained by seeded polymerization. To investigate the effect of surface functionality on the conditions for nickel deposition, the polymer particle was functionalized with the thiol group. From morphological observation, it was found that the mode of nickel deposition was greatly dependent on the surface functionality of the polymer particle. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 420–424, 2003 相似文献
57.
Seung-Min Oh Mark. Cappelli Dong-Wha Park 《Korean Journal of Chemical Engineering》2002,19(5):903-907
Nano-sized silicon carbide (SiC) powder was prepared by thermal plasma process using silicon tetrachloride (SiCl4) and methane (CH4). The synthesized powder was characterized by X-ray diffraction pattern, scanning electron microscopy, transmission electron
microscopy, FT-IR spectroscopy and particle size analyzer. The powder was dominated by β-SiC including some of α-SiC and free
carbon species. The quality of the powder was varied with process conditions such as the molar ratio of H/Si and C/Si, and
collecting positions. It was known that the conversion to SiC was mainly affected by the addition of hydrogen gas because
it promoted the decomposition and reduction of SiCL. CH4 was easily decomposed to carbon species for the formation of SiC as well as removal of impure oxygen, but excessive carbon
suppressed the formation of crystalline SiC and resulted in the solid carbon contamination. The optimum ratio of H/Si was
approx. 26 and that of C/Si was 1.1. For collecting positions, the powder collected at the vessel and filter was preferable
to that at the reaction tube. The average size of the powder synthesized was estimated to be below 100 nm and uniform in distribution. 相似文献
58.
Byoung Chul Kim Hyun Woog Kang Young Han Kim 《Korean Journal of Chemical Engineering》2006,23(5):789-794
A crystallization monitoring system using a quartz crystal oscillator was utilized to predict different shapes of crystal
formation by measuring crystal growth rate and to measure supersaturation. Applying different rates of cooling, crystal formation
of different shapes was induced, and the frequency variation of the oscillator and the crystal shape observed with an SEM
were compared to determine how the frequency variation can be interpreted for the prediction of produced crystal shape. The
experimental results obtained from the crystallization of potassium nitrate and cupric sulfate solutions showed that the proposed
frequency measurement technique could be applied in the prediction of crystal shape of cooling crystallization processes.
In addition, supersaturation was determined from the measurements of solution and coolant temperatures. 相似文献
59.
Han Mo Jeong Shang Hoon Lee Kwang Jae Cho Young Tae Jeong Kap Ku Kang Jae Kwon Oh 《应用聚合物科学杂志》2002,84(9):1709-1715
The block copolymer of poly(1‐hexadecene) (PHD) and polypropylene (PP) was effectively synthesized by the sequential polymerization of propylene and 1‐hexadecene by using highly isospecific TiCl3/Cp2Ti(CH3)2 (Cp = cyclopentadienyl). The block copolymers had two separate melting temperatures of constituent blocks. The modulus of PHD–PP block copolymer was enhanced as the content of sequentially polymerized PP block was increased. The elongation at break showed positive deviation at the intermediate compositions from the simple additive values of constituent homopolymers. Shape memory effect which utilizes the crystalline PHD block as a reversible phase and the crystalline PP block as a fixed structure was examined. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1709–1715, 2002; DOI 10.1002/app.10551 相似文献
60.
Oh Sang-Young Choi Ho-Lim 《International Journal of Control, Automation and Systems》2021,19(2):1151-1157
In this paper, we consider a problem of global stabilization for a class of approximately feedback linearized nonlinear systems. In order to handle more nonlinearity over the existing results, we provide a new feedback controller with two gain-scaling factors and we show that more nonlinearity can be treated by our control scheme. Moreover, we analytically show that the considered nonlinear systems can be stabilized by the proposed controller. Through comparison practical examples, we illustrate the improved features of our proposed control method.
相似文献