Characterisation of K, Na, and Li birnessites prepared by oxidation with H2O2 in a basic medium. Ion exchange properties and study of the calcined products

Birnessites containing Na, K or Li in the interlayer have been prepared by oxidation of Mn(II) cations with H₂O₂ in a basic medium with different alkaline cation/Mn molar ratios. The solids prepared have been characterised by elemental chemical analysis, powder X-ray diffraction, thermal analyses (differential thermal analysis and thermogravimetric analysis), FT-IR spectroscopy and surface texture assessment by adsorption of N₂ at –196°C. Crystalline birnessites are obtained for A/Mn ratios (A = K, Li) larger than 3.4, but MnO(OH) has been also identificed when such a ratio is smaller than 3.4. Ion exchange is topotactic, but is not complete for exchanging Na, K, or Mg for pre-existing Li. The solids are stable up to 400°C, and formation of spinels and solids with tunnel structures is observed at this temperature. Li-containing birnessites are transformed to LiMn₂O₄ spinel at 400°C, and co-crystallization of bixbyte (Mn₂O₃) is observed at higher temperatures. Bixbyte and cryptomelane are formed at 500°C for the K-containing birnessites.     

Fundamentals of oscillator performance

The oscillator is arguably the most essential part of any communication system: it defines a channel frequency, or timing and synchronisation in a digital system. The phase noise of any oscillator has a fundamental lower limit. It limits the achievable efficiency of spectrum use and degrades the error rate in practical applications. Any low-noise oscillator can be described as a positive-feedback Q-multiplier circuit. Such a model shows that phase noise is minimised if the square of the effective circuit Q and the signal-to-noise ratio in the oscillator are maximised. This simple fact is true for all oscillators and it provides the basis for more efficient and lower noise designs     

Effect of exponentially graded base doping on the performance ofGaAs/AlGaAs heterojunction bipolar transistors

The authors have fabricated n-p-n GaAs/AlGaAs heterojunction bipolar transistors (HBTs) with base doping graded exponentially from 5×10¹⁹ cm^-3 at the emitter edge to 5×10¹⁸ cm^-3 at the collector edge. The built-in field due to the exponentially graded doping profile significantly reduces base transit time, despite bandgap narrowing associated with high base doping. Compared to devices with the same base thickness and uniform base doping of 1×10¹⁹ cm^-3 , the cutoff frequency is increased from 22 to 31 GHz and maximum frequency of oscillation is increased from 40 to 58 GHz. Exponentially graded base doping also results ill consistently higher common-emitter current gain than uniform base doping, even though the Gummel number is twice as high and the base resistance is reduced by 40%     

Cyclostationary crosstalk suppression by decision feedbackequalization on digital subscriber loops

Interference from digital signals in multipair cables has been shown to be cyclostationary under some conditions. This work evaluates the performance of a decision feedback equalizer (DFE) in the presence of cyclostationary interference (CI), intersymbol interference (ISI), and additive white noise (AWN). A comparison between a DFE with CI and one with stationary interference (SI) shows the ability of the DFE to substantially suppress CI. Fractionally spaced and symbol-rate DFE equalizers are also compared and the former is found to yield better performance, especially in the presence of CI. The use of a symbol-rate DFE using an adaptive timing technique that finds the receiver's best sampling phase is proposed for when the fractionally spaced DFE cannot be used because of its complexity. The results also demonstrate the potential benefits of synchronizing central office transmitter clocks, if a fractionally spaced DFE is used at the receiver     

Long-wavelength infrared photoinduced switching of a resonanttunneling diode using the intersubband transition

Voltage switching induced by long-wavelength infrared light from a CO₂ laser was observed using a double-barrier resonant tunneling diode (RTD) biased in the bistable region and the intersubband transition (IT) between the quantum confined states. Possible optoelectronic and all-optical switching applications involving hysteresis are proposed and discussed     

The integrated academic information management system at Columbia-Presbyterian Medical Center.

Over the past seven years, Columbia-Presbyterian Medical Center has been planning and implementing an integrated academic information management system. Accomplishments to date include establishing an institutional information architecture, installing a campus-wide network of workstations, recruiting the staff needed to develop and implement the system, and developing various applications. This paper presents the rationale and steps involved in these accomplishments, as well as data on use of the system so far.     

Two-electrode DFB laser filter used as a wide tunable narrow-bandFM receiver: tuning analysis, characteristics and experimental FSK-WDMsystem

Characteristics of a two-electrode DFB laser filter are studied both theoretically and experimentally. Using a matrix analysis of spontaneous emission, a continuous tuning range of 6.7 Å is achieved by changing both net field gains of the two electrodes. A total discontinuous tuning range of over 10 nm comprising alternating mode jumps and continuous tuning range of 4 Å are measured experimentally. The laser filter presents a FWHM bandwidth of 5 GHz which depends on the optical input power. In addition, it is demonstrated that a DFB laser filter can act as a frequency discriminator/photodetector, i.e., a narrow-band FM receiver, with a uniform bandwidth of 1.5 GHz. Using the two-electrode DFB laser for both transmitter and receiver, a two-channel FSK-WDM transmission system utilizing the discontinuous tuning range is reported. The advantage of such a device is the simplicity as compared to the heterodyne technique     

Working memory and work with memory: visual-spatial and further components of processing

Empirical and theoretical evidence for the concept of working memory is considered. We argue that the major weakness of this concept is its loose connection with the knowledge about background perceptive and cognitive processes. Results of two relevant experiments are provided. The first study demonstrated the classical chunking effect in a speeded visual search and comparison task, the proper domain of a large-capacity very short term sensory store. Our second study was a kind of extended levels-of-processing experiment. We attempted to manipulate visual, phonological, and (different) executive components of long-term memory in the hope of finding some systematic relationships between these forms of processing. Indeed, the results demonstrated a high degree of systematicity without any apparent need for a concept such as working memory for the explanation. Accordingly, the place for working memory is at all the interfaces where our metacognitive strategies interfere with mostly domain-specific cognitive mechanisms. Working memory is simply our work with memory.