Hole Transport Materials Based on 6,12‐Dihydroindeno[1,2‐b]fluorine with Different Periphery Groups: A New Strategy for Dopant‐Free Perovskite Solar Cells

Although several hole‐transporting materials (HTMs) have been designed to obtain perovskite solar cells (PSCs) devices with high performance, the dopant‐free HTMs for efficient and stable PSCs remain rare. Herein, a rigid planar 6,12‐dihydroindeno[1,2‐b]fluorine (IDF) core with different numbers of bulky periphery groups to construct dopant‐free HTMs of IDF‐SFXPh, IDF‐DiDPA, and IDF‐TeDPA is modified. Thanks to the contributions of the planar IDF core and the twisted SFX periphery groups, the dopant‐free IDF‐SFXPh‐based PSCs device achieves a device performance of 17.6%, comparable to the doped 2,2′,7,7′‐tetrakis(N,N‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD)‐based device (17.6%), with much enhanced device stability under glovebox and ambient conditions.     

集散控制火灾 报警控制系统

探讨了国内目前火灾自动报警系统中存在的问题,提出应用集散控制理论,构成新一代火灾自动报警控制系统.     

Topological‐Structure Modulated Polymer Nanocomposites Exhibiting Highly Enhanced Dielectric Strength and Energy Density

Dielectric materials with high electric energy densities and low dielectric losses are of critical importance in a number of applications in modern electronic and electrical power systems. An organic–inorganic 0–3 nanocomposite, in which nanoparticles (0‐dimensional) are embedded in a 3‐dimensionally connected polymer matrix, has the potential to combine the high breakdown strength and low dielectric loss of the polymer with the high dielectric constant of the ceramic fillers, representing a promising approach to realize high energy densities. However, one significant drawback of the composites explored up to now is that the increased dielectric constant of the composites is at the expense of the breakdown strength, limiting the energy density and dielectric reliability. In this study, by expanding the traditional 0–3 nanocomposite approach to a multilayered structure which combines the complementary properties of the constituent layers, one can realize both greater dielectric displacement and a higher breakdown field than that of the polymer matrix. In a typical 3‐layer structure, for example, a central nanocomposite layer of higher breakdown strength is introduced to substantially improve the overall breakdown strength of the multilayer‐structured composite film, and the outer composite layers filled with large amount of high dielectric constant nanofillers can then be polarized up to higher electric fields, hence enhancing the electric displacement. As a result, the topological‐structure modulated nanocomposites, with an optimally tailored nanomorphology and composite structure, yield a discharged energy density of 10 J/cm³ with a dielectric breakdown strength of 450 kV mm^–1, much higher than those reported from all earlier studies of nanocomposites.     

基于能量中心的电力机车接触导线几何参数视觉检测方法

传统的电力机车接触导线几何参数检测方法存在若干不足。根据检测要求和磨损后接触线的图像特征,提出了基于双目视觉技术的在线、非接触、多参数综合测量方法。对基于LOG 算子的线条边缘图像处理方法的误差进行了深入的理论分析,在此基础上提出了采用图像能量中心算法的边缘定位新方法,并进行了数值模拟。仿真结果表明:能量中心算法的抗干扰和抗模糊能力更强,定位精度更高。以不同高度、拉出值和磨损宽度的圆钢为检测对象进行了验证实验,并与激光测距仪和数显式游标卡尺检测的结果进行了比对。实验表明,能量中心算法的边缘检测精度优于LOG 算法,同时,提出的测量方法示值误差小、重复性较好,能够满足接触线在线、非接触综合检测的需要。     

激光横风测量技术的研究

基于激光在湍流大气中的光强闪烁现象搭建了一套横风测量系统,并提出了一种趋势匹配算法.对拟合后激光回波信号的趋势序列进行匹配,计算两束回波信号的相关时间时延,并反演出整条路径上的合成风速.用该系统与标准测风雷达分别对117、225、485m的目标路径进行同步测量,实验结果表明,两台设备的测量数据具有较好的一致性,相关系数...     

基于CNN特征的宽频段智能测向方法

当前电磁环境日益复杂,利用机器学习方法实现快速且精确的宽频段无线电测向逐渐成为研究的热点。使用卷积神经网络基于端到端的方式完成宽频段测向的方法能够在一定程度上解决宽频段相位模糊的问题,但卷积运算后特征维数大大增加,稀疏的特征影响了最后一层全连接前馈神经网络的分类效果。针对这一问题,提出将无线电测向分为特征学习任务和方向预测任务,使用卷积神经网络作为特征提取器,将通过多层卷积运算得到的结果视为二次提取的特征,作为方向预测任务的输入;针对二次提取特征的稀疏性,提出使用主成分分析算法对特征进行降维,并将稀疏性降低后的特征作为后续分类器的输入。此外,针对特征的特点,探索了几种分类模型作为分类器的效果,包括决策树、随机森林、径向基函数神经网络和K-近邻。实验结果表明,使用主成分分析算法对特征进行降维能够提升训练和测试效率;采用K-近邻构成分类器的准确度明显高于原卷积神经网络的准确度;若需要兼顾准确度和测向效率,采用随机森林构成分类器的效果最好。     

Engineering Bioactive M2 Macrophage-Polarized Anti-Inflammatory,Antioxidant, and Antibacterial Scaffolds for Rapid Angiogenesis and Diabetic Wound Repair

Diabetic wound healing still faces great challenges due to the excessive inflammation, easy infection, and impaired angiogenesis in wound beds. The immunoregulation of macrophages polarization toward M2 phenotype that facilitates the transition from inflammation to proliferation phase has been proved to be an effective way to improve diabetic wound healing. Herein, an M2 phenotype-enabled anti-inflammatory, antioxidant, and antibacterial conductive hydrogel scaffolds (GDFE) for producing rapid angiogenesis and diabetic wound repair are reported. The GDFE scaffolds are fabricated facilely through the dynamic crosslinking between polypeptide and polydopamine and graphene oxide. The GDFE scaffolds possess thermosensitivity, self-healing behavior, injectability, broad-spectrum antibacterial activity, antioxidant and anti-inflammatory ability, and electronic conductivity. GDFE effectively activates the polarization of macrophages toward M2 phenotype and significantly promotes the proliferation of dermal fibroblasts, the migration, and in vitro angiogenesis of endothelial cells through paracrine mechanisms. The in vivo results from a full-thickness diabetic wound model demonstrate that GDFE can rapidly promote the diabetic wound repair and skin regeneration, through fast anti-inflammation and angiogenesis and M2 macrophage polarization. This study provides highly efficient strategy for treating diabetic wound repair through designing the M2 polarization-enabled anti-inflammatory, antioxidant, and antibacterial bioactive materials.     

一种改进的安全访问控制矩阵模型

操作系统安全保密的核心是访问控制。基本访问控制矩阵作为一种数学模型,在许多实际系统的访问控制中得到了应用,但是它不能满足对安全性有特殊要求的操作系统。本文在基本访问控制矩阵的基础上加上了访问条件,提出了一种三维访问控制矩阵;并且就主体和客体按访问条件的分类对这种矩阵的简化提出了一些看法。作为上述观点的实际例子,本文还介绍了一种非接触式IC卡的访问控制机制。     

九江长江干流江岸赤心堤段高压喷射灌浆施工

介绍了江西省九江长江干流江岸赤心堤段高压喷射灌浆设计与施工,并对高喷灌浆效果进行了评价,分析资料表明高喷灌浆达到了预期的良好效果,所采用的施工工艺合适可行。     

充填料浆的预脱水试验研究

通过理论分析和实验研究 ,首创并试验了多孔管滤网振动预脱水和分流沉降预脱水新技术 ,实现充填料浆的低浓度输送、高浓度充填。