Binary integer programming formulations for scheduling in market-driven foundries

This paper describes the development and solution of binary integer formulations for production scheduling problems in market-driven foundries. This industrial sector is comprised of small and mid-sized companies with little or no automation, working with diversified production, involving several different metal alloy specifications in small tailor-made product lots. The characteristics and constraints involved in a typical production environment at these industries challenge the formulation of mathematical programming models that can be computationally solved when considering real applications. However, despite the interest on the part of these industries in counting on effective methods for production scheduling, there are few studies available on the subject. The computational tests prove the robustness and feasibility of proposed models in situations analogous to those found in production scheduling at the analyzed industrial sector.     

Anti-inflammatory activity of American yam Dioscorea trifida L.f. in food allergy induced by ovalbumin in mice

Tropical ecosystems are particularly rich in edible plant species with different bioactive substances. Among the plants with promising benefits for health are species from the genus Dioscorea (Dioscoreaceae), especially those named yam. Recent studies have shown the beneficial effects of different species of Dioscorea, and its main constituent, diosgenine, in the treatment of food allergy. In this study we evaluated the potential of D. trifida, the only yam native from South America, in the treatment of ovalbumin (OVA) induced food allergy in Balb/c mice. HPLC/DAD analysis showed the presence of three very distinctive groups of natural products in extracts and fractions: (I) very polar substances, including allantoin, (II) phenolic substances as flavonoids and phenolic acids and (III) diosgenin and derivatives. Sensitive mice received casein feed with supplementation of crude extract (CE) and fractions. The supplementation with all products from D. trifida reduced IGE, intestinal oedema and mucus production, parameters observed in OVA allergic mice. The results showed the potential of this food to prevent or treat this disease and the necessity to be better explored.     

Benzodioxoles as alternative coinitiators for radical polymerization in a model‐dental adhesive resin

This study evaluated the effectiveness of benzodioxole derivatives as coinitiators of radical polymerization in a model‐dental adhesive resin. To compose the adhesive resin, a monomer mixture based on 50 wt % of Bis‐GMA, 25 wt % of TEGDMA, and 25 wt % of HEMA was used. Camphorquinone (CQ) 1 mol % was used as a photoinitiator to initiate polymerization. 1,3‐Benzodioxole (BDO) and piperonyl alcohol (PA) were used as coinitiators at 0.25, 0.5, 1, 2, 4, 8, and 16 mol % level. In addition, tertiary amine, ethyl 4‐dimethylamino benzoate (EDAB) was used as coinitiator in the control group. Some physical, chemical, and mechanical properties of the polymer formed in the experimental adhesives were evaluated using the kinetics of polymerization, sorption and solubility, flexural strength, and elastic modulus tests. The results indicated that BDO and PA were effective coinitiators in the photoinitiator system based on CQ. Comparisons between the benzodioxoles derivative coinitiators and EDAB showed similar performance in the kinetics of polymerization and flexural strength. For water sorption and solubility evaluation, BDO and PA demonstrated significantly more sorption of water and less solubility than the EDAB control group. The findings suggest that BDO and PA were feasible alternatives to conventional amine as coinitiator. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Video mediated social interaction between groups: System requirements and technology challenges

This paper discusses results from research related to the use of television as a device that supports social interaction between close-knit groups in settings that include more than two locations, each location being potentially equipped with more than one camera. The paper introduces the notion of a framing experience, as a specific scenario or situation within which social communication takes place. It reports on the evaluation of some of the key attributes of social communication through semi-structured interviews, with 16 families across four European countries. The inferences drawn from this study are reduced to four system capabilities including the ability to support: excitement, engagement and entertainment; high quality, reliable audiovisual communications; flexibility and adaptability sufficient to support the unpredictable and reactive nature of human interaction and discourse. These system requirements are, in turn, reduced to a number of technology challenges which if solved will help enable effective social communications between groups, mediated by the television. These technology challenges include: high quality reliable audio visual communication; interaction orchestration, multimedia interpretation and multimedia composition. Finally the paper reflects on the impact the use of framing experiences, such as those described here, could have on strategy and policy for service providers and regulators.     

Catalytic activity evaluation for hydrogen production via autothermal reforming of methane

A nickel catalyst (5.75 wt.%) supported on gamma-alumina was evaluated through autothermal reforming of methane (ATR). The reforming process was pointed to hydrogen production, following thermodynamic and stoichiometric predictions. The catalyst was characterised by several methods including atomic absorption spectroscopy (AAS), B.E.T.-N₂, X-ray diffraction (XRD), scanning electron microscope (SEM) and thermal analyses (thermogravimetry, TG; derivate thermogravimetry, DTG; and differential thermal analysis, DTA). Experimental evaluations in a fixed-bed reactor (1023–1123 K, 1.00 bar, 150–400 cm³/min feed) presented methane conversions in the range of 40–65%. The effluent mixtures provided hydrogen yields in the range of 78–84%, carbon monoxide 3–14%, and carbon dioxide 5–18%. High molar H₂/CO ratios, ranging from 8 to 90, were obtained. Operating autothermal conditions (excess of steam, 1023–1123 K, 1.00 bar) provided low coke formation and high hydrogen selectivity (81%) for methane reforming.     

Amplitude estimation for near‐sinusoidal oscillators by using a modified Barkhausen criterion

By using an approach based on the Taylor/Volterra series, nonlinear amplifier characteristics can be introduced into the Barkhausen criterion in order to estimate the amplitude for near‐sinusoidal oscillators. The characteristic equation is similar to the 1^st‐order determining equation obtained by Chua. This new method includes all desirable features of Chua's equation and lets us generalize the linear approach directly to a nonlinear one without losing the mathematical simplicity of the Barkhausen criterion. It also allows us to determine the oscillation amplitude with a desired accuracy. Moreover, this method investigates the influence of the feedback factor and the voltage supply on the oscillation amplitude. Employing only the 3^rd‐order nonlinearity of the amplifying element, the amplitude of the oscillation predicted by the modified Barkhausen criterion was compared to the one estimated using the transient analysis of SPICE, the harmonic balance analysis of Serenade, and by measurements. The amplitudes obtained by these four approaches for several feedback factors and supply voltages are in good agreement. © 2005 Wiley Periodicals, Inc. Int J RF and Microwave CAE, 2005.     

Electrochemical reactions of lithium with Li2ZnGe and Li2ZnSi

Electrochemical reactions of lithium with cubic α-Li₂ZnGe and with hexagonal Li₂ZnSi have been studied. Charging a Li/α-Li₂ZnGe battery results in lithium extraction to yield a Li_1.2ZnGe composition, through a first step at ca. 0.9 V that involves a phase transition from cubic to hexagonal, and a second step at ca. 1.1 V where Ge and Zn segregation is observed. By discharge of the Li/α-Li₂ZnGe battery, the composition Li₃ZnGe is reached at 0.2 V while the cubic structure is maintained. Lithium insertion into Li₂ZnSi preserves the hexagonal structure, but lithium extraction modifies the X-ray diffraction pattern.