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The spectrum modification technique is a digital procedure for placing the spectrum of any band-limited signal-analog or digital within an arbitrarily chosen set of (nonoverlapping) frequency intervals, the sum of whose lengths is not less than the original bandwidth of the signal. Because it can serve the function of several digital techniques, such as mixing, interpolating, and decimating, and can he realized in a finite impulse response (FIR) filter form, it may be suitably implemented by a programmable FIR filter having a flexible timing scheme. The technique is more computationally efficient for many of its applications than the conventional algorithms it replaces. In the application for which it was developed, it replaced a mixer and the concomitant filtering required to shift a signal spectrum a fraction of its bandwidth and cut the computational rate an order of magnitude.  相似文献   
23.
Herein we describe a new methodology for the asymmetric hydrogenation (AH) of 2‐substituted pyridinium salts. An iridium catalyst based on a mixture of a chiral monodentate phosphoramidite and an achiral phosphine was shown to hydrogenate N‐benzyl‐2‐arylpyiridinium bromides to the corresponding N‐benzyl‐2‐arylpiperidines with full conversion and good enantioselectivity. The mechanism of the reaction under optimized conditions was investigated via kinetic measurements and isotopic labeling experiments. Our study suggests that the hydrogenation starts with a 1,4‐hydride addition and that the enantiodiscriminating step involves the reduction of an iminium intermediate.

  相似文献   

24.
This paper focuses on the development of biomimetic sensory abilities for an undulatory soft-body lamprey-like robot, which has been designed to replicate the locomotion mechanisms of living lamprey in order to address useful applications wherever locomotion in unstructured environments is required. The compliant sensory elements are piezo-resistive and made from compliant material called a quantum tunneling composite by mixing micro/nano carbon black particles into a highly soft silicone rubber matrix. The relationship of the composite strip between piezo-resistivity and mechanical strain is investigated by a universal strain–stress tensiometer through resistivity monitoring. Increasing and decreasing resitivity both appears during elongation and retraction, suggesting that piezo-resistivity in the composite material is governed by both percolation theory and quantum tunneling effects. Dynamic tests on the bench shows that the compliant stretch receptor is able to follow the stimulations under fairly wide frequency ranges, exceeding initial estimations. In addition, the compliant artificial stretch receptor has enough sensitivity to detect the local actuations and the actions generated by neighboring actuators in the segmented robotic structure. Finally, the experiments on biomimetic cilia-based cupula receptor show that a low cost flexible/compliant biomimetic sensor is able to detect medium fluidic speeds ranging from 0.05 m/s to 0.6 m/s.  相似文献   
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The first results of a new method for real-time shape acquisition with a laser scanner are presented. The new method is essentially based on the use of a laser beam and a web-cam. A digital filter parameters identification was studied for the laser line detection in the image. After this, a model for the reconstruction in real-time of the laser line in the space was developed. The first test rig was just conceived to validate the method; hence, no high resolution cameras were adopted. Nevertheless, the tests have showed encouraging results.  相似文献   
27.
This paper is focused on the use of data acquisition boards (DAQs) for the development of high accuracy PC-based instruments for the measurements of electrical power. The proposed systems are simple, portable and low cost because they are based on commercial data acquisition boards (DAQs) connected to a common personal computer. Data processing is carried out by a commercial software based on an interpolating windowed FFT. In the paper it is shown how the voltage can be sensed directly, thanks to the DAQ input range, thus avoiding expensive voltage dividers. The set up of the DAQs-based solutions is described and the evaluation of their metrological features is made by means of a comparison with the Italian power primary standard, which was built at INRIM with a complex solution and expensive with two high precision digital voltmeters.  相似文献   
28.
The scope for diffusion of very low-enthalpy geothermal plants in the Piemonte region of Italy, using groundwater heat pumps (GWHP), was analyzed to check environmental sustainability and the benefits in terms of reducing greenhouse gas emissions from fossil fuels. GWHP implementation seemed particularly suitable to the specific characteristics of the Piemonte plain. An important thick and productive shallow aquifer is present across the entire plain beneath the major energy users and is therefore appropriate for geothermal energy development purposes. The building stock could be adapted to heat pumps in different ways, but objective-oriented policies will be required to reach the best results in terms of environmental benefits.  相似文献   
29.
Differently hydrogenated radio frequency-sputtered a-Si layers have been studied by infrared (IR) spectroscopy as a function of the annealing time at 350°C with the aim to get a deeper understanding of the origin of blisters previously observed by us in a-Si/a-Ge multilayers prepared under the same conditions as the ones applied to the present a-Si layers. The H content varied between 10.8 and 17.6 at.% as measured by elastic recoil detection analysis. IR spectroscopy showed that the concentration of the clustered (Si-H)n groups and of the (Si-H2)n (n ≥ 1) polymers increased at the expense of the Si-H mono-hydrides with increasing annealing time, suggesting that there is a corresponding increase of the volume of micro-voids whose walls are assumed from literature to be decorated by the clustered mono-hydride groups and polymers. At the same time, an increase in the size of surface blisters was observed. Also, with increasing annealing time, the total concentration of bonded H of any type decreases, indicating that H is partially released from its bonds to Si. It is argued that the H released from the (Si-H)n complexes and polymers at the microvoid surfaces form molecular H2 inside the voids, whose size increases upon annealing because of the thermal expansion of the H2 gas, eventually producing plastic surface deformation in the shape of blisters.  相似文献   
30.
This paper presents a single-point method for the identification of prevailing disturbing loads in power systems for both single-phase and three-phase applications downstream or upstream from the metering section. It is based on the simultaneous measurement of three nonactive power quantities, which are based on the IEEE Std. 1459-2000 approach. The proposed method is only based on the separation of the fundamental components from the harmonic content of voltage and current; thus, it does not require any spectral analysis of the voltages and current. In this paper, the formulation of the proposed method and its time-domain implementation are described; moreover, some simulation results are presented and discussed, showing the effectiveness of the method both in the absence and in the presence of the measurement transducers.  相似文献   
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