Edge-to-edge interfaces in Ti?Al modeled with the embedded atom method

The atomistic structure and energies of high-index interphase boundaries are explored using a combination of molecular statics and dynamics simulations with embedded atom potentials. We investigate planar boundaries between the α₂ and γ phases in the Ti−Al system. The class of boundaries considered has a high-index boundary orientation; the orientation relationship between the α₂ and γ phases also is high index, and a set of planes from each phase meet edge to edge at the boundary plane. For the particular case of a boundary that is commensurate in one direction and coincides with a moiré plane given by the so-called “Δg” diffraction condition, the boundary is not structurally singular, but it is energetically stable and does not appear to dissociate into other low-energy configurations. Misfit compensating defects are not observed; misfit in directions other than the commensurate one appears to be distributed uniformly. The boundary energy is evaluated as a function of the orientation of the boundary plane, and the edge-to-edge (moiré) boundary is found to lie in an energy cusp. This article is based on a presentation made in the “Hume-Rothery Symposium on Structure and Diffusional Growth Mechanisms of Irrational Interphase Boundaries,” which occurred during the TMS Winter meeting, March 15–17, 2004, in Charlotte, NC, under the auspices of the TMS Alloy Phases Committee and the co-sponsorship of the TMS-ASM Phase Transformations Committee.     

Effects of alloy additions on the microstructures and tensile properties of cast Co-Cr-Mo alloy used for surgical implants

The composition of the Co-Cr-Mo alloy has been modified by additions of nickel and some trace elements aluminium, titanium and boron. In this paper, the first part of the present study, the effects of alloy additions on the microstructures and tensile properties of the as-cast Co-Cr-Mo alloy are discussed. The effects of alloy additions on the fatigue behaviour of the alloy will be discussed in the second part of the present study. It is found that alloy additions do not seem to result in changes in the nature of the casting structure. A directional, coarse dendritic cast structure is produced in the modified alloys as in the base alloY. However, the alloy additions affect the carbide precipitations and the formation of some fine details of the microstructure such as dislocations, stacking faults and twins produced during the solidification. A considerable improvement in the transient mechanical properties, especially in the tensile ductility, is achieved by modifying the base alloy with alloy additions.     

THEORETICAL STUDY OF A NEW MATERIAL FOR FILTERS: AEROGELS

Aerogels are highly porous materials made by removing the liquid phase of a dilute suspension of solids by taking off the vapor under super-critical temperature and pressure conditions. The aerogel structure has a skeleton of nanometer-size elements forming pores that are tens of nanometers in dimension. In some cases the structure of the aerogel arises from clusters having fractal geometry. The collection efficiency and pressure drop for such material is predicted here from models in the literature. A quality factor is used to compare aerogel material with other filter materials. The quality factor relating gas filtration efficiency with pressure drop is predicted to be unusually high for these materials in comparison with other common fibrous filter media, predicting lower flow resistance for aerogels at equivalent particle collection efficiency levels.     

A finite elastostatic analysis of bimaterial interface cracks

A numerical method is developed to study the bimaterial interface problem in Neo-Hookean materials under plane stress conditions. Comparison is made with the analytical predictions for the asymptotic field of the problem. The range of dominance of the asymptotic solution at different load levels is established and the amplitudes of the crack-tip asymptotic field are related to the far field loading. The numerical model is extended to analyze the experiments conducted on specimens with an edge crack at the interface between two dissimilar Solithane plates that are characterized by Mooney-Rivlin material behavior.

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Résumé On met au point une méthode numérique pour l'étude d'un problème d'interfaces entre deux matériaux néo-Hookiens sollicités en état plan de tension. On compare les résultats avec les prédictions analytiques étabiies pour un champ asymptotique. On établit la gamme dans laquelle la solution asymptotique est dominante, à différents niveaux de charge, et on met en relation l'ampleur du champ asymptotique à l'extrémité de la fissure avec celle du champ de contraintes à une certaine distance. Le modèle numérique est étendu à l'analyse d'essais sur éprouvettes comportant une fissure de bord à l'interface de deux tôles de Solithane caractérisée par un comportement de matériau de Mooney-Rivlin.

     

Admiral John A. B. Dahlgren (1809–1870): His life, times and technical work in U.S. naval ordnance

John Dahlgren served in the U.S. Navy for nearly 35 years, sometimes in a sea-keeping capacity but mostly developing large naval artillery. To-day, his name, when recognised by students of naval ordnance, is associated with teh Dahlgren or ‘soda bottle shaped’ gun of 9 to 11 inch calibre. He designed, developed and lived to see his guns installed aboard warships and used to considerable effect, especially in the American Civil War. However, a nearly indistinguishable external design of gun was developed for the Army by T. J. Rodman, an officer now even less known than Dahlgren and whose researches and contributions are virtually forgotten. This paper and that in Ref. [1] attempt to appreciate (along with other technical questions of the period) the different ways pursued by these men towards the final development of the ‘soda bottle shaped’ gun, though it is a matter still not entirely understood.

Both names are totally omitted from several ‘classic’ books on artillery and this is a grave misfortune. Besides trying to throw factual light on the Dahlgren-Rodman controversy and the priority issue (though not one pursued with acrimony by the men themselves at the time), the paper describes Admiral Dahlgren's general career, the books he wrote, the technical problems he attacked and the problematic ordnance discussions of his day, to which he gave his life.

The work of Dahlgren and Rodman, in particular, saw the elevation of American gun design from the level of mere copying (of early Columbiads in the first decades of the century) to that which compelled attention from, and study by, the super-powers of the day, Great Britain, France and Russia.     

Toughening of Dental Porcelain by Tetragonal ZrO2 Additions

The effect on mechanical behavior of ZrO₂ additions to a dental porcelain was investigated. The ZrO₂ was introduced into the glassy matrix phase of the porcelain by refritting the all-glass porcelain constituent. X-ray diffraction indicated that a sizeable fraction of the ZrO₂ was retained in the tetragonal form after the porcelain was fired. Zirconia additions to the porcelain produced substantial improvements in fracture toughness, strength, and thermal shock resistance.     

Pesticide monitoring programme of the Ministry of Health of Brazil

The structure of the recently introduced Brazilian government programme for monitoring pesticide residues in six major agricultural products is described. Residues found from the analysis of samples of tomatoes and strawberries are discussed in detail. The much greater frequency of detection of pesticide residues, many of which are not approved for use in Brazil, in produce being sold on the domestic market, as opposed to that produced for export, is of major concern. It is perceived that this new monitoring programme will become permanent and be used to underpin enforcement actions that will need to be taken to reduce the numbers of incidents of illegal residues occurring, particularly in fresh fruits and vegetables.     

The wear behaviour of oxide ceramics-A Review

The paper reviews the wear behaviour of oxide ceramics. Wear maps are considered and consequently mild and severe wear are defined. Since the use of ceramics in engineering applications require operation in the mild wear regime, the paper concentrates on mild wear mechanisms, but also considers factors which control the transition to severe wear. Within the mild wear regime, the formation of tribofilms are discussed and the manner in which dislocation activity leads to the wear transition is considered. The wear of so-called ceramic nanocomposites, for which no time dependent wear transition has yet been observed, is considered and the reasons for enhanced performance discussed. The role of transformation toughening in zirconia ceramics is considered in detail, and reasons for the generally poor wear response of these materials defined.     

Production of maraging steel grades and the influence of specified and nonspecified elements for special applications

The material properties of maraging steels are greatly affected by the alloy and inclusion content and hence by the production route. This paper describes various past and current production routes at Böhler Edelstahl GmbH and the effect of these routes on the specified element (alloy) and non-specified element (inclusion) contents. Non-metallic inclusions were investigated by EDX analysis. The effects of various alloying and tramp elements on the material properties are presented as a statistical evaluation of previous melts. Nitrogen solubility was calculated with Thermo–Calc for maraging steel Mat.-No. 1.6354 and the precipitation of nitrides is discussed. A proposal is made for the production of melts with improved properties.