Synthesis of polyurethane elastomers hypercross-linked by partially hydrated polyhydroxylated C60

Utilization of polyhydroxylated C₆₀ (fullerenols) in a condensation reaction with diisocyanated oligo(tetramethylene oxide) led to the successful fabrication of elastomeric poly (urethane-ether) networks. These polymer networks exhibit interesting thermal behavior at low temperatures, improved tensile strength and elongation at ambient temperatures, and enhanced thermal mechanical stability at high temperatures, as compared with those of the parent linear polyurethane analogues; or with the conventional oligo (tetramethylene oxide)-derived polyurethane elastomers cross-linked by trihydroxylated reagents (1,I,1-trismethylol propane) or tetrahydroxylated reagents (pentaerythritol). The presence of a limited quantity of water molecules in the condensation reaction of fullerenols with diisocyanated prepolymers modified the physical properties of the resulting elastomeric products with a notable increase in tensile strength, modulus, and Ts over those of elasotmers prepared under anhydrous conditions. These water molecules contributed effectively to the increase of the number of cross-linking centers during the reaction.     

Fullerene Derivatives Attenuate Bronchoconstriction Induced by Xanthine-Xanthine Oxidase

The intratracheal instillation of xanthine-xanthine oxidase caused a marked decrease in dynamic respiratory compliance, indicating airway constriction. The constriction was significantly attenuated by fullerenol-1, but not by other agents or receptor antagonists.     

Percutaneous balloon pericardiotomy for patients with recurrent pericardial effusion: using a novel double-balloon technique with one long and one short balloon

Percutaneous balloon pericardiotomy is effective and less invasive for the treatment of recurrent pericardial effusion. This study suggests that the double-balloon method with 1 longer and 1 shorter balloon is the procedure of choice for percutaneous balloon pericardiotomy.     

Comparison of calcium phosphate cement mixture and pure calcium hydroxide as direct pulp-capping agents

This review reports the different genetic factors that have been identified either as risk factor for Alzheimer's disease (AD) or directly causing the disease. First are reviewed epidemiological data and biological mechanisms about the apoplipoprotein E gene allele epsilon 4 that is a major risk factor for Alzheimer's disease. The second part describes the mutations responsible for early-onset autosomal dominant AD found in three different genes. The gene located on chromosome 21 encodes the amyloid precusor protein (APP). The presenilin 1 and presenilin 2 genes, located on chromosome 14 and 1 respectively, encode not yet known membrane proteins.     

Quantitation of intrathecal measles virus IgG antibody synthesis rate: subacute sclerosing panencephalitis and multiple sclerosis

A method for quantitating specific anti-viral antibodies in serum and cerebrospinal fluid (CSF) is established using enzyme-linked immunosorbent assay (ELISA). Quantitated antibody levels are used to determine intrathecal specific IgG synthesis rate for the particular antibody. Measles virus was used as a model for validating this quantitative technique: a mutated form of measles virus is a cause of subacute sclerosing panencephalitis (SSPE) and there is a possibility that measles virus is related to the cause of multiple sclerosis (MS). Matched serum and CSF samples were assayed. Concentration of anti-measles IgG was determined and intrathecal measles-specific IgG synthesis rate was calculated. For the SSPE samples, measles-specific IgG synthesis rate was elevated and comprised > 20% of the total intrathecal IgG synthesis rate; these results are consistent with the literature. The ELISA method can be performed routinely, providing a quick, simple, reproducible means of quantitating specific antibody concentrations, with sensitivity greater than 1 nanogram per milliliter. With this method, quantitation of IgG antibodies to any other viral antigen can be reliably and precisely determined.     

Crack tip parameters and elastic-plastic fracture of metals

By using optical displacement-measuring techniques we obtain the crack tip fields in terms of crack tip strain, crack opening angle (COA) and crack tip opening angle (CTOA). Thin plates with different crack configurations made of six elastic-plastic materials with strain hardening exponent ranging from 3 to are studied. We find that the COA resistance curve assumes certain characteristics common to all the materials. The experimental results indicate that the critical value of COA may be used as a fracture toughness parameter for these materials.

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Résumé En utilisant une technique de mesure optique des déplacements, on obtient les champs régnant à l'estrémité d'une entaille, qui s'experiment par la déformation d'extrémité d'entaille, l'angle d'ouverture de la crique (COA et l'angle d'ouverture de la pointe de la crique (CTOA). On étudie des feuillards présentant différentes configurations de fissures et réalisés en six matériaux élasto-plastiques dont les modules d'écrouissage s'échelonnent de 3 à l'infini.On trouve que la courbe de résistance COA suppose certaines caractéristiques communes à tous les matériaux. Les résultats expérimentaux indiquent que la valeur critique du COA peut être utilisée comme paramètre de ténacité à la rupture pour les matériaux étudiés.

     

Exploring latent browsing graph for question answering recommendation

In this paper, we develop a framework of Question Answering Pages (referred to as QA pages) recommendation. Our proposed framework consists of the two modules: the off-line module to determine the importance of QA pages and the on-line module for on-line QA page recommendation. In the off-line module, we claim that the importance of QA pages could be discovered from user click streams. If the QA pages are of higher importance, many users will click and spend their time on these QA pages. Moreover, the relevant relationships among QA pages are captured by the browsing behavior on these QA pages. As such, we exploit user click streams to model the browsing behavior among QA pages as QA browsing graph structures. The importance of QA pages is derived from our proposed QA browsing graph structures. However, we observe that the QA browsing graph is sparse and that most of the QA pages do not link to other QA pages. This is referred to as a sparsity problem. To overcome this problem, we utilize the latent browsing relations among QA pages to build a QA Latent Browsing Graph. In light of QA latent browsing graph, the importance score of QA pages (referred to as Latent Browsing Rank) and the relevance score of QA pages (referred to as Latent Browsing Recommendation Rank) are proposed. These scores demonstrate the use of a QA latent browsing graph not only to determine the importance of QA pages but also to recommend QA pages. We conducted extensive empirical experiments on Yahoo! Asia Knowledge Plus to evaluate our proposed framework.     

一种高动态范围图像可视化算法*

提出的自适应HDR图像可视化算法中,输入图像被分解为基本层和细节层.该算法将整体明暗效果的显示看做整体问题,对表示亮度的基本层采用基于整体统计信息的直方图调整算法处理;可视细节信息的保持作为局部问题,算法采用自适应细节增强算法处理细节层.通过定义映射图对细节增强后的图像进行最终映射,将两方面结合起来得到最终结果.实验结果表明,该算法能对HDR图像进行较高视觉质量的显示.     

Optimization and evaluation of reduced graphene oxide hydrogel composite as a demulsifier for heavy crude oil-in-water emulsion

The rising production of produced water from oilfields had been proven to bring detrimental environmental effects. In this study, an efficient, recyclable, and environmental-friendly reduced graphene oxide immobilized κ-Carrageenan hydrogel composite(κCa GO) was fabricated as an alternative sorbent for crude oil-in-water demulsification. Polyethyleneimine(PEI) was employed to form a stable hydrogel composite. The conditions for the immobilization of graphene oxide(GO) on PEI-modified κ-Carrageenan(κC) beads were optimized appropriately. An immobilization yield of 77% was attained at 2% PEI, 2 h immobilization activation time, and p H6.5. Moreover, the synthesized κCa GO is capable of demulsification with an average demulsification efficiency of 70%. It was found that the demulsification efficiency increases with salinity and κCa GO dosage, and it deteriorates under alkaline condition. These phenomena can be attributed to the interfacial interactions between κCa GO and the emulsion. Furthermore, the κCa GO can be recycled to use for up to six cycles without significant leaching and degradation. As such, the synthesized κCa GO could be further developed as a potential sorbent substitute for the separation of crude oil from produced water.