Pseudocapacitive Sodium Storage by Ferroelectric Sn2P2S6 with Layered Nanostructure

Sodium ion batteries (SIB) are considered promising alternative candidates for lithium ion batteries (LIB) because of the wide availability and low cost of sodium, therefore the development of alternative sodium storage materials with comparable performance to LIB is urgently desired. The sodium ions with larger sizes resist intercalation or alloying because of slow reaction kinetics. Most pseudocapacitive sodium storage materials are based on subtle nanomaterial engineering, which is difficult for large‐scale production. Here, ferroelectric Sn₂P₂S₆ with layered nanostructure is developed as sodium ion storage material. The ferroelectricity‐enhanced pseudocapacitance of sodium ion in the interlayer spacing makes the electrochemical reaction easier and faster, endowing the Sn₂P₂S₆ electrode with excellent rate capability and cycle stability. Furthermore, the facile solid state reaction synthesis and common electrode fabrication make the Sn₂P₂S₆ that becomes a promising anode material of SIB.     

A modified θ projection model for constant load creep curves-II. Application of creep life prediction

To minimize the deviation of the predicted creep curves obtained under constant load conditions by the original θ projection model, a new modified version that can be expressed by $\epsilon ={\theta }_1\left(1-e^{-{\theta }_{2}t}\right)+{\theta }_3\left(e^{{\theta }_4{e}^{{\theta }_5\epsilon }t}-1\right)$, was derived and experimentally validated in our last study. In the present study, the predictive capability of the modified θ projection model was investigated by comparing the simulated and experimentally determined creep curves of K465 and DZ125 superalloys over a range of temperatures and stresses. Furthermore, the linear relationship between creep temperature and initial stress was extended to the 5-parameter model. The results indicated that the modified model could be used as a creep life prediction method, as it described the creep curve shape and resulted in predictions that fall within a specified error interval. Meanwhile, this modified model provides a more accurate way of describing creep curves under constant load conditions. The limitations and future direction of the modified model were also discussed. In addition, this modified θ projection model shows great potential for the evaluation and assessment of the service safety of structural materials used in components governed by creep deformation.     

Facile synthesis of perfect ZnSn(OH)<Subscript>6</Subscript> octahedral microcrystallines with controlled size and high sensing performance towards ethanol

Uniform and monodisperse ZnSn(OH)₆ perfect octahedrons have been synthesized by a facile coprecipitation reaction process. The particle size of the as-prepared ZnSn(OH)₆ octahedral structure can be readily controlled by adjusting the reaction temperature (T), and the side length of ZnSn(OH)₆ octahedrons was tailored from 3 μm (40°C) to 4 μm (60°C) and 5 μm (80°C). The ethanol sensing properties of ZnSn(OH)₆ octahedrons were carefully investigated. The gas sensing experimental data show that the sensor based on ZnSn(OH)₆ (40°C) has good selectivity, fast response/recovery time and the highest response (R_a/R_g = 23.8) to 200 ppm ethanol at relatively low optimum operating temperature (200°C) compared to sensors based on ZnSn(OH)₆ (60°C) and ZnSn(OH)₆ (80°C), which might result from different specific surface areas. The study demonstrated that perfect octahedral ZnSn(OH)₆ with controlled crystalline size and desirable sensing performance can be synthesized by a simple fabrication procedure, and the octahedral ZnSn(OH)₆ could be a highly promising material for high-performance sensors.     

高超声速飞行器的滑模边界层模糊自适应控制方法研究

针对高超声速飞行器飞行过程中存在的高度非线性、强耦合、参数不确定性等问题提出了一种基于滑模边界层模糊自适应的控制方法;首先将纵向模型进行精确线性化,通过引入一个滑模边界层可调参数,在边界层外施加基于正切趋近律的准滑模控制律;在边界层内,去掉准滑模控制律,采用饱和函数法设计的控制律;边界层参数用模糊逻辑系统进行在线调节,从而消除了系统处于准滑动模态时的高频抖振;仿真结果表明:该方法在保证控制系统具有良好跟踪性能的同时,具有削弱抖振的能力和强鲁棒性。     

静脉输液过程中滴速自动控制系统的建模与仿真

为对静脉输液过程的滴速自动控制系统进行设计和分析,对此类型系统进行建模和仿真研究;通过实验数据拟合出输液过程的静态模型,进而得到非线性的动态模型;采用一阶惯性环节对执行机构的动态特性进行描述,采用定积分对基于红外光电对管的滴速检测环节进行建模;在静态工作点对过程模型进行基于增量法的近似线性化处理,对给定值小范围变化的情况设计了PID控制律,对给定值大范围变化的情况采用先开环控制后闭环控制的控制策略;仿真结果表明,该模型能较准确反映被控过程和控制系统的特性,对控制系统的实施有较好的参考价值。     

两个宽带噪声矢量场模型的空间相关特性

针对宽带噪声矢量场的空间相关特性问题,文章讨论了各向同性噪声模型和表面噪声模型。在高频近似条件下,根据射线声学理论和简谐平面行波满足的欧拉公式,采用时域建模方法分别建立了宽带各向同性噪声和表面噪声矢量场模型。给出了噪声场相关函数的积分表达式和竖直方向空间相关系数的解析表达式。数值分析结果表明,相较于窄带噪声矢量场,宽带噪声矢量场各分量空间相关系数振荡幅度更小,随空间两点间距的增大更快地趋近于零;噪声源指向性对表面噪声场竖直方向上的空间相关特性的影响显著。相较于已有的宽带噪声空间相关系数计算方法,文中模型无需使用傅里叶合成方法,可通过时域建模直接获得宽带噪声空间相关函数。     

一种自适应EPF算法及其在光纤水听器中的应用

基于椭圆拟合的相位生成载波(Phase Generated Carrier,PGC)解调方法是消除非线性因素对光纤水听器PGC解调结果影响的一种有效手段,椭圆曲线参数的最优估计问题是实现该方法的关键。扩展卡尔曼粒子滤波(Extended Kalman Particle Filter,EPF)是解决此类非线性估计问题的一种常用的最优估计算法。但传统的EPF算法在用于常参数过程方程的参数或状态估计问题时,过程噪声的方差通常设置为一个常量,这使得算法难以兼顾收敛速度和估计精度,一定程度上限制了算法的整体性能。为了解决这个问题,文章对现有的EPF进行了改进,提出了一种自适应扩展卡尔曼粒子滤波(Adaptive Extended Kalman Particle Filter,AEPF)算法。模拟仿真和实验结果表明,文中所提出的AEPF算法能根据基于椭圆拟合的PGC解调方法有效地解调出待测声信号,相比EKF算法和EPF算法,AEPF算法的收敛速度和估计精度都得到了提升。此外,文章所提出的AEPF算法也适用于其他具有常参数过程方程的参数或状态估计问题,具有一定的通用性。     

芯轴摩擦系数对推压-拉拔复合缩径的影响

推压-拉拔复合缩径工艺是管坯减径的新方法,芯轴外表面与管坯内表面之间摩擦系数对工艺有重要的影响。通过建立推压-拉拔复合缩径变形过程中变形管坯的力学模型,分析了芯轴外表面与管坯内表面之间摩擦系数对成形的影响规律。针对某载重6.5 t胀压成形汽车桥壳管件的第一道次推压-拉拔复合缩径,设定不同的芯轴摩擦系数,进行了有限元仿真,得到了芯轴摩擦系数对管坯变形的影响规律,并基于管坯传力区不失稳以及变形所需凹模推力和芯轴拉拔力较小,给出了芯轴摩擦系数的设定范围。进行了缩径实验,实验和有限元模拟的结果接近。较小的芯轴摩擦系数可能造成管坯起皱失稳,而较大的芯轴摩擦系数,有利于降低管坯轴向压应力、凹模推力和芯轴拉拔力,但可能造成管坯表面划伤。