Taming Charge Transport in Semiconducting Polymers with Branched Alkyl Side Chains

The solid‐state packing and polymer orientation relative to the substrate are key properties to control in order to achieve high charge carrier mobilities in organic field effect transistors (OFET). Intuitively, shorter side chains are expected to yield higher charge carrier mobilities because of a denser solid state packing motif and a higher ratio of charge transport moieties. However our findings suggest that the polymer chain orientation plays a crucial role in high‐performing diketopyrrolopyrrole‐based polymers. By synthesizing a series of DPP‐based polymers with different branched alkyl side chain lengths, it is shown that the polymer orientation depends on the branched alkyl chain lengths and that the highest carrier mobilities are obtained only if the polymer adopts a mixed face‐on/edge‐on orientation, which allows the formation of 3D carrier channels in an otherwise edge‐on‐oriented polymer chain network. Time‐of‐flight measurements performed on the various polymer films support this hypothesis by showing higher out‐of‐plane carrier mobilities for the partially face‐on‐oriented polymers. Additionally, a favorable morphology is mimicked by blending a face‐on polymer into an exclusively edge‐on oriented polymer, resulting in higher charge carrier mobilities and opening up a new avenue for the fabrication of high performing OFET devices.     

Bandwidth-Efficient Modulation Codes Based on Nonbinary Irregular Repeat–Accumulate Codes

Using nonbinary low-density parity-check (LDPC) codes with random-coset mapping, Bennatan and Burshtein constructed bandwidth-efficient modulation codes with remarkable performance under belief propagation (BP) decoding. However, due to the random nature of LDPC codes, most of the good LDPC codes found in the literature do not have a simple encoding structure. Thus, the encoding complexity of those LDPC codes can be as high as O(N ²), where N is the codeword length. To reduce the encoding complexity, in this paper, nonbinary irregular repeat-accumulate (IRA) codes with time-varying characteristic and random-coset mapping are proposed for bandwidth-efficient modulation schemes. The time-varying characteristic and random-coset mapping result in both permutation-invariance and symmetry properties, respectively, in the densities of decoder messages. The permutation-invariance and symmetry properties of the proposed codes enable the approximations of densities of decoder messages using Gaussian distributions. Under the Gaussian approximation, extrinsic information transfer (EXIT) charts for nonbinary IRA codes are developed and several codes of different spectral efficiencies are designed based on EXIT charts. In addition, by proper selection of nonuniform signal constellations, the constructed codes are inherently capable of obtaining shaping gains, even without separate shaping codes. Simulation results indicate that the proposed codes not only have simple encoding schemes, but also have remarkable performance that is even better than that constructed using nonbinary LDPC codes.     

High Input Impedance Voltage-Mode Universal Biquadratic Filter with Three Inputs and Six Outputs Using Three DDCCs

A new high input impedance voltage-mode universal biquadratic filter with three input terminals and six output terminals is presented. The proposed circuit uses three plus-type differential difference current conveyors (DDCCs), three resistors, and two grounded capacitors. The proposed circuit can realize all the standard filter functions, namely, lowpass, bandpass, highpass, notch, and allpass, simultaneously, without component matching conditions. The proposed circuit still offers the features of high input impedance, using only grounded capacitors, and orthogonal controllability of resonance angular frequency and quality factor.     

Performance analysis and power allocation for decode‐and‐forward cooperative communications over Rician fading channel

This paper derives the asymptotic symbol error rate (SER) and outage probability of decode‐and‐forward (DF) cooperative communications over Rician fading channels. How to optimally allocate the total power is also addressed when the performance metric in terms of SER or outage probability is taken into consideration. Analysis reveals the insights that Rician factor has a great impact on the system performance as compared with the channel variance, and the relay–destination channel quality is of importance. In addition, the source–relay channel condition is irrelevant to the optimal power allocation design. Simulation and numerical evaluation substantiate the tightness of the asymptotic expressions in the high‐SNR regions and demonstrate the accuracy of our theoretical analysis. Copyright © 2011 John Wiley & Sons, Ltd.     

An Ultra-Broadband Doubly Balanced Monolithic Ring Mixer for Ku- to Ka-band Applications

A novel 12-40 GHz ultra-broadband doubly balanced monolithic ring mixer with a small chip size covering the Ku- to Ka-band applications implemented by a 0.15-mum pseudo- morphic high electron-mobility transistor process is presented. The proposed mixer consists of two spiral transformer baluns and a band-reject filter. The use of the spiral baluns leads to the achievement of a chip size less than 0.8 times 0.8 mm². The radio frequency (RF) spiral balun with a band-reject filter served by an L-C resonator is used to improve the bandwidth of the mixer and to provide an output port for the intermediate frequency (IF) extraction as well. The mixer exhibits a 6-12 dB conversion loss, high isolation over 12-40 GHz RF/local oscillation bandwidth, a DC-8 GHz IF bandwidth, and a 1-dB compression power of 14 dBm for both down- and up-converter applications.     

Mimic Drug Dosage Modulation for Neuroplasticity Based on Charge-Trap Layered Electronics

The human brain is often likened to an incredibly complex and intricate computer, rather than electrical devices, consisting of billions of neuronal cells connected by synapses. Different brain circuits are responsible for coordinating and performing specific functions. The reward pathway of the synaptic plasticity in the brain is strongly related to the features of both drug addiction and relief. In the current study, a synaptic device based on layered hafnium disulfide (HfS₂) is developed for the first time, to emulate the behavioral mechanisms of drug dosage modulation for neuroplasticity. A strong gate-dependent persistent photocurrent is observed, arising from the modulation of substrate-trapping events. By controlling the polarity of gate voltage, the basic functions of biological synapses are realized under a range of light spiking conditions. Furthermore, under the control of detrapping/trapping events at the HfS₂/SiO₂ interface, positive/negative correlations of the A_n/A₁ index, which significantly reflected the weight change of synaptic plasticity, are realized under the same stimulation conditions for the emulation of the drug-related addition/relief behaviors in the brain. The findings provide a new advance for mimicking human brain plasticity.     

Electromagnetic shielding of nylon-66 composites applied to laser modules

Electromagnetic shielding of nylon-66 composites applied to laser modules was studied experimentally and theoretically. The effects of conductive carbon fiber length and weight percentage upon the shielding effectiveness (SE) of nylon composites were investigated. The SE of long carbon fiber filled nylon-66 composites was found to be higher than short carbon fiber composites under the same weight percentage of carbon fibers. In addition, higher electromagnetic shielding was obtained for the composite with higher carbon fibers contents at the same length. The SE of conductive carbon fiber filled nylon-66 composites was measured to be 42 dB at a low frequency of 30 MHz and 50 dB at a high frequency of 1 GHz. The SE predicted by theoretical models and measured by experiments were in good agreement for filled nylon-66 composites with different length fiber.     

Current balancing control for an interleaved boost power converter

The interleaved boost power converter has the advantages of ripple cancellation and better efficiency. The major problem of the interleaved boost power converter is the current balancing among different phases of the boost power converters. In this paper, a current balancing control method for equalizing the currents of two-phase interleaved boost power converter is proposed. The output current can effectively detect the mismatch between the boost power converters for the interleaved boost power converter. The output current is used to perform both the current balance and the current-mode control. The salient feature is that only one current sensor is used in the proposed current balancing control method. A hardware prototype is developed, and the experimental results verify the performance of the proposed current balancing control method is as expected.     

Integrated optical device with second-harmonic generator,electrooptic lens, and electrooptic scanner in LiTaO3

This paper reports the first demonstration of an integrated optical device in z-cut LiTaO₃ that contains the following three functional parts: a quasiphase-matched second-harmonic generation (SHG) grating, an electrooptic (EO) lens, and an electrooptic scanner. The SHG device consists of channel waveguides passing through periodic domain-inverted gratings. The frequency of the input infrared (IR) light at 864 nm was doubled into blue light at 432 nm. A stack of EO lenses was used to collimate the light from the channel waveguide. The measured beam size at the output facet for various applied voltages to the lenses agreed with simulation. After collimation, light passes through an EO scanner that controls the angle of the output beam. A scanning sensitivity of 17 mrad/kV was measured for the scanner, compared to the calculated value of 15 mrad/kV     

Defect Engineering in Ambipolar Layered Materials for Mode-Regulable Nociceptor

Defect engineering represents a significant approach for atomically thick 2D semiconductor material development to explore the unique material properties and functions. Doping-induced conversion of conductive polarity is particularly beneficial for optimizing the integration of layered electronics. Here, controllable doping behavior in palladium diselenide (PdSe₂) transistor is demonstrated by manipulating its adatom-vacancy groups. The underlying mechanisms, which originate from reversible adsorption/desorption of oxygen clusters near selenide vacancy defects, are investigated systematically via their dynamic charge transfer characteristics and scanning tunneling microscope analysis. The modulated doping effect allows the PdSe₂ transistor to emulate the essential characteristics of photo nociceptor on a device level, including firing signal threshold and sensitization. Interestingly, electrostatic gating, acting as a neuromodulator, can regulate the adaptive modes in nociceptor to improve its adaptability and perceptibility to handle different danger levels. An integrated artificial nociceptor array is also designed to execute unique image processing functions, which suggests a new perspective for extension of the promise of defect engineered 2D electronics in simplified sensory systems toward use in advanced humanoid robots and artificial visual sensors.