X-ray based tools for the investigation of buried interfaces in organic electronic devices

X-ray reflectivity combined with grazing incidence diffraction is a valuable tool for investigating organic multilayer structures that can be used in devices. We focus on a bilayer stack consisting of two materials (poly-(3-hexylthiophene)) (P3HT) and poly-(4-styrenesulfonic acid) (PSSA) spin cast from orthogonal solvents (water in the case of PSSA and chloroform or toluene for P3HT). X-ray reflectivity is used to determine the thickness of all layers as well as the roughness of the organic–organic hetero-interface and the P3HT surface. The surface roughness is found to be consistent with the results of atomic force microscopy measurements. For the roughness of P3HT/PSSA interface, we observe a strong dependence on the solvent used for P3HT deposition. The solvent also strongly impacts the texturing of the P3HT crystallites as revealed by grazing incidence diffraction. When applying the various PSSA/P3HT multilayers in organic thin-film transistors, we find an excellent correlation between the determined interface morphology, structure and the device performance.     

Performance of PKI-based security mechanisms in mobile ad hoc networks

Security for ad hoc network environments has received a lot of attention as of today. Previous work has mainly been focussing on secure routing, fairness issues, and malicious node detection. However, the issue of introducing and conserving trust relationships has received considerably less attention. In this article, we present a scalable method for the use of public key certificates and their revocation in mobile ad hoc networks (MANETs). With the LKN-ad hoc security framework (LKN-ASF) a certificate management protocol has been introduced, bringing PKI technology to MANETs. In addition a performance analysis of two different revocation approaches for MANETs will be presented.     

Investigating Energy Prosumer Behaviour in Crowd Energy Using an Interactive Model/Diorama

Smart living labs such as the one located in Fribourg (Switzerland) focus on improving wellbeing and furthering knowledge related to building the district of the future on a technical and social level. Therefore, smart living labs represent an experimental platform/space where sustainable production and consumption strategies can be tested in a protected environment. A significant change in the socioeconomic production and consumption sphere can be expected by the rise of the so-called energy prosumer. Accordingly, this article presents an interactive model for the experimental investigation of energy prosumer behavior. In this context, two potential experiments on investment and trade decisions are briefly outlined. Since (behavioral and economic) experiments are usually conducted under controlled conditions in experimental labs involving mainly undergraduate students, the presented interactive model is flexible and mobile, providing the advantage to conduct experiments nearly everywhere involving everyday citizens.     

Topology Optimization of Segmented Thermoelectric Generators

The thermoelectric (TE) power output, \(f_P\), and conversion efficiency, \(f_{\eta }\), for segmented thermoelectric generators (TEGs) have been optimized by spatially distributing two TE materials (BiSbTe and Skutterudite) using a numerical gradient-based topology optimization approach. The material properties are temperature-dependent, and the segmented TEGs are designed for various heat transfer rates at the hot and cold reservoirs. The topology-optimized design solutions are characterized by spike-shaped features which enable the designs to operate in an intermediate state between the material phases. Important design parameters, such as the device dimensions, objective functions and heat transfer rates, are identified, investigated and discussed. Comparing the topology optimization approach with the classical segmentation approach, the performance improvements of \(f_P\) and \(f_{\eta }\) design problems depend on the heat transfer rates at the hot and the cold reservoirs, the objective function and the device dimensions. The largest performance improvements for the problems investigated are \(\approx \) 6%.     

Two-Dimensional Silicene–Stanene Heterostructures by Epitaxy

The synthesis of new Xenes and their potential applications prototypes have achieved significant milestones so far. However, to date the realization of Xene heterostructures in analogy with the well known van der Waals heterostructures remains an unresolved issue. Here, a Xene heterostructure concept based on the epitaxial combination of silicene and stanene on Ag(111) is introduced, and how one Xene layer enables another Xene layer of a different nature to grow on top is demonstrated. Single-phase (4 × 4) silicene is synthesized using stanene as a template, and stanene is grown on top of silicene on the other way around. In both heterostructures, in situ and ex situ probes confirm layer-by-layer growth without intercalations and intermixing. Modeling via density functional theory shows that the atomic layers in the heterostructures are strongly interacting, and hexagonal symmetry conservation in each individual layer is sequence selective. The results provide a substantial step toward currently missing Xene heterostructures and may inspire new paths for atomic-scale materials engineering.     

A BIST-DFT technique for DC test of analog modules

Among test techniques for analog circuits, DC test is one of the simplest method for BIST application since easy to integrate test pattern generator and response analyzer are conceivable. Precisely, this paper presents such an investigation for a CMOS operational amplifier that is latter extended to active analog filters. Since the computation of fault coverage is still a controversy question for analog cells, we develop first an evaluation technique for optimizing the tolerance band of the measurements to test. Then, using some DFT solutions we derive single DC pattern and discuss the minimal number of points to test for the detection of defects. A response analyzer is integrated with a Built-in Voltage Sensor (BIVS) and provides directly a logic pass/fail test result. Finally, the extra circuitry introduced by this BIST technique for analog modules does not exceed 5% of the total silicon area of the circuit under test and detects most of the faults.     

Optimization and Adaptation of Error Control Algorithms for Wireless ATM

A common problem of all wireless digital datatransmission systems is the bit error rates of the radiosubsystem, which can be several orders of magnitudehigher than for a wire- or fiber-based technology. Forward error correction (FEC), automaticrepeat request (ARQ), and interleaving are used as meansto improve throughput and bandwidth efficiency. Thispaper presents some considerations on the optimization and adaptation of these algorithms with focuson recent wireless ATM developments. The optimization,with respect to the target bit error rate and themapping of the wireless connection quality to the ATM quality of service (QoS) concept, is discussedin detail. In addition to the theoretical evaluation,which is verified by extensive simulations, we presentcomprehensive architecture and implementation considerations on the design of an adaptiveerror control system for a wireless ATMnetwork.     

Fabrication of low defect density 3C-SiC on SiO2 structures using wafer bonding techniques

This paper reports on a process to fabricate single-crystal 3C-SiC on SiO₂ structures using a wafer bonding technique. The process uses the bonding of two polished polysilicon surfaces as a means to transfer a heteroepitaxial 3C-SiC film grown on a Si wafer to a thermally oxidized Si wafer. Transfer yields of up to 80% for 4 inch diameter 3C-SiC films have been achieved. Homoepitaxial 3C-SiC films grown on the 3C-SiC on SiO₂ structures have a much lower defect density than conventional 3C-SiC on Si films.     

Pulse-driven Josephson digital/analog converter [voltage standard]

The authors have designed and demonstrated a pulse-driven Josephson digital/analog converter. When used as a programmable voltage standard, this device can synthesize metrologically accurate ac waveforms as well as stable dc voltages. We show through simulations that Josephson quantization produces a nearly ideal quantization noise spectrum when a junction is driven with a typical waveform produced by a digital code generator. This technique has been demonstrated in preliminary experiments with arrays of 1000 junctions clocked at frequencies up to 6 Gb/s, where sine waves of a few millivolts in amplitude were synthesized at frequencies up to 1 MHz     

High-resolution venography of the brain using magnetic resonance imaging

The purpose of this study was to evaluate a non-flow related magnetic resonance imaging method to visualize small veins independent of arteries in the human brain. A long TE, high-resolution 3D gradient echo MR acquisition was used to highlight venous information. The method is based on the paramagnetic property of deoxyhemoglobin and the resulting phase difference between veins and brain parenchyma at long echo times. The MR magnitude images were masked with a phase mask filter to enhance small structure visibility.. Venous information down to sub-pixel vessel diameters of several hundred microns is visible. Venous data are displayed in an angiographic manner using a minimum intensity projection algorithm. Both superficial veins and deep white matter veins are visible. The method has been successfully applied in volunteers. Preliminary results in patients with cerebral arteriovenous malformations indicate its potential in clinical applications. The proposed method is easy to implement and does not require administration of a contrast agent or application of specially designed rf pulses to highlight the veins. Rather it exploits the intrinsic magnetic properties (BOLD-effect) and the prolonged T ^_2* of venous blood. The method may be of diagnostic potential in the assessment of arteriovenous malformations or other vascular venous lesions. © 1998 Elsevier Science B.V. All rights reserved.