Picosecond pulse generation with ultralow jitter in 1.5-μmmulticontact MQW lasers using Q-switching

High-peak-power picosecond pulses with ultralow jitter of 65 fs (50-500 Hz) have been generated by Q-switching multi-quantum-well (MQW) distributed-feedback (DFB) and Fabry-Perot (FP) multicontact lasers. Peak pulse powers of 80 mW have been measured for pulses having durations of 26 ps and repetition rates of 1.25 GHz     

RSVP and integrated services in the Internet: a tutorial

The growing use of multimedia communication applications, with specific bandwidth and real-time delivery requirements has created the need for an integrated services Internet in which traditional best-effort datagram delivery can coexist with additional enhanced quality of service (QoS) delivery classes. Such classes provide data flows with QoS commitments with regard to bandwidth, packet loss, and delay through the reservation of network resources along the data path, which can be done using the Resource Reservation Protocol (RSVP). This article is a tutorial on how RSVP can be used by end applications to ensure that they receive the end-to-end QoS that they require     

Hydrogen-bonded diketopyrrolopyrrole (DPP) pigments as organic semiconductors

Diketopyrrolopyrroles (DPPs) have recently gained attention as building-blocks for organic semiconducting polymers and small molecules, however the semiconducting properties of their hydrogen-bonded (H-bonded) pigment forms have not been explored. Herein we report on the performance of three archetypical H-bonded DPP pigments, which show ambipolar carrier mobilities in the range 0.01–0.06 cm²/V s in organic field-effect transistors. Their semiconducting properties are correlated with crystal structure, where an H-bonded crystal lattice supports close and relatively cofacial π–π stacking. To better understand transport in these systems, density functional theory calculations were carried out, indicating theoretical maximum ambipolar mobility values of ∼0.3 cm²/V s. Based on these experimental and theoretical results, H-bonded DPPs represent a viable alternative to more established DPP-containing polymers and small molecules where H-bonding is blocked by N-alkylation.     

Pulsed Laser Deposition of Photoresponsive Two‐Dimensional GaSe Nanosheet Networks

Synthesis of functional metal chalcogenide (GaSe) nanosheet networks by stoichiometric transfer of laser‐vaporized material from bulk GaSe targets is presented. Uniform coverage of interconnected, crystalline, and photoresponsive GaSe nanosheets in both in‐plane and out‐of‐plane orientations are achieved under different ablation conditions. The propagation of the laser‐vaporized material is characterized by in situ ICCD‐imaging. High (1 Torr) Ar background gas pressure is found to be crucial for the stoichiometric growth of GaSe nanosheet networks. Individual 1–3 layer GaSe triangular nanosheets of ≈200 nm domain size are formed within 30 laser pulses, coalescing to form nanosheet networks in as few as 100 laser pulses. The thickness of the deposited networks increases linearly with pulse number, adding layers in a two‐dimensional (2D) growth mode. GaSe nanosheet networks show p‐type semiconducting characteristics with mobilities reaching as high as 0.1 cm²V^?1s^?1. Spectrally‐resolved photoresponsivities and external quantum efficiencies range from 0.4 AW^?1 and 100% at 700 nm, to 1.4 AW^?1 and 600% at 240 nm, respectively. Pulsed laser deposition under these conditions appears to provide a versatile and rapid approach to stoichiometrically transfer and deposit functional networks of 2D nanosheets with digital thickness control and uniformity for a variety of applications.     

The Control of Shrinkage and Thermal Instability in SU‐8 Photoresists for Holographic Lithography

The negative‐tone epoxy photoresist, SU‐8, expands ≈1% by volume after postexposure baking. However, if the maximum optical fluence is comparable to that at the insolubility threshold, as in a holographic exposure, the developed resist shrinks (≈35% by volume) due to the removal of light oligomers not incorporated into the polymeric network. IR spectroscopy shows that, at this level of exposure, only 15% of the epoxy groups in the insoluble polymer have reacted; consequently microstructural elements soften and collapse at >100 °C. When the light oligomers are removed, the sensitivity of the resist is unchanged, provided that 5% (w/w) of a high‐molecular‐weight reactive plasticizer (glycidoxy‐terminated polyethylene glycol) is added, but it shrinks less on development and, when used as a photonic crystal template, shows improved uniformity with less cracking and buckling. Reinforcing the polymer network by reaction with the polyfunctional amine (bis‐N,N′‐(3‐aminopropyl)ethylenediamine) increases the extent of cross‐linking and the thermal stability, allowing inverse replicas of photonic crystal templates to be fabricated from both Al:ZnO and Zr₃N₄ using atomic layer deposition at temperatures up to 200 °C.     

Generating compact, guaranteed passive reduced-order models of 3-D RLC interconnects

As very large scale integration (VLSI) circuit speeds and density continue to increase, the need to accurately model the effects of three-dimensional (3-D) interconnects has become essential for reliable chip and system design and verification. Since such models are commonly used inside standard circuit simulators for time or frequency domain computations, it is imperative that they be kept compact without compromising accuracy, and also retain relevant physical properties of the original system, such as passivity. In this paper, we describe an approach to generate accurate, compact, and guaranteed passive models of RLC interconnects and packaging structures. The procedure is based on a partial element equivalent circuit (PEEC)-like approach to modeling the impedance of interconnect structures accounting for both the charge accumulation on the surface of conductors and the current traveling in their interior. The resulting formulation, based on nodal or mixed nodal and mesh analysis, enables the application of existing model order reduction techniques. Compactness and passivity of the model are then ensured with a two-step reduction procedure where Krylov-subspace moment-matching methods are followed by a recently proposed, nearly optimal, passive truncated balanced realization-like algorithm. The proposed approach was used for extracting passive models for several industrial examples, whose accuracy was validated both in the frequency domain as well as against measured time-domain data.     

Efficient visualization of large routing topologies

As the Internet grows in size and complexity, network managers face a significant challenge in trying to understand the behaviour of routing protocols in large networks. In this paper, we present a tool called VLNT (visualizing large network topologies), which helps network managers to analyse complex routing topologies. A key contribution of our system is a novel hybrid layout algorithm, which significantly reduces the computation time required to layout large network topologies in comparison to conventional layout approaches. In addition our algorithm includes a novel termination criterion that avoids unnecessary iterations when optimizing the network layout. We demonstrate how the visualization features of VLNT can be used to analyse and improve BGP routing topologies, and provide examples using real‐life routing data. Copyright © 2004 John Wiley & Sons, Ltd.     

Seismic wavelet estimation: a frequency domain solution to ageophysical noisy input-output problem

In seismic reflection prospecting for oil and gas a key step is the ability to estimate the seismic wavelet (impulse response) traveling through the Earth. Such estimation enables filters to be designed to deblur the recorded seismic time series and allows the integration of “downhole” and surface seismic data for seismic interpretation purposes. An appropriate model for the seismic time series is a noisy-input/noisy-output linear model. The authors tackle the estimation of the impulse response in the frequency domain by estimating its frequency response function. They use a novel approach where multiple coherence analysis is applied to the replicated observed output series to estimate the output signal-to-noise ratio (SNR) at each frequency. This, combined with an estimate of the ordinary coherence between observed input and observed output, and with the spectrum of the observed input and cross-spectrum of the observed input and output, enables estimation of the frequency response function. The methodology is seen to work well on real and synthetic data     

The hydrogen-fueled internal combustion engine: a technical review

A review is given of contemporary research on the hydrogen-fueled internal combustion engine. The emphasis is on light- to medium-duty engine research. We first describe hydrogen-engine fundamentals by examining the engine-specific properties of hydrogen and surveying the existing literature. Here it will be shown that, due to low volumetric efficiencies and frequent preignition combustion events, the power densities of premixed or port-fuel-injected hydrogen engines are diminished relative to gasoline-fueled engines. Significant progress has been made in the development of advanced hydrogen engines with improved power densities. We discuss several examples and their salient features. Finally, we consider the overall progress made and provide suggestions for future work.     

Simple modelling of the effects of exploitation on hot springs, Geyser Valley, Wairakei, New Zealand

Many hot springs in Geyser Valley declined and ceased flowing during well testing (1950–1958) or the early stages of development (1958–1964) of the Wairakei field, North Island, New Zealand. A simple model that considers mixing, geothermal reservoir pressure, and Darcy flow is applied to analyse the changes in flow rate and chemistry of spring SP18. The model suggests that prior to the testing the observed flow rate of 3 l/s was comprised of about 2.1 l/s of water from the deep reservoir and about 0.9 l/s from shallow groundwater. As the pressure in the reservoir decreased as a result of exploitation, the reservoir component declined but the groundwater component remained near constant until the spring had nearly ceased flowing. The model reasonably predicts the flow cessation date for four other springs (Group A) but poorly predicts that for seven other springs (Group B). These two groups of springs do not appear to be clustered at the ground surface. The pressure–elevation relationship suggests that the Group A springs feed from within the shallower Waiora Formation and Group B springs from within the deeper Wairakei Ignimbrite Formation. The observation that declines of chloride concentrations in Group A springs occurred at least three years before those in springs of Group B is consistent with the finding that Group A springs have a shallower feeder depth.