双向飞翼超声速客机激波阻力和声爆研究

基于超声速双向飞翼构型,采用CFD方法进行阻力计算,采用F-BOOM程序进行声爆计算,研究翼型、平面形状和EFCE激波阻力优化算法对双向飞翼激波阻力和声爆的影响。计算结果表明,平底构型可以明显降低双向飞翼超声速客机的超声速巡航的声爆,却很大程度上增加了巡航阻力,而对称构型却恰好相反;细长的平面几何形状对降低双向飞翼激波阻力和声爆都有作用,尤其对降低对称构型的声爆效果明显;EFCE激波阻力优化算法对降低双向飞翼激波阻力有明显作用,但同时会带来声爆方面的不利影响。因此,超声速客机的减阻设计和低声爆设计需要进行权衡研究。     

基于时滞不等分法T-S模糊时滞系统稳定性准则

提出一种新的时滞分解方法—时滞不等分法,研究了T-S模糊常时滞系统的稳定性准则问题。基于Lyapunov稳定性理论,构造恰当的Lyapunov-Krasovskii泛函,以线性矩阵不等式形式给出一个决策变量少、运算效率高、保守性小的时滞相关稳定性准则。最后给出数例说明该方法的有效性。     

基于表面反应和扩散迁移控制的灰岩单裂隙渗流—溶解模型及其数值模拟

针对碳酸盐类可溶岩地区水电站坝址流场、化学场以及固相介质属性等随时间发生改变,从而对工程安全运行造成不利影响等问题,研究了灰岩地区地下水运移过程中各物理场间的相互作用,分析了影响灰岩溶解速率的两个因素,即表面反应控制和扩散迁移控制。在此基础上,建立了单裂隙中的渗流—溶解耦合模型,并进行数值求解。模拟结果表明,在垂直裂隙延伸方向,其溶蚀锋面为非齐整平面,而是呈似“虫洞”状非均一变化,而沿裂隙延伸方向即自上游侧向下游方向溶蚀程度逐渐减轻;而通过裂隙的流量呈现随时间逐渐增大的趋势,但变幅不大;根据流量求得的等效水力隙宽,其增幅和增长速率均小于实际平均隙宽;同时,化学场中Ca2+浓度的分布与裂隙开度变化具有相似性,不同时刻下上游侧反应速率R均大于下游侧。就反应机制而言,在初期均受表面反应控制,而随反应进行,位于上游补给区部位转为受扩散迁移控制,但在下游位置仍受表面反应控制。     

考虑爆裂影响的轴向约束高强混凝土柱耐火性能研究

应用有限元软件ABAQUS,基于一次爆裂模式,建立了轴向约束高强混凝土（HSC）柱的抗火分析模型.采用试验数据验证了模型的合理性.采用验证后的模型,分析了不同轴向约束刚度比下高强混凝土柱轴力及位移变化的规律,重点考虑了爆裂深度、爆裂长度、爆裂开始时间等爆裂参数对高强混凝土柱轴向位移、截面温度场和耐火极限的影响规律.研究表明：相同爆裂时间前提下,HSC柱轴向位移随爆裂深度、爆裂长度的增大而增大,耐火极限随之减小.爆裂深度、爆裂长度相同前提下,爆裂开始时间对HSC柱的耐火性能影响很小.当荷载比不变时,轴向约束刚度比对HSC柱膨胀阶段的最大轴向位移影响甚小,但是在越过初始平衡位置的收缩阶段对轴向位移影响很大.轴向约束刚度比对轴向约束HSC柱的耐火极限影响不大.     

微波加热法合成蜂窝状堇青石载体Al2O3涂层

采用微波加热法在堇青石蜂窝陶瓷基体表面涂覆多孔Al2O3涂层,研究了制备条件对堇青石蜂窝陶瓷表面Al2O3涂层中Al2O3的质量分数的影响。通过BET、SEM对涂层结构及形貌进行了表征,结果表明,采用微波加热法制备的Al2O3涂层均匀、稳定,具有较大的比表面积、孔容和较高的Al2O3质量分数。     

Valence-induced effects on the electrical properties of NiMn2O4 ceramics with different Ni sources

Spinel-structured NiMn₂O₄ ceramics, with different valence Ni sources, were originally prepared using Ni₂O₃ and NiO as raw materials, and the effects of different valence Ni sources on their electrical properties were first investigated. XRD patterns show that both Ni₂O₃-based and NiO-based NiMn₂O₄ ceramics are single cubic spinel structures. SEM/EDS images indicate that the NiMn₂O₄ ceramics exhibited high density at the experiment-determined sintering temperatures. XPS results and Raman drifts prove that the Ni valence-induced changes in Mn ions at B sites played a significant role in the electrical properties and thermal stability of NiMn₂O₄ ceramics. Compared with NiO-based NiMn₂O₄, the resistivity at 25°C (ρ_25°C) of Ni₂O₃-based NiMn₂O₄ increased dramatically from 3109 to 106958 Ω cm, the thermal constant (B_25/50) increased from 3264 to 4473 K, and the resistance shifts after annealing for 1000 h at 150°C decreased from 0.80% to 0.74%. The investigation of the relationship between the material properties and valence of Ni sources has provided a new and effective way for designing the spinel-structured negative temperature coefficient (NTC) materials by modulating the valence of ions at A sites in the raw materials.     

Electro-reduction of Cu2O to Cu in urea/1-ethyl-3-methylimidazolium chloride

Journal of Applied Electrochemistry - Urea/1-ethyl-3-methylimidazolium chloride (urea-EMIC) was developed to electrodeposit Cu from Cu2O at room temperature. Density, viscosity and conductivity of...     

Differences in electrochemical corrosion behaviours between selective laser melted and wrought Ti6Al4V alloys in acid fluoride-containing artificial saliva

Journal of Applied Electrochemistry - In this work, the electrochemical corrosion behaviours of selective laser melted (SLMed) and wrought Ti6Al4V alloys in acid fluoride-containing artificial...     

Prestructured MXene fillers with uniform channels to enhance CO2 selective permeation in mixed matrix membranes

The packing pattern of two-dimensional (2D) sheet-like fillers in membranes is relatively random, leading to the unfavorable permeability from tortuous diffusion pathway. A new strategy that using prestructured materials with uniform channels as fillers was proposed. In this work, Ti₃AlC₂ is etched to prepare multilayered MXene (m-MXene), the channels aggregate as a whole unit, ensure the impossibility of ineffective packing compared with traditional individual sheets, largely facilitating the selective permeation. Then, the m-MXene/Poly (amide-6-b-ethylene oxide) (Pebax) MMMs are synthesized. SEM images demonstrate the accordion shaped structure of filler, which is the multi-channels laminates. Furthermore, the results of gas permeation test exhibit enhanced performance of m-MXene/Pebax MMMs. MMM with 0.5 wt.% m-MXene behaved best, CO₂ permeability of 86.22 Barrer as well as CO₂/N₂ selectivity of 104.85, transcending the Robeson upper bound (2008). Having distinct enhancement for CO₂ separation, the m-MXene/Pebax MMMs in this work offer prospective practical applications.     

Effect of particle size on flame retardancy and mechanical properties of hydroxyethyl diphosphate modified aluminum hydroxide intrinsic polyethylene terephthalate

Organic–inorganic hybrid flame retardant was obtained by modifying aluminum hydroxide with different particle size with 1-hydroxyethylidene-1,1-diphosphonic acid. The structure of the organic–inorganic hybrid flame retardant is characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy, while ¹H-NMR spectroscopy only characterizes specific samples. The thermal stability and flame retardancy of the samples were analyzed by thermogravimetric analysis, limiting oxygen index (LOI), vertical combustion of UL-94 and cone calorimeter. The results show that the modified 10 μm aluminum hydroxide has a better effect than the 25 μm aluminum hydroxide and 100 nm aluminum hydroxide. Compared with pure polyethylene terephthalate (PET), the LOI value of the best sample is increased by 24.4%, and UL-94 V reaches V-0 level. Heat release rate, total heat release rate, and carbon monoxide production rate decreased by 45.8%, 33.2%, and 41.5%, respectively, compared to pure PET. The results showed that the aluminum hydroxide with a particle size of 10 μm exhibited the best flame retardant effect, which could be attributed to the decomposition of organic phosphoric acid and the dehydration of aluminum hydroxide, yielding a higher amount of residual carbon.