The molecular weight distribution and oligomers of sodium hydroxide hydrolyzed poly(ethylene terephthalate)

Methanolic sodium hydroxide reacted more quickly than aqueous sodium hydroxide with poly(ethylene terephthalate) (PET). Larger amounts of low molecular weight deposits were formed at the product surface after the former treatment, also indicating the severity of this attack. The molecular weight distribution, obtained by gel permeation chromatography for the product of methanolic NaOH hydrolysis, had a population with 2400 peak molecular weight, which was not present on the chromatograph of the aqueous sodium hydroxide hydrolyzed product. This population is hypothesized to have been crystalline material. Extraction and analysis by high performance liquid chromatography of the low molecular weight products on the surface and in the bulk of the hydrolyzed PET samples, in comparison to controls, revealed the presence of more oligomeric species after hydrolysis. Also, more oligomeric species were present in the bulk extract of the methanolic sodium hydroxide hydrolyzed sample than in the aqueous NaOH hydrolyzed product.     

Laparoscopic versus open appendectomy

BACKGROUND: Clinical manifestations and course of sickle-cell anemia are variable. Knowledge about the factors, possibly geographic, that influence prognosis are still scanty. POPULATION AND METHODS: Data of hospitalization and management of children with sickle-cell disease were studied during two years (1992-1993) in the Pediatric Unit of Libreville Hospital. They concerned 205 admissions of 171 children and 131 outpatients. RESULTS: The main causes of hospitalization were: acute anemia (36 cases before the age of 5 years); painful crisis whose frequency increased with age (23% before 5 years, 35% between 5 and 10, 42% after 10 years); infections, essentially pulmonary occurring early, and bone infections at any age. Eight children died (because a complication of their disease). Among the 131 outpatients, half were detected because pyrexia, anemia and/or more often "hand-foot syndrome". More than 60% had hepatomegaly, one third still had splenomegaly after five years of age and more than one third was icteric. More than half children older than ten years had growth disorders. Mean hemoglobin level was 7 g/dL. 21 of the 83 tested children for HBsAg were positive and only one out of 79 was positive for HIV. CONCLUSIONS: Clinical manifestations and course of sickle-cell anemia in our patients are similar to those reported in Congolese children. Genetic and environmental factors may be responsible for differences with children from other, in particular French, cohorts.     

A simple model for laser drilling

A simple mathematical model of laser drilling is proposed. Assuming axi-symmetry of the process around the axis of the laser beam, a one-dimensional formulation is obtained after cross-sectional averaging. The novelty of the approach relies on the fact that even after dimension reduction, the shape of the hole can still be described. The model is derived, implemented and validated for drilling using lasers with intensities in the GW/cm² range and microsecond pulses.     

The Challenges of Cross-Modal Translation: English-to-Sign-Language Translation in the Zardoz System

The sign languages used by deaf communities around the world represent a linguistic challenge that natural-language researchers in AI have only recently begun to take up. This challenge is particularly relevant to research in Machine Translation (MT), as natural sign languages have evolved in deaf communities into efficient modes of gestural communication, which differ from English not only in modality but in grammatical structure, exploiting a higher dimensionality of spatial expression. In this paper we describe Zardoz, an on-going AI research system that tackles the cross-modal MT problem, translating English text into fluid sign language. The paper presents an architectural overview of Zardoz, describing its central blackboard organization, the nature of its interlingual representation, and the major components which interact through this blackboard both to analyze the verbal input and generate the corresponding gestural output in one of a number of sign variants.     

Single-factor coefficient bounds

In a 1993 paper Beauzamy, Trevisan and Wang derived a single-factor coefficient bound, one which limits the max norm (height) of at least one irreducible factor of any univariate integral polynomial A. Their bound is a function of the degree and the weighted norm of A. In the conclusion of their paper they ask whether the max norm of A might already be a single-factor coefficient bound. In 1998 Knuth, citing these authors, asked instead whether there is a constant c such that c times the max norm of A is a single-factor coefficient bound. We present the results of extensive calculations relating to this question. We show that c, if it exists, must be greater than 2 and accrue evidence in support of a conjecture that the answer to Knuth’s question is “no”.     

Electrochemically Tuned Properties for Electrolyte‐Free Carbon Nanotube Sheets

Injecting high electronic charge densities can profoundly change the optical, electrical, and magnetic properties of materials. Such charge injection in bulk materials has traditionally involved either dopant intercalation or the maintained use of a contacting electrolyte. Tunable electrochemical charge injection and charge retention, in which neither volumetric intercalation of ions nor maintained electrolyte contact is needed, are demonstrated for carbon nanotube sheets in the absence of an applied field. The tunability of electrical conductivity and electron field emission in the subsequent material is presented. Application of this material to supercapacitors may extend their charge‐storage times because they can retain charge after the removal of the electrolyte.