全文获取类型
收费全文 | 13563篇 |
免费 | 719篇 |
国内免费 | 18篇 |
专业分类
电工技术 | 150篇 |
综合类 | 9篇 |
化学工业 | 3456篇 |
金属工艺 | 255篇 |
机械仪表 | 234篇 |
建筑科学 | 485篇 |
矿业工程 | 19篇 |
能源动力 | 480篇 |
轻工业 | 2210篇 |
水利工程 | 108篇 |
石油天然气 | 40篇 |
无线电 | 661篇 |
一般工业技术 | 2137篇 |
冶金工业 | 1640篇 |
原子能技术 | 81篇 |
自动化技术 | 2335篇 |
出版年
2024年 | 25篇 |
2023年 | 109篇 |
2022年 | 455篇 |
2021年 | 524篇 |
2020年 | 295篇 |
2019年 | 356篇 |
2018年 | 534篇 |
2017年 | 488篇 |
2016年 | 528篇 |
2015年 | 366篇 |
2014年 | 556篇 |
2013年 | 852篇 |
2012年 | 826篇 |
2011年 | 980篇 |
2010年 | 687篇 |
2009年 | 678篇 |
2008年 | 613篇 |
2007年 | 563篇 |
2006年 | 459篇 |
2005年 | 399篇 |
2004年 | 310篇 |
2003年 | 293篇 |
2002年 | 265篇 |
2001年 | 192篇 |
2000年 | 189篇 |
1999年 | 171篇 |
1998年 | 637篇 |
1997年 | 389篇 |
1996年 | 289篇 |
1995年 | 170篇 |
1994年 | 141篇 |
1993年 | 140篇 |
1992年 | 57篇 |
1991年 | 61篇 |
1990年 | 57篇 |
1989年 | 49篇 |
1988年 | 40篇 |
1987年 | 41篇 |
1986年 | 41篇 |
1985年 | 42篇 |
1984年 | 33篇 |
1983年 | 34篇 |
1982年 | 39篇 |
1981年 | 47篇 |
1980年 | 38篇 |
1979年 | 16篇 |
1978年 | 20篇 |
1977年 | 39篇 |
1976年 | 64篇 |
1973年 | 20篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
41.
A. Hernández O. Arés C. Hart D. Domínguez H. Pastoriza A. Butera 《Journal of Low Temperature Physics》2004,135(1-2):119-122
The response of mesoscopic superconductors to an ac magnetic field is investigated both experimentally and with numerical simulations. We study small square samples with dimensions of the order of the penetration depth. We obtain the ac susceptibitity χ=χ′+iχ″ at microwave frequencies as a function of the dc magnetic field H dc. We find that the dissipation, given by x″, has a non monotonous behavior in mesoscopic samples. In the numerical simulations we obtain that the dissipation increases before the penetration of vortices and then it decreases abruptly after vortices have entered, the sample. This is verified experimentally, where we find that χ″ has strong oscillations as a function of H dc in small squares of Pb. 相似文献
42.
Andrés Rigail-Cedeño 《Polymer》2005,46(22):9378-9384
Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy. 相似文献
43.
Summary In this study, new hydrogels in rod shape were prepared from N-acryloyl-TRIS(hydroxymethyl)aminomethane (NAT) using ethylene glycol dimethacrylate (EGDMA) or N,N’methylenebisacrylamide (BIS) as crosslinking agent, dimethylformamide (DMF) as solvent and benzoyl peroxide (BPO) as initiator. In most cases, 2-hydroxyethyl methacrylate (HEMA), acrylamide (Aam) or acrylic acid (Aac) were used as co-monomers. The polymeric matrices obtained by free radical polymerization exhibited different properties by changing crosslinker, crosslinker concentration, co-monomer and initial NAT/co-monomer mole ratio. Besides, hydrogels from HEMA, Aam and Aac with BIS in absence of NAT were prepared under the same experimental reaction conditions in order to compare the properties of these products with those synthesized from NAT and the respective co-monomers. Some of the final products were selected to perform urea release assays, conducted through swelling-controlled release. Urea was chosen as “model” plant fertilizer agent. 相似文献
44.
S. Genovés J.V. Gil P. Manzanares J.L. Aleixandre S. Vallés 《Journal of food science》2003,68(6):2096-2100
ABSTRACT: A recombinant Saccharomyces cerevisiae wine yeast strain expressing the Candida molischiana bgln gene encoding a β-glucosidase (BGLN) has been used to produce this enzyme. Shaking rate, pH, and aeration rate conditions have been optimized to obtain maximum activity to facilitate enzyme purification. The ability of the heterologous enzyme to efficiently release terpenols and alcohols from a Muscat wine glycoside extract and also directly from wine has been demonstrated. Terpenol glycoside content decreased by 50% after 1 mo of wine storage in agreement with results reported for the β-glucosidase produced by C. molischiana. 相似文献
45.
A sieve bootstrap procedure for constructing interpolation intervals for a general class of linear processes is proposed. This sieve bootstrap provides consistent estimators of the conditional distribution of the missing values, given the observed data. A Monte Carlo experiment is used to show the finite sample properties of the sieve bootstrap and finally, the performance of the proposed method is illustrated with a real data example. 相似文献
46.
For the first time, order-order and order-disorder transitions were detected and characterized in a model diblock copolymer of poly(butadiene-1,3) and poly(dimethylsiloxane) (PB-b-PDMS). This model PB-b-PDMS copolymer was synthesized by the sequential anionic polymerization (high vacuum techniques) of butadiene 1,3 (B) and hexamethylciclotrisiloxane (D3), and subsequently characterized by nuclear magnetic resonance (1H and 13C NMR), size exclusion chromatography (SEC), Fourier Transform infrared spectroscopy (FTIR), Small-Angle X-ray scattering (SAXS) and rheology. SAXS combined with rheological experiments shows that the order-order and order-disorder transitions are thermoreversible. This fact indicates that the copolymer has sufficient mobility at the timescale and at the temperatures of interest to reach their equilibrium morphologies. 相似文献
47.
48.
M Isabel Sánchez de Rojas Julián Rivera Moisés Frías Félix Marín 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(3):209-217
Copper slag is a by‐product generated during smelting to extract copper metal from the ore. The copper slag obtained may exhibit pozzolanic activity and may therefore be used in the manufacture of addition‐containing cements. In this paper the effect of the incorporation of the copper slag in cement is measured. Blends of copper slag with Portland cement generally possess properties equivalent to Portland cement containing fly ash, but very different to the silica fume incorporation. Copper slag and fly ash reduce the heat of hydration more effectively than silica fume in mortars. The replacement of 30% cement by copper slag reduces the flexural and compressive strength in a similar way to fly ash; however, after 28 days, the reduction is less than the percentage of substitution. Hydrated calcium aluminate phases were analysed using scanning electron microscopy (SEM) and X‐ray diffraction (XRD) techniques. The pozzolanic activity of copper slag is similar to that of fly ash and higher than silica fume. In the presence of low water/cement ratios, certain pozzolanic materials produce a very compact cement paste that limits the space available for hydration products, a determining factor in the formation of hydrated calcium aluminates. SEM was found to be a useful analytical technique when aluminates are formed and can be clearly detected by XRD. Copyright © 2008 Society of Chemical Industry 相似文献
49.
Joaquín Cortés Eliana Valencia Gonzalo Aguila Esteban Orellana Paulo Araya 《Catalysis Letters》2008,126(1-2):63-71
An experimental study is made of the time decay of activity of the CO–NO reaction on a Pd/Al2O3 looking at the effect on reaction order and apparent activation energy. The optimum kinetics parameters fitting the steady state data at moderate pressures are determined. The time decay curves are analyzed through various catalyst deactivation models. 相似文献
50.
This paper reports the results of current fundamental research at the Department of Process Engineering, University of Miskolc on the processing of clean coal from Mecsek bituminous coal, Southern Hungary. The theoretical possibility of the separation of different petrographic components was proven experimentally and their liberation degree was determined based on the petrographic composition, flotation kinetic study of isolated components (groups of components), scanning electron microscopy and microprobe analyses. The mill with stirred ball media was chosen for the ultra-fine liberation of the coal components. It was revealed that along with the liberation of coal components, their surface oxidation and spontaneous agglomeration, entrapping the mineral impurities take place in ultra-fine grinding. This paper discusses the interfacial phenomena occurring in the ultra-fine grinding process and their influence on the flotation. The concept for the advanced preparation of clean coal was developed, tested and proved. The main steps of this concept are the ultra-fine liberation in the stirred-media mill, the de-agglomeration of flocs spontaneously formed during the ultra-fine grinding and the induced (hydrophobic) flocculation with the following two-step flotation in a flotation column. 相似文献