Polymerization kinetics of polyurethane and vinyl ester resin interpenetrating polymer networks by using fourier transform infrared spectroscopy

Fourier transform infrared spectroscopy (FTIR) was applied to the study of polymerization kinetics of simultaneous interpenetrating polymer networks (SINs) composed of polyurethane (PU) and vinyl ester resin (VER), in which the pendent hydroxyl groups were capped with acetyl groups to minimize the possibility of chemical binding between the two networks. It was found that during the course of synthesis the two pairs of reactants interfere with each other in the SIN systems, giving rise to depressed reaction rates, although they follow different polymerization mechanisms. Increasing the reaction temperature could be more effective than increasing the free-radical initiator level with regard to the final conversions of both components. The reaction sequence could be varied through the amount of the step-growth polymerization catalyst and free-radical initiator as well as the reaction temperature adjustment. Using VER containing pendent hydroxyl groups could strongly affect the reaction kinetics of such SINs and lead to hybrid structures. The quick formation of one network would always depress the conversion of the other network in all SINs studied. © 1996 John Wiley & Sons, Inc.     

Infrared spectroscopic studies of melting behavior of poly(ethylene 2, 6-naphthalenedicarboxylate)

The FTIR method was used to study the melting behavior of poly(ethylene 2, 6-naphthalene-dicarboxylate) (PEN) samples of different thermal history of crystallization. With subtraction of the spectra of PEN samples of different crystallinities and amorphous PEN, the spectra of crystalline trans conformers, amorphous trans conformers, and amorphous gauche conformers were obtained. By following the changes in intensity of various gauche and crystalline bands during heating, the phenomenon of multiple melting endothermic peaks was shown to be due to the melting of imperfect crystalline conformation formed during crystallization. For two-step annealed samples, the crystalline conformational defects change into a more perfect one during annealing at higher temperatures. © 1996 John Wiley & Sons, Inc.     

稀土对Fe-17.5Mn合金阻尼性能的影响

利用倒扭摆仪对比研究了Fe-17.5Mn二元合金和Fe-17.5Mn-0.3Mm(富铈混合稀土)合金的阻尼性能,并借用Olympus显微镜观察分析了合金的微观组织.研究结果表明,在1000℃保温1h后水淬状态下,Fe-17.5Mn-0.3Mm合金的阻尼性能明显优于Fe-17.5Mn二元合金.在微量稀土元素的作用下,Fe-17.5Mn-0.3Mm合金中相对于Fe-17.5Mn二元合金其马氏体数量较多、板条较细薄,板条变薄且单位体积内界面面积增加,使振动的微观阻尼源增多,导致阻尼性能提高.     

冶勒水电站砂砾胶结岩洞室爆破

本文根据冶勒水电站盖重料砂砾胶结岩洞室爆破的爆破试验及爆破参数的选择。对软岩洞室爆破进行了叙述并总结提出了几点施工经验。     

Quantum控制系统在20 000m3/h制氧机的应用

介绍Quantum系统在制氧机控制上的应用,描述分子筛纯化系统、污氮流量、氧压机起停等自动控制的实现,并且介绍与其他设备的通信。Quantum控制系统的投入提高了控制系统的可靠性,简化了操作过程,保证了制氧机长期稳定运行。     

MSP430多处理器之间的通信方式及协议

MSP430的功能已经非常强大,其片内外设丰富,适合众多的场合使用;但是在大型复杂的场合或者实时性要求较高的场舍,使用一个处理器处理所有的业务,总是显得有些不足。引入多处理器协作工作的模式,可提高系统的实时性、可靠性和适用性;利用MSP430固有的特点,选择UART模式,采用ModBus的通信协议,可进行不同处理器之间的数据交换。     

新的场地确认方法——参考场地法

首先分析了归一化场地衰减法用于场地确认的缺点。为了克服这些缺点,CISPR 引入了新的场地确认方法——参考场地法(归一化场地衰减法的替换方法)。给出了参考场地法的原理和分析了其用于场地确认的优点。     

混沌协议同步机制研究

利用实际通信平台,从网络通信协议的思路出发,结合通信环境对UDP协议进行了适当改造,提出了一种基于协议同步的混沌语音保密通信新系统,研究了实现协议同步的基本思想、算法实现技术及混沌信号、混沌加密信息的相关统计特性,建立了混沌协议同步机制.     

多结构形式小通道液冷板散热性能对比研究

小通道冷板作为一种有效的热控装置,已被广泛应用于高热流密度电子器件的热管理领域。文中以通道特征尺寸为2 mm 的串行、并行以及射流冲击/小通道混合液冷板为研究对象,旨在获取这3种结构形式冷板的极限散热能力和流动阻力损失的差异。研究结果表明：在相同冷却工质流量条件下,3种冷板的散热功率由大到小依次为串行通道、并行通道、射流冲击/小通道混合液冷板;串行通道冷板的板内阻力损失明显大于其余两者;在综合考虑压力损失和散热性能的基础上,根据不同热源热流密度条件选择合适的冷板结构,有望满足特定应用的需求。该研究可供小通道液冷板的设计和优化参考。     

大型直流电机采用短路法无火花换向区域的测定试验及分析

阐述了大型直流电机不能采用GB1311-89介绍的四种短路加载方式时,采用西门子短路法进行无火花换向区域的测定试验,经多年实践证明是安全可靠的.