Moisture Distribution and Dewatering Efficiency for Wet Materials

This review paper summarizes current research efforts toward a comprehensive view of wet material dewatering, considering the binding energy as the strength to hold water, and rupture energy given to remove moisture from materials.     

The prediction of transport parameters in filamentous fermentation broths based on results obtained in pseudoplastic polymer solutions

Transport phenomena studies on single phase “model” fluids are of limited value in biochemical engineering if they cannot be translated to the heterogeneous systems encountered in real fermentation processes. In this paper we discuss the utility of polymer solutions as models of filamentous fermentation broths for evaluation of: pipeline friction factors and impeller power numbers (turbine and helical ribbon). To a first approximation, polymer solutions can serve as suitable models for the prediction of laminar flow pressure drop in pipelines and turbulent power consumption in stirred tanks. However, results obtained on polymer solutions do not directly apply to filamentous fermentation broths for predictions of laminar flow impeller power consumption and the transition point for turbulent flow in stirred tanks. These discrepancies are believed to result from the existence of a time dependent yield stress in filamentous fermentation broths.     

Thermal conductivity of magnesite refractories in the range 500–1800°C

Conclusions An experimental setup was developed for studying the thermal conductivity of refractories up to 2300°C on the hot face of the specimen.In the average temperature range of 500–1800°C a study was made of the thermal conductivity of magnesite refractories of different porosity. The experimental data obtained satisfactorily agree with well-known literature and calculated values for the thermal conductivity coefficients.Translated from Ogneupory, No. 1, pp. 17–21, January, 1972.     

Refractories for lining mobile mixers

Conclusions New and effective refractories have been developed whose physicotechnical and working parameters are better than those of existing Soviet and foreign materials. Commercial production of them has been organized.MKFU-83 and KKFU-76 refractories increase mixer lining resistance by substantial factors and reduce the number of repair cycles and the material and labor costs, while increasing the metal output. The refractories are recommended for use in steel-melting processes (electric furnaces and buckets).Translated from Ogneupory, No. 2, pp. 24–26, February, 1991.     

The chemistry and development of tannin-based weather- and boil-proof cold-setting and fast-setting adhesives for wood

Condensed tannins, being phenolic in nature, can be chemically modified to undergo reaction with formaldehyde in such a way that the adhesives formed harden at ambient temperature in industrially meaningful times. Resorcinol, m-hydroxyaniline, and their condensation products with formaldehyde and/or tannin resoles have been used for this purpose. The optimum conditions of application, such as paraformaldehyde amount, pH, and open and close assembly times, were used when comparing the different resins prepared. Results satisfying the requirements of international standard specifications and comparable to those of phenol/resorcinol/formaldehyde cold-setting resins were obtained.     

Non-markovian diffusion processes in polymers and a stretched exponential relaxation constitutive equation

Non-Markovian diffusion transport in polymers was studied. Applying the results of various researchers, a stretched exponential relaxation function was obtained and a linear viscoelastic constitutive equation formulated. Frequency dependent material functions, obtained from this constitutive equation were studied and the results successfully compared with experimental data for polyethylene oxide solutions. Sorption kinetics in a polymeric film were also studied. © 1994 John Wiley & Sons, Inc.     

Strain-induced crystallization,Part IV: Induction time analysis

The empirical equation, 1/t_i = Ae^Ei/RT, which expresses the exponential dependence of the reciprocal of crystallization induction time, t_i, has been analyzed and shown to be equivalent to the nucleation rate equations derived earlier in Part III (1). Consequently we have used the t_i measurements obtained earlier by Krueger and Yeh to calculate not only the nucleation rate enhancements but also the melting point elevations, the relative crystal thickness changes and molecular coil extension ratios of shear-crystallization polyethylene. It is shown that polyethylene when crystallized between 129 and 131°C at shear rates between 1.56 and 9.70 sec^?1 can have melting point increases of 4.2 to 7.2°C and crystal thickness decreases of 20 to 25 percent, when compared to those crystallized at 130°C in the quiescent state. The predicted “coil” extension in the melt just prior to shear-induced crystallization ranges between 21 and 36 percent. The results of these analyses as well as those on nucleation rates of polyethylene oxide are discussed in detail.     

Use of mesoporous SBA-15 for nanostructuring titania for photocatalytic applications

SBA15–TiO₂ samples prepared by introducing titanium with a grafting method and having TiO₂ loadings below 15 wt.% have been characterized by XRF, XRD, IR, porosimetry, SEM, HRTEM, and UV–Visible diffuse reflectance. Differently from the samples reported in the literature characterized by a high TiO₂ loading, no evidences have been found for the presence of titania particles inside or outside the mesopores of SBA-15. Three different titanium species were instead evidenced to be present. The first two derive from the reaction of titanium with silanol groups in the corona area of inner SBA-15 walls leading to the formation of either TiO₄ tetrahedral sites (by reaction by hydroxyl nests of surface defect sites) and/or pseudo-octahedral surface sites anchored by two (or more) Si or Ti ions through bridging oxygens. The third species derives from the reaction of titanium in the regions with high sylanol density, e.g. in the micropores located in the corona of SBA-15 channels, leading to the formation of TiO₂-like nanoareas (probably Si-doped) with dimensions of around 1–2 nm maximum. The potential interest of these materials as photocatalysts, for the presence of a TiO₂-like nanoareas highly accessible by reactants, is discussed.     

Cysteine adds to lipid hydroperoxide

Cysteine reacts with linoleic acid hydroperoxide to yield several products, some of which were identified as fatty acid-cysteine adducts. The addition was catalyzed by ferric chloride (10⁻⁵ M) by initiating free radical reactions. When isomerically pure 13-hydroperoxy-cis-9,trans-11-octadecadienoic acid and cysteine were reacted in 80% ethanol under N₂, the major adducts were 9-S-cysteine-13-hydroxy-10-ethoxy-trans-11-octadecenoic acid (I) and 9-S-cysteine-10,13-dihydroxy-trans-11-octadecenoic acid (II). When the reaction included both isomers of the hydroperoxide (13-and 9-hydroperoxide) and air, an adduct of 9-oxononanoic acid and cysteine also was isolated. Additional experiments gave information about possible mechanisms of I and II formation.