Untersuchungen zum Korrosionsverhalten von AlLi-Legierungen

Corrosion behaviour of aluminium-lithium alloys The AlLiMgCu alloy 8090 was studied in its texturated fine grained version “A” and in its recrystallized coarse grain structured version “C” in different artificially aged conditions in reference to several other AlLi alloys, each in its heat treatment condition of practical interest, and to the convetional alloy 2024 T3. The subject of research was the general corrosion behaviour of semifinished AlLi products, particularly sheet material, under alternate and permanent immersion conditions in neutral 3.5% sodium chloride solution; the stress corrosion behaviour was studied under constant load in the long transverse direction according to ASTM G44 and G49. The underaged conditions, which are the relevant conditions for technical application of the 8090 “A” and “C” sheets, showed an approximately equivalent or even better corrosion behaviour in comparison to the lithium-free alloy 2024 T3 in the corrosion tests with unloaded specimens. The threshold above which the AlLi alloy 8090 in some heat treatment conditions is attacked by stress corrosion cracking within the 30 days lasting constant load test depends on alloy composition, testing direction, grain size, stretch-forming, artificial ageing condition, surface pretreatment and the specimens' dimensions.     

Catalytic properties and electronic structure of copper ions in Cu-ZSM-5

The effect of ion exchange conditions, such as Si/Al ratio, precursor copper salt, pH and concentration of the solution, on the catalytic activity in SCR of NO by propane and on the electronic state of copper ions in Cu-ZSM-5 has been studied. The NO conversion in NO SCR by C₃H₈ has been found to reach a maximum value at Cu/Al ratio about 0.37–0.4 and remain constant at higher Cu/Al.

ESR and UV–vis DR spectroscopy have been used to elucidate stabilization conditions of copper ions in Cu-ZSM-5 zeolites as isolated Cu²⁺ ions, chain copper oxide structures and square-plain oxide clusters. The ability of copper ions for reduction and reoxidation in the chain structures may be responsible for the catalytic activity of Cu-ZSM-5. These transformations of copper ions are accompanied by the observation of intervalence transitions Cu²⁺–Cu⁺ and CTLM of the chain structures in the UV–vis spectra.     

Current and future water issues in the Oldman River Basin of Alberta, Canada.

Long-term trends in alpine and prairie snow pack accumulation and melt are affecting streamflow within the Oldman River Basin in southern Alberta, Canada. Unchecked rural and urban development also has contributed to changes in water quality, including enhanced microbial populations and increased waterborne pathogen occurrence. In this study we look at changing environment within the Oldman River Basin and its impact on water quality and quantity. The cumulative effects include a decline in net water supplies, and declining quality resulting in increased risk of disease. Our data indicates that decreases in the rate of flow of water can result in sedimentation of bacterial contaminants within the water column. Water for ecosystems, urban consumption, recreation and distribution through irrigation is often drawn from waterholding facilities such as dams and weirs, and concern must be expressed over the potential for contaminate build-up and disproportionate potential of these structures to pose a risk to human and animal health. With disruption of natural flow rates for water resulting from environmental change such as global warming and/or human intervention, increased attention needs to be paid to use of best management practices to protect source water supplies.     

Implementation of adaptive critic-based neurocontrollers for turbogenerators in a multimachine power system

This paper presents the design and practical hardware implementation of optimal neurocontrollers that replace the conventional automatic voltage regulator (AVR) and the turbine governor of turbogenerators on multimachine power systems. The neurocontroller design uses a powerful technique of the adaptive critic design (ACD) family called dual heuristic programming (DHP). The DHP neurocontrollers' training and testing are implemented on the Innovative Integration M67 card consisting of the TMS320C6701 processor. The measured results show that the DHP neurocontrollers are robust and their performance does not degrade unlike the conventional controllers even when a power system stabilizer (PSS) is included, for changes in system operating conditions and configurations. This paper also shows that it is possible to design and implement optimal neurocontrollers for multiple turbogenerators in real time, without having to do continually online training of the neural networks, thus avoiding risks of instability.     

Laminar-turbulent transition in an electromagnetically levitated droplet

During experiments on the MSL-1 (first microgravity science laboratory) mission of the space shuttle (STS-83 and STS-94, April and July 1997), a droplet of palladium-silicon alloy was electromagnetically levitated for viscosity measurements. For the nondeforming droplet, the resultant magnetohydrodynamic (MHD) flow inside the drop can be inferred from motion of impurity particulates on the surface. In the experiments, subsequent to melting, Joule heating produces a continuous reduction of viscosity of the fluid resulting in an acceleration of the flow with time. These observations indicate formation of a pair of co-rotating toroidal flow structures inside the spheroidal drop that undergo flow instabilities. As the fluid temperature rises, the amplitude of the secondary flow increases, and beyond a point, the tracers exhibit noncoherent chaotic motion signifying emergence of turbulence inside the drop. Assuming that the observed laminar-turbulent transition is shear-layer type, the internal structure of the toroidal loops is used to develop a semiempirical correlation for the onset of turbulence. Our calculations indicate that the suggested correlation is in modest agreement with the experimental data, with the transition occurring at a Reynolds number of 600.     

Online and Offline Rotary Regression Analysis of Torque Estimator for Switched Reluctance Motor Drives

A new torque estimator for switched reluctance motor (SRM) drives based on 2-D rotary regression analysis is presented in this paper. The proposed torque estimator is composed of a bicubic regressive polynomial as a function of rotor position and input current. The regressive coefficients can be computed offline or online from the torque characteristics acquired either experimentally or from numerical computation. Furthermore, a torque estimation method by taking mutual coupling into consideration is proposed. It can be seen that the estimated and experimentally obtained self-coupling and mutual-coupling torque characteristics are in good agreement with each other. In addition, the dynamic torque waveforms with and without the mutual coupling, estimated by the proposed estimator, are found to be virtually the same as those obtained from the bicubic spline interpolation for SRM drives with single-pulse voltage, hysteresis current chopping, as well as with voltage pulse width modulation control. The success of all the case studies being reported is a good validation of the usefulness and accuracy of the proposed real-time torque estimator that, as described in this paper, can be used to quickly estimate the instantaneous output torque of SRM drives.     

3D velocity from 3D Doppler radial velocity

We present local least squares and regularization frameworks for computing 3D velocity (3D optical flow) from 3D radial velocity measured by a Doppler radar. We demonstrate the performance of our algorithms quantitatively on synthetic radial velocity data and qualitatively on real radial velocity data, obtained from the Doppler radar at Kurnell Radar station, Botany Bay, New South Wales, Australia. Radial velocity can be used to predict the future positions of storms in sequences of Doppler radar datasets.© 2005 Wiley Periodicals, Inc. Int J Imaging Syst Technol, 15, 189–198, 2005     

Atypische Korrodierung der St?rke bei der mit Fusarium roseum und Gibberella Saubinetii befallenen amerikanischen Futtergerste

Zusammenfassung der Untersuchungsergebnisse Nach dem Ergebnis dieser Unterschung kann als festgestellt gelten, daß durch den Befall mit Fusarium roseum bezw. Gibberella Saubinetii die Stärke der befallenen Gerste in einer atypischen Weise korrodiert wird. Die Art dieser Korrodierung unterscheidet sich wesentlich, sowohl von der Korrodierung im keimenden Korn, als auch von der bei starkem Schimmelpilzbefall beobachteten Korrodierung. Die Ursache für die atypische Korrodierung kann in einem örtlichen Nährstoffentzug durch die Pilzhyphen angenommen werden (lokale Frementbildung). Da solche atypisch korrodierte Stärke in den von Fusarium roseum befallenen Teilen eines Kornes immer angetroffen wird, kann diese Veränderung zur Diagnose des Pilzes im Schrot und Mehl mit herangezogen werden.bedeutet mit Abbildungen.