Effect of wall wettability condition on drift-flux parameters in lead–bismuth two-phase flow in circular and annular bubble columns

Lead–bismuth two-phase flow in a cylindrical vessel and annulus was experimentally investigated by varying the surface wettability of the vessel wall. The test section used in this study was a cylindrical stainless vessel with/without inner sleeve to change the hydraulic diameter. Volume-averaged void fraction was measured by varying the surface wettability of the test section, which was enhanced by using a soldering flux. Measured void fraction was compared with existing two-phase flow correlations and with one-dimensional theoretical simulations assuming one-dimensional drift-flux model. From experimental results, measured distribution parameters of the lead–bismuth two-phase flow are much larger than that of ordinary two-phase flow regardless of the surface wettability. In the present work, the one-dimensional analysis was carried out for the cylindrical vessel to reproduce the distribution parameter. From the simulation results, predicted value for the cylindrical vessel showed good agreement with experimental results. However, in annulus, the distribution parameters in annulus were underestimated by the present model. It was suggested that, in case of annulus, steeper void fraction profile might be formed near the inner surface for poor wettability condition.     

Thermal diffusivity and porosity of solid materials by the electromagnetic ultrasonic technique. Part 3—simultaneous measurement of ultrasonic velocity and thermal diffusivity

The objective of this study is to evaluate simultaneously the time dependence of the thermal diffusivity of carbon-carbon composites (C/C composites) and their porosity during heat treatment using the electromagnetic ultrasonic technique. This paper describes two kinds of experiments conducted to confirm the principle for simultaneous measurement of both the ultrasonic velocity (used to evaluate the porosity) and the thermal diffusivity at room temperature. For each material, the samples used in both experiments were identical. The ultrasonic velocity of type 304 stainless steel and its thermal diffusivity were 5.85 km/s and 3.8 mm²/s with precisions of ±1.6 and ±8 percent, respectively. The ultrasonic velocity of a two-dimensional woven C/C composite and its thermal diffusivity were 2.86 km/s and 4.8 mm²/s with precisions of ±5.0 and ±8 percent, respectively. The results appear to indicate that the electromagnetic ultrasonic technique can measure the ultrasonic velocity and the thermal diffusivity simultaneously and that it is also applicable to C/C composites. © 1997 Scripta Technica, Inc. Heat Trans Jpn Res, 25(5): 308–322, 1996     

Sequential study on glutathione peroxidase and selenium contents of human milk

Breast milk samples collected sequentially from five lactating women were analysed for selenium and Se-dependent glutathione peroxidase (GSH-Px), which is the only active form of Se known in man. Both GSH-Px and Se contents of breast milk decreased with increasing time of lactation and reached a plateau at a month post-partum. This sequential change was not due to the Se intake of the mother as reflected in urinary Se content. GSH-Px and Se contents of mature milk were strictly regulated irrespective of the Se intake of the mother. There was a significant positive correlation between GSH-Px and Se contents of breast milk. Mean GSH-Px and Se contents and the proportion of GSH-Px-bound Se content of the total Se content in mature milk were 38.8 U ml-1, 22.5 ng ml-1 and 23.4%, respectively. Preservation of mature milk at -20 degrees C decreased linearly its GSH-Px activity with increasing time at a rate of 5.8 U ml-1 day-1.     

Enzymatic Synthesis of 1‐Alkyl‐2‐hydroxy‐sn‐glycero‐2,3‐cyclic‐phosphate Using a Novel Lysoplasmalogen‐Specific Phopholipase D

Many phospholipase Ds (PLDs) are known to catalyze transphosphatidylation as well as hydrolysis of phospholipids. Transphosphatidylation of lysoplasmalogen (LyPls)‐specific phospholipase D (LyPls‐PLD), which catalyzes hydrolysis of ether lysophospholipids such as LyPls and 1‐hexadecyl‐2‐hydroxy‐sn‐glycero‐3‐phosphocholine (Lyso‐PAF), still remains unclear. This study aims to reveal the transphosphatidylation activity of LyPls‐PLD, that is, the production of cyclic ether lysophospholipid. The enzymatic reaction is conducted in a buffer system, and the reaction products of a novel LyPls‐PLD from Thermocrispum sp. are investigated using mass spectrometry (MS). MS analyses demonstrate the reaction products to consist of 100% 1‐hexadecyl‐2‐hydroxy‐sn‐glycero‐2,3‐cyclic‐phosphate (cLyPA) and choline from Lyso‐PAF; however, 1‐alkenyl‐2‐hydroxy‐sn‐glycero‐2,3‐cyclic‐phosphate from 1‐O‐1′‐(Z)‐octadecenyl‐2‐hydroxy‐sn‐glycero‐3‐phosphocholine and 1‐O‐1′‐(Z)‐octadecenyl‐2‐hydroxy‐sn‐glycero‐3‐phosphoethanolamine is not produced. These results are expected to help in elucidating the catalytic mechanism of LyPls‐PLD, that is, the rate‐limiting step, and indicate LyPls‐PLD to be useful for the one‐pot synthesis of cLyPA. Practical Applications: A novel phospholipase D, LyPls‐PLD, can exclusively synthesize cLyPA from Lyso‐PAF using a one‐step enzymatic reaction without an organic solvent. cLyPA could be expected to show bioactivities similar to those of cyclic phosphatidic acid, which promotes normal cell differentiation, hyaluronic acid synthesis, antiproliferative activity in fibroblasts, and inhibitory activity toward cancer cell invasion and metastasis.     

Sintering Kinetics at Constant Rates of Heating: Effect of Al2O3 on the Initial Sintering Stage of Fine Zirconia Powder

The sinterabilities of fine zirconia powders including 5 mass% Y₂O₃ were investigated, with emphasis on the effect of Al₂O₃ at the initial sintering stage. The shrinkage of powder compact was measured under constant rates of heating (CRH). The powder compact including a small amount of Al₂O₃ increased the densification rate with elevating temperature. The activation energies at the initial stage of sintering were determined by analyzing the densification curves. The activation energy of powder compact including Al₂O₃ was lower than that of a powder compact without Al₂O₃. The diffusion mechanisms at the initial sintering stage were determined using the new analytical equation applied for CRH techniques. This analysis exhibited that Al₂O₃ included in a powder compact changed the diffusion mechanism from grain boundary to volume diffusions (VD). Therefore, it is concluded that the effect of Al₂O₃ enhanced the densification rate because of decrease in the activation energy of VD at the initial sintering stage.     

Deoxidation of Ti Melt by Newly Developed Two-Step Plasma Arc Melting Process Using Hydrogen

Metallurgical and Materials Transactions B - A two-step plasma arc melting process, comprising a first step under Ar-30 pct H2 gas flow and the second step under Ar gas flow, has been...     

Corrosion characteristics of reduced activation ferritic steel, JLF-1 (8.92Cr–2W) in molten salts Flibe and Flinak

Static corrosion tests were performed in molten salts, LiF–BeF₂ (Flibe) and LiF–NaF–KF (Flinak), at 500 °C and 600 °C for 1000 h. The purpose is to investigate the corrosion characteristics of reduced activation ferritic steels, JLF-1 (8.92Cr–2W) in the fluids. The concentration of hydrogen fluoride (HF) in the fluids was measured by slurry pH titration method before and after the exposure. The HF concentration determined the fluoridation potential. The corrosion was mainly caused by dissolution of Fe and Cr into the fluids due to fluoridation and/or electrochemical corrosion. Carbon on the surface might be dissolved into the fluids due to the corrosion, and this resulted to the decrease of carbide on the surface. The corrosion depth of the JLF-1 specimen, which was obtained from the weight losses, was 0.637 μm in Flibe at 600 °C and 6.73 μm in Flinak at 600 °C.     

Polyphasic characterization of two microbial consortia with wide dechlorination spectra for chlorophenols

Two soil-free anaerobic dechlorinating cultures (3-CP and 35-DCP) were enriched from a pentachlorophenol (PCP)-to-phenol dechlorinating soil-dependent culture, using 3-chlorophenol (3-CP) and 3,5-dichlorophenol (3,5-DCP) as specific respective substrates, and characterized polyphasically. Physiological characterization indicated that the 3-CP and 35-DCP cultures had similar features, but with some variations. Both cultures utilized formate or acetate preferably as optimum electron donors for reductive dechlorination, and they shared similar patterns of dechlorination spectra for chlorophenols ranging from mono-CPs to a tetra-CP, with preferred dechlorination pathways in the ortho and meta positions. Alternative electron acceptors such as NO(3)(-) but not SO(4)(2-) inhibited the dechlorination activity in both cultures, while amorphous iron oxides (FeOOH) suppressed dechlorination activity only in the 35-DCP culture. Complete inhibition of dechlorination was observed in both cultures supplemented with chloramphenicol and vancomycin. The addition of 2-bromoethanesulfonate resulted in delayed dechlorination activity in the 35-DCP culture but not in the 3-CP culture; molybdate did not exert any inhibitory effect in either culture. Phylogenetic analysis based on 16S rRNA genes confirmed that the two cultures exhibited similar bacterial species but with varied responsible dechlorinators. Dehalobacter spp. were the likely dechlorinators in the 3-CP culture versus Sulfurospirillum spp. in the 35-DCP culture, with Clostridium and Clostridium-like spp. as candidate dechlorinators in both cultures.