全文获取类型
收费全文 | 1080篇 |
免费 | 53篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 61篇 |
综合类 | 3篇 |
化学工业 | 272篇 |
金属工艺 | 29篇 |
机械仪表 | 25篇 |
建筑科学 | 38篇 |
能源动力 | 50篇 |
轻工业 | 131篇 |
水利工程 | 7篇 |
石油天然气 | 3篇 |
无线电 | 88篇 |
一般工业技术 | 248篇 |
冶金工业 | 31篇 |
原子能技术 | 34篇 |
自动化技术 | 119篇 |
出版年
2024年 | 1篇 |
2023年 | 6篇 |
2022年 | 31篇 |
2021年 | 47篇 |
2020年 | 21篇 |
2019年 | 38篇 |
2018年 | 27篇 |
2017年 | 24篇 |
2016年 | 41篇 |
2015年 | 40篇 |
2014年 | 58篇 |
2013年 | 73篇 |
2012年 | 81篇 |
2011年 | 117篇 |
2010年 | 75篇 |
2009年 | 71篇 |
2008年 | 83篇 |
2007年 | 62篇 |
2006年 | 35篇 |
2005年 | 39篇 |
2004年 | 35篇 |
2003年 | 29篇 |
2002年 | 19篇 |
2001年 | 14篇 |
2000年 | 8篇 |
1999年 | 4篇 |
1998年 | 16篇 |
1997年 | 9篇 |
1996年 | 7篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 3篇 |
1992年 | 4篇 |
1990年 | 1篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有1139条查询结果,搜索用时 15 毫秒
71.
Westerhoff P Mezyk SP Cooper WJ Minakata D 《Environmental science & technology》2007,41(13):4640-4646
Pulse radiolysis experiments were conducted on dissolved organic matter (DOM) samples isolated as hydrophobic and hydrophilic acids and neutrals from different sources (i.e., stream, lake, wastewater treatment plant). Absolute bimolecular reaction rate constants for the reaction of hydroxyl radicals (*OH) with DOM (k*(OH), DOM) were determined. k*(OH, DOM) values are expressed as moles of carbon. Based on direct measurement of transient DOM radicals (DOM*) and competition kinetic techniques, both using pulse radiolysis, the k*(OH, DOM) value for a standard fulvic acid from the Suwannee River purchased from the International Humic Substances Society was (1.60 +/- 0.24) x 10(8) M(-1) s(-1). Both pulse radiolysis methods yielded comparable k*(OH, DOM) values. The k*(OH, DOM) values for the seven DOM isolates from different sources ranged from 1.39 x 10(8) M(-1) s(-1) to 4.53 x 10(8) M(-1) s(-1), and averaged 2.23 x 108 M(-1) s(-1) (equivalent to 1.9 x 10(4) (mgC/L)(-1) s(-1)). These values represent the first direct measurements of k*(OH, DOM,) and they compare well with literature values obtained via competition kinetic techniques during ozone or ultraviolet irradiation experiments. More polar, lower-molecular-weight DOM isolates from wastewater have higher k*(OH, DOM) values. In addition, the formation (microsecond time scale) and decay (millisecond time scale) of DOM* transients were observed for the first time. DOM* from hydrophobic acids exhibited broader absorbance spectra than transphilic acids, while wastewater DOM isolates had narrower DOM* spectra more skewed toward shorter wavelengths than did DOM* spectra for hydrophobic acids. 相似文献
72.
Higuchi M Miyata D Kawamura S Ueda E Imanaka M Tonogai Y 《Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan》2004,45(6):339-343
Daily intakes of 12 phenols which are possible endocrine disruptors were estimated in hospital meals from 2000 to 2001. 4-Nonylphenol (4-NP (mix)) and bisphenol A (BPA) were detected at levels of 5.0 to 19.4 ng/g and 0.2 to 1.1 ng/g, respectively. 4-tert-Butylphenol, 4-n-pentylphenol, 4 -tert-pentylphenol, 4-n-hexylphenol, 4-n-heptylphenol and 4-tert-octylphenol were detected at levels of 0.1 to 2.4 microg/g. The daily intakes of 4-NP (mix) and BPA were 5.8 microg/day and 0.42 microg/day, respectively. The daily intakes of other phenols were less than 1 microg/day. 相似文献
73.
Yan Wu Daisuke Tozawa Tatsuya Ito Tsutomu Tada Keitaro Hitomi 《Journal of Nuclear Science and Technology》2013,50(3):320-327
A crown ether loaded resin was prepared by successive impregnation and fixing the 4′,4′(5″)-di(tert-butylcyclohexano)-18-crown-6 (DtBuCH18C6) and its molecule modifier, 1-dodecanol, onto the porous silica/polymer composite support (SiO2-P particles). The characterization of DtBuCH18C6 loaded resin was examined by thermal gravimetry and differential thermal analysis and electron probe microanalysis. The adsorption behavior of Sr(II), Cs(I), Ru(III), Pd(II), La(III), Nd(III), Sm(III), Gd(III), Zr(IV), and Mo(VI) was investigated by the batch method. Furthermore, the column test for Sr (II) was performed. The batch experiments were carried out by varying the shaking times, HNO3 concentration, and initial concentration of metal ions. A relatively large K d value above 182 cm3/g for Sr(II) was obtained in the presence of 3 M HNO3. In contrast, the K d values of Cs(I), Ru(III), Pd(II), La(III), Nd(III), Sm(III), Gd(III), Zr(IV), and Mo(VI) were considerably lower than 10 cm3/g. The adsorption of Sr(II) was found to be controlled by chemisorption mechanism, and followed a Langmuir-type adsorption equation. The breakthrough curve of Sr(II) had S-shaped profile, and the elution percentage was estimated to be 99.9% by using the eluent of H2O. 相似文献
74.
We investigated the possibility of conjugative plasmid transfer to the predominant bacteria in activated sludge and the factors influencing the transfer frequency in the activated sludge process. We performed conjugative transfers of a self-transmissible, broad-host-range plasmid RP4 from Escherichia coli C600 to activated sludge bacteria by broth mating. Most of the activated sludge bacteria tested could acquire plasmid RP4, although the transfer frequencies varied from 8.8 x 10(-7) to 1.3 x 10(-2) transconjugants per recipient. The transfer frequencies in several strains were similar to, or higher than, that in intraspecific transfer to E. coli HB101. Matings under various environmental conditions showed that factors relevant to physiological activity, such as temperature and nutrient conditions, seemed to affect the transfer frequency. In addition, conjugative transfer was detected even in filtered raw and treated wastewaters. Thus, the predominant activated sludge bacteria seem to have sufficient potential as recipients in conjugative plasmid transfer under the conditions likely to occur in the activated sludge process. Transfer frequency was reduced by agitation in the presence of suspended solid. This may suggest that conjugative plasmid transfer is physically inhibited in aeration tanks. 相似文献
75.
Daisuke Tashima Yoshihiro Hamasuna Daisuke Mishima Seiji Kumagai John D. W. Madden 《IEEJ Transactions on Electrical and Electronic Engineering》2014,9(4):343-350
Electrochemical double‐layer capacitors (EDLCs) are devices that store enormous amounts of charge electrostatically when a potential is applied between electrodes of very high surface area (typically made of porous carbon) and an electrolyte. Wider commercialization of this technology has been held back by the lack of ultralow‐cost electrode materials. We demonstrate that used coffee grounds can be processed to form low‐cost electrodes. The surface and electrochemical characteristics of microporous activated carbons from used coffee grounds (CGCs) were measured. First, optimal times and temperatures for carbonization and activation were identified on the basis of Brunauer–Emmett–Teller (BET) surface area, pore volume, and pore size distribution. Second, CGCs were used as polarized electrodes in EDLCs, whose capacitances were evaluated using cyclic voltammetry. The results show that carbonization for 1 h at 600 °C with a heating rate of 300 °C/h, followed by CO2 activation for 2 h at 1000 °C, affords the highest BET surface area (1867 m2/g) compared to other works. The produced CGCs have many micropores of less than 2 nm across, which contribute to the formation of an electric double layer. Capacitors made using these CGCs show the highest capacitance (103 F/g) in 0.8 M (C2H5)4NBF4/PC as an organic electrolyte, which is much higher than the ∼80 F/g typically used in organic‐electrolyte‐based commercial EDLCs, suggesting that coffee grounds are a useful electrode material. © 2014 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
76.
Maki D Ishii T Sato F Kato Y Yamamoto T Iida T 《Radiation protection dosimetry》2011,144(1-4):222-225
A confocal laser microscope system was developed for the measurement of radiophotoluminescence (RPL) photons emitted from a minute alpha-ray-irradiated area in an RPL glass dosemeter. The system was composed mainly of an inverted-type microscope, an ultraviolet laser, an XY movable stage and photon-counting circuits. The photon-counting circuits were effective in the reduction of the background noise level in the measurement of RPL photons. The performance of this microscope system was examined by the observation of standard RPL glass samples irradiated using (241)Am alpha rays. The spatial resolution of this system was ~ 3 μm, and with regard to the sensitivity of this system, a hit of more than four to five alpha rays in unit area produced enough amount of RPL photons to construct the image. 相似文献
77.
Takashi Soga Akihiro Musa Koki Okabe Kazuhiko Komatsu Ryusuke Egawa Hiroyuki Takizawa Hiroaki Kobayashi Shun Takahashi Daisuke Sasaki Kazuhiro Nakahashi 《Computers & Fluids》2011,45(1):215-221
The building-cube method (BCM) is a new generation algorithm for CFD simulations. The basic idea of BCM is to simplify the algorithm in all stages of flow computation to achieve large-scale simulations. Calculation of a pressure field using the Successive Over Relaxation (SOR) method consumes most of the total execution time required for BCM. In this paper, effective implementations on modern vector and scalar processors are investigated. NEC SX-9 and Intel Nehalem-EX are the latest vector and scalar processors. Those processors have much higher peak performances than their previous-generation processors. However, their memory bandwidth improvement cannot catch up with the performance improvement of processors. This is the so-called memory wall problem. In our paper, we discuss optimization techniques for implementation of the SOR method based on architectural characteristics of these modern processors, and evaluate their effects on the sustained performances of these processors for BCM. 相似文献
78.
Ohmori T Morita H Tanaka M Miyauchi K Kasai D Furukawa K Miyashita K Ogawa N Masai E Fukuda M 《Journal of Bioscience and Bioengineering》2011,111(4):437-442
Rhodococcus jostii RHA1 accumulates chlorobenzoates (CBA) during the degradation of polychlorinated biphenyls (PCBs). CBA degradation is considered one of the rate-limiting steps in the complete degradation of PCBs. To reduce the accumulation of CBAs, the upper pathway enzyme genes for PCB degradation of RHA1 were introduced into a CBA-degrading bacterium, Burkholderia sp. NK8. The resulting recombinant strain exhibited no biphenyl 2,3-dioxygenase (BphA) activity encoded by bphAaAbAcAd genes, which encode the large and small subunits of the terminal oxygenase component and the ferredoxin and reductase subunits responsible for electron transfer from NADH to the large subunit. The remaining enzyme genes involved in the transformation of biphenyl to benzoate, bphB2C1D1, which encode dehydrogenase, ring-cleavage dioxygenase and hydrolase, conferred activities to NK8. To obtain the BphA activity of RHA1 in NK8, sets of BphA genes were constructed by combining the bphAaAbAcAd genes of RHA1 and bphA3A4 of Pseudomonas pseudoalcaligenes KF707, encoding the ferredoxin and reductase subunits. Hybrid derivatives of BphA containing the KF707 bphA3 conferred BphA activity to NK8, and a derivative containing the RHA1 bphAaAb and KF707 bphA3A4 genes exhibited the highest BphA activity. A plasmid containing the RHA1 bphAaAb and KF707 bphA3A4 genes plus the RHA1 bphB2C1D1 genes was constructed and introduced into NK8. The resulting recombinant strain efficiently degraded 2-, 3- and 4-chlorobiphenyls with an apparent reduction in CBA accumulation in comparison to the recombinant mutant strain, which had an insertion in the cbeA gene to inactivate CBA dioxygenase. 相似文献
79.
Masashi Tanaka Daisuke Shimada 《Journal of Superconductivity and Novel Magnetism》2011,24(5):1491-1495
We have carried out point contact tunneling measurements by contacting degenerated GaAs semiconductor to polycrystalline samples
of NdFeAsO1−x
F
x
with T
c=44−51±1.2. The obtained conductance curves have plural structures included in energy region of the superconducting gap. These
structures are seen at almost the same bias positions on every measurement. And as temperature increases, the structures are
smeared out. Thus, the structures are attributed to multiple gap structures. The gap values are Δ
S=6.3±0.3 meV, Δ
L=12.5±0.5 meV and 2Δ
S/k
B
T
c=3.1±0.3, 2Δ
L/k
B
T
c=6.2±0.7. Separately from these multiple gap structures, some fine structures are seen in outer energy region of the gap structures.
We have calculated d2
I/dV
2 and T
c from using conventional s-wave Eliashberg equations by appropriately assuming α
2
F(ω). The phonon positions of the calculated d2
I/dV
2 curve are in quite good agreement with that of experimental result. Moreover, the calculated T
c reproduces the experimental one. 相似文献
80.
Scintillation properties of Tm-doped Lu3Al5O12 single crystals 总被引:1,自引:0,他引:1
Makoto Sugiyama Yutaka Fujimoto Takayuki Yanagida Daisuke Totsuka Yuui Yokota Akira Yoshikawa 《Optical Materials》2011,34(2):439-443
Using the micro-pulling-down (μ-PD) method, Tm-doped Lu3Al5O12 (Tm:LuAG) single crystals were grown to examine their scintillation properties. In transmittance spectra, they exhibited about 80% transparency in the wavelengths longer than 320 nm and five absorption lines due to Tm3+ 4f–4f transitions were observed. 241Am α-ray excited radioluminescence spectra were measured and intense 4f–4f emission peaks were observed with the host emission. When excited by 137Cs γ-Ray to obtain pulse height spectra, Tm 1% doped LuAG showed the highest light yield coupled with a photomultiplier (PMT) or a silicon avalanche photodiode (Si-APD). The light yield was estimated to be 5800 and 7300 photons/MeV for PMT and Si-APD, respectively. Decay time profiles consist of two exponential components and the fast and slow components are considered to be attributed to the host and the combination of the host and Tm3+ 4f–4f emission, respectively. 相似文献