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81.
Transdermal Iontophoretic Delivery of Thyrotropin-Releasing Hormone Across Excised Rabbit Pinna Skin
Enhanced transport of a model peptide drug thyrotropin-releasing hormone (TRH), a tripeptide of molar mass 362 g and a pKa 6.2, through excised rabbit pinna skin was achieved by means of iontophoresis with continuous current or monophase periodically pulsed current. The resulting flux in the steady state was proportional to the applied current density. In the transdermal iontophoretic delivery of TRH, the pulsed iontophoretic flux exceeded that obtained with a continuous current. At a low ionic strength, an increased degree of protonation in TRH increased the rate of permeation. The flux of TRH in a buffer at pH 4 is greater than that at pH 8 when the ionic strength is 0.1 M. At a greater ionic strength, the trend is reversed. The enhanced flux of unprotonated TRH during transdermal iontophoresis is attributed largely to electro-osmotic volume flow. An increased rate of permeation of TRH crossing the skin is achieved at low ionic strength, moderate pH, and a large duly cycle of current; the frequency of pulsed current had no significant influence on the rate of transdermal iontophoretic delivery of TRH. 相似文献
82.
W. W. Gerberich H. Huang W. Zielinski P. G. Marsh 《Metallurgical and Materials Transactions A》1993,24(3):535-543
An interconnected set of observations assesses current equilibrium models of the ductile-brittle-transition temperature (DBTT).
This involvesin situ transmission electron microscopy (TEM) studies of crack-tip dislocations in single and polycrystals and bulk fracture toughness
tests at various temperatures. Beyond KI values of 8 MPa · m1/2 in both iron-base single and polycrystals, large numbers of redundant dislocations are created, as postulated recently by
Weertman. [38] Still, the necessary shielding dislocations, as required by equilibrium, can be detected at values as high
as 20 and 40 MPa · m1/2 byex situ TEM and electron channeling, respectively. In addition, the close approach of dislocations to the crack tip in some of the
studies, as opposed to others, suggests that large dislocation free zones (DFZ) are a thin-film artifact. However, a failure
criterion based partly on the Rice-Thomson model’21 is both consistent with the absence of a large DFZ and observed fracture
toughness variations with test temperature. It is emphasized that this toughness transition is entirely in the semibrittle
regime where cleavage is the failure mode. Nevertheless,K
lc values increase from 3 to 60 MPa·m1/2 with an increase in test temperature.
This article is based on a presentation made in the symposium “Quasi-Brittle Fracture” presented during the TMS fall meeting,
Cincinnati, OH, October 21–24, 1991, under the auspices of the TMS Mechanical Metallurgy Committee and the ASM/MSD Flow and
Fracture Committee. 相似文献
83.
进行了PAA(PolyacrylicAcid)-PSF(Polysulfone)交联复合膜的制备,研究了交联剂、添加剂对膜性能的影响,并通过扫描电镜观察了膜的断面结构.研究了PAA-PSF交联复合膜对低浓度有机醇类水溶液反渗透分离性能.发现对于1000×10-6乙醇水溶液截留率达到66.2%,透过流束可达0.9×10-6(m3·m-2·s-1).随醇的分子量的增加,截留率不断上升,对戊醇的截留率达94.3%,而透过流束则保持相对稳定.对不同结构醇类的分离性能研究表明,截留率存在有:tert->sec->iso->n-的规律. 相似文献
84.
85.
钛容器的特点 总被引:2,自引:1,他引:1
黄嘉琥 《石油化工设备技术》1996,17(5):19-24
根据钛材的化学、物理、力学和工艺性能介绍了钛容器在设计、制造、检验和应用方面的特点。 相似文献
86.
87.
88.
RG Wilde JT Billheimer SJ Germain EA Hausner PC Meunier DA Munzer JK Stoltenborg PJ Gillies DL Burcham SM Huang JD Klaczkiewicz SS Ko RR Wexler 《Canadian Metallurgical Quarterly》1996,4(9):1493-1513
Acyl-CoA:cholesterol acyltransferase (ACAT) is the enzyme largely responsible for intracellular cholesterol esterification. A systemic inhibitor of ACAT is believed to be able to slow or even reverse the atherosclerotic process. Towards that goal, a series of cyclic sulfides, derived from the hetero-Diels-Alder reaction of thioaldehydes with 1,3-dienes, and bearing carboxamide substituents, were prepared and evaluated for in vitro (in several tissues and species) and ex vivo ACAT inhibition. Minor changes in subsequent structure were found to have a significant effect in optimization of the biological activity of this series of compounds. 相似文献
89.
Through rigorous full-wave analysis, the effective dielectric constant, normalized attenuation constant, characteristic impedance, and radiation pattern of two types of conductor-backed coplanar waveguides are obtained. The analytic results show that the leakage effect is not only controlled by the thickness and dielectric constant of the substrate but also by the slot width. The leakage power transforms to a radiation space wave and a surface wave, the transverse electric field diagrams in the substrate and the far-zone radiation pattern verify the leakage phenomenon. The first structure has the maximum radiation intensity in the endfire direction, while the second one which has more leaky waves radiates into the air, is better served as a radiating device. For both structures under the nonleakage condition, the characteristic impedance is sensitive to the change of the strip width but not the slot width. Using these properties, the nonleaky and leaky circuits can exist on the same circuit board by choosing appropriate circuit dimensions 相似文献
90.
研究添加不同含量的Ag对CP276合金的拉伸性能和时效组织的影响。对拉伸强度、延伸率测试及透射电镜观察表明:0.11wt%加入可促进T1相析出,使合金强度值升高;0.35wt%Ag的加入可在时效前期生成富Ag、Mg的稳定的GP区,从而降低合金中Cu的固溶度,阻碍T1相析出,时效后期,GP区分解,生成大量T1相,使合金强度值显著升高。 相似文献