Foams based on low density polyethylene/hectorite nanocomposites: Thermal stability and thermo‐mechanical properties

Novel polymer nanocomposite foams made by a two step compression molding method are analyzed in this article. Nanocomposites of low density polyethylene and an organo‐modified hectorite were first melt compounded and then foamed using a compression molding method. To study the influence of the presence and the amount of hectorite in both mechanical and thermal properties, samples with 3% and 7% content of hectorite were prepared. Polyethylene crystalline characteristics and thermal stability of the samples were studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Mechanical properties of foams and solid nanocomposites were analyzed by using dynamical mechanical analysis (DMA). Thermal expansion of the samples was analyzed by thermomechanical analysis. The results indicate that the exfoliation of hectorite platelets was achieved after the foaming process, but not during the melt mixing step. Foams with hectorite nanoparticles exhibit improved thermal stability and mechanical properties when compared with neat polymeric foams. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Predicting teamwork results from social network analysis

Modelling students' behaviours has reached a status that can only be overcome by improving the ability of predicting the results on teamwork. Indeed, teamwork is an important piece on the learning process, but understanding their mechanisms and predicting the results achieved is far from being solved by traditional classifiers. In this paper, we address the problem of predicting teamwork results, and propose a recommender system that suggests new teams, in the context of a given curricular unit. Any student, who is looking for a team, may use the system; in particular, he may ask for the best team to join, either considering all available colleagues or just the set of his previous teammates. Our system makes use of social network analysis and classification methods as the algorithmic core of the decision‐making process. System evaluation is presented through a set of experimental results, which report the performance of social network analysis and classification algorithms over real datasets.     

Factors influencing the decision to crowdsource: A systematic literature review

Crowdsourcing is currently attracting much attention from organisations for its competitive advantages over traditional work structures regarding how to utilise skills and labour and especially to harvest expertise and innovation. Prior research suggests that the decision to crowdsource cannot simply be based on perceived advantages; rather multiple factors should be considered. However, a structured account and integration of the most important decision factors is still lacking. This research fills the gap by providing a systematic literature review of the decision to crowdsource. Our results identify nine factors and sixteen sub-factors influencing this decision. These factors are structured into a decision framework concerning task, people, management, and environmental factors. Based on this framework, we give several recommendations for managers making the crowdsourcing decision.     

One-Way Functions Using Algorithmic and Classical Information Theories

We prove several results relating injective one-way functions, time-bounded conditional Kolmogorov complexity, and time-bounded conditional entropy. First we establish a connection between injective, strong and weak one-way functions and the expected value of the polynomial time-bounded Kolmogorov complexity, denoted here by?E(K ^t (x|f(x))). These results are in both directions. More precisely, conditions on?E(K ^t (x|f(x))) that imply that?f is a weak one-way function, and properties of?E(K ^t (x|f(x))) that are implied by the fact that?f is a strong one-way function. In particular, we prove a separation result: based on the concept of time-bounded Kolmogorov complexity, we find an interval in which every function?f is a necessarily weak but not a strong one-way function. Then we propose an individual approach to injective one-way functions based on Kolmogorov complexity, defining Kolmogorov one-way functions and prove some relationships between the new proposal and the classical definition of one-way functions, showing that a Kolmogorov one-way function is also a deterministic one-way function. A relationship between Kolmogorov one-way functions and the conjecture of polynomial time symmetry of information is also proved. Finally, we relate?E(K ^t (x|f(x))) and two forms of time-bounded entropy, the unpredictable entropy?H ^unp, in which ??one-wayness?? of a function can be easily expressed, and the Yao⁺ entropy, a measure based on compression/decompression schema in which only the decompressor is restricted to be time-bounded.     

On the design of multi‐rate tracking controllers: Application to rotorcraft guidance and control

This paper presents a new methodology for the design and implementation of gain‐scheduled controllers for multi‐rate systems. The proposed methodology provides a natural way to address the integrated guidance and control problem for autonomous vehicles when the outputs are sampled at different instants of time. A controller structure is first proposed for the regulation of non‐square multi‐rate systems with more measured outputs than inputs. Based on this structure, an implementation for a gain‐scheduled controller is obtained that satisfies an important property known as the linearization property. The implementation resembles the velocity implementation for single‐rate systems. The method is then applied to the problem of steering an autonomous rotorcraft along a predefined trajectory defined in terms of space and time coordinates. By considering a convenient error vector to describe the vehicle's dynamics, the trajectory tracking problem is reduced to that of regulating the error variables to zero. Because of the periodic multi‐rate nature of the onboard sensor suite, the controller synthesis is dealt with under the scope of linear periodic systems theory. Simulation results obtained with a full non‐linear rotorcraft dynamic model are presented and discussed. Copyright © 2010 John Wiley & Sons, Ltd.     

Designing vulnerability testing tools for web services: approach,components, and tools

This paper proposes a generic approach for designing vulnerability testing tools for web services, which includes the definition of the testing procedure and the tool components. Based on the proposed approach, we present the design of three innovative testing tools that implement three complementary techniques (improved penetration testing, attack signatures and interface monitoring, and runtime anomaly detection) for detecting injection vulnerabilities, thus offering an extensive support for different scenarios. A case study has been designed to demonstrate the tools for the particular case of SQL Injection vulnerabilities. The experimental evaluation demonstrates that the tools can effectively be used in different scenarios and that they outperform well-known commercial tools by achieving higher detection coverage and lower false-positive rates.     

Influence of diameter in the Raman spectra of aligned multi-walled carbon nanotubes

Aligned multi-walled carbon nanotubes (MWCNTs) were produced with different diameters, according to the thickness of Ni catalyst layer, by microwave plasmas enhanced chemical vapor deposition, in N₂/H₂/CH₄ environment. Raman spectroscopy, performed both on top and lateral surfaces, revealed that the relative intensity of the G′ band and the G and G′ bandwidths have high sensitivity to tube diameter distribution and also to structural variations along the tube axis. The D band present a distinct behavior: I_D/I_G is sensitive to structural organization, particularly along tube axis, while D bandwidth is sensitive to tube diameter distribution. This result may indicate D bandwidth as a parameter to correlate to the diameter of the aligned MWCNTs.     

Post-cracking behaviour of steel fibre reinforced concrete

Recently, RILEM TC 162-TDF has proposed equivalent,f _eq , and residual,f _R , flexural tensile strength parameters to characterize and simulate the post-cracking behaviour of steel fibre reinforced concrete (SFRC) structures. In the current work, more than two hundred flexural tests are carried out according to the RILEM TC 162-TDF recommendations and the corresponding values off _eq andf _R parameters are evaluated. In series of specimens reinforced with fibres of a distinct length/diameter ratio, similar values off _eq andf _R parameters were obtained in these series. Although a strong correlation betweenf _eq andf _R was determined, a larger scatter off _R values was observed thereby revealingf _eq to be more appropriate for design purposes. A numerical strategy involving a cross sectional layered model and an inverse analysis was developed to evaluate the post-cracking stress-strain and the stress-crack opening diagrams for the tested SFRC. This strategy was also used to determine a relation between the post-cracking strain, ɛ ^pcr , and the crack opening displacement,w, (ɛ ^pcr =w/L _p ) which is useful for evaluating the crack opening when numerical strategies based on a stress-strain approach are used. The obtainedL _p values range from half the specimen cross section height to half the distance between the tip of the notch and the top of the cross section.

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Résumé Récemment, pour caractériser et simuler le comportement post-fissuration en traction du béton renforcé des fibres d'acier, la Commission Technique 162-TDF de la RILEM a proposé des paramètres désignés par résistance équivalente, f_eq, et résistance résiduelle, f_R, à la contrainte en flexion. Dans le travail présent, des valeurs de ces paramètres sont obtenues sur plus de deux cents essais de flexion effectués en accord avec les recommandations du TC 162-TDF de la RILEM. Des valeurs semblables de f_eq et f_R ont été obtenues dans des séries d'éprouvettes renforcées avec des fibres d'un rapport longueur/diamètre distinct. Bien qu'une forte corrélation entre f_eq et f_R ait été déterminée, une plus grande dispersion de valeurs du f_R a été observée, en démontrant que f_eq est plus approprié pour les buts du projet. Pour évaluer les diagrammes contrainte-déformation et contrainte-ouverture après fissuration, une stratégie numérique a été développée, en utilisant un modèle de section et en effectuant une analyse inverse. Cette stratégie a aussi été utilisée pour déterminer une relation entre la contrainte après fissuration, ɛ ^pcr , et l'ouverture de fissure, w, (ɛ ^pcr =w/L _p ) utile pour évaluer l'ouverture de la fissure quand les stratégies numériques sont basées sur une approche contrainte-déformation. Les valeurs de L_p obtenues ont varié entre la demi-hauteur de la section de l'éprouvette et la demi-distance entre l'extrémité de l'entaille et le sommet de la section.

     

An application framework for developing collaborative handheld decision-making tools

This paper describes an application framework supporting collaborative handheld decision-making (CHDM). The main characteristics of the framework are: (1) extensive usage of visual elements and gestures; and (2) independence from specific decision-making methods, processes and tasks. The research departed from the analysis and systematisation of several CHDM scenarios, highlighting repeatable behaviour across multiple decision-making contexts. From these scenarios, we distilled a coherent set of common functional requirements organised in three main categories: process, macro- and micro-functionality. The proposed framework has been validated at length through the development of several CHDM tools. Six different tools are described in the paper. The main contribution of this work is a common foundation for developing CHDM tools.