Examining the ecological consequences of restoring flow intermittency to artificially perennial lowland streams: Patterns and predictions from the Broken—Boosey creek system in northern Victoria,Australia

The reinstatement of natural flow regimes is a rapidly emerging issue in river restoration worldwide. In northern Victoria, Australia, efforts are presently underway to restore a natural, intermittent flow regime to several streams which have received perennial diversions for both irrigation and stock and domestic water‐supplies for over 100 years. A pipeline to deliver water to landholders will significantly reduce transmission losses throughout the system allowing irrigation canals and diversion weirs to be decommissioned. The motivation for flow alteration in this system lies primarily in reducing inefficiencies in water delivery which, in turn, will be used to meet escalating demands on water resources. The ecological impact of the flow regime shift on these streams is likely to be substantial. This study utilized an existing artificial hydrological gradient (from perennial to intermittent) in two creek systems, to explore relationships between flow regime and a range of ecological variables. These data provide a benchmark against which to assess ecological changes once flow has been altered and form the basis for predicting changes that can assist future management decisions. Data collected from 10 sites across a strong hydrological gradient detected clear differences in geomorphology, water quality and biotic assemblages (macrophytes, macroinvertebrates and fish). By examining the relationship between flow regime and the distribution of biota we identify both the positive and negative outcomes of restoring naturally intermittent flow regimes within artificially perennial lowland streams. The reinstatement of intermittent flow regimes in artificially perennial streams will continue in many parts of the world as water delivery via these systems becomes increasingly uneconomical. While flow restoration may in principle be regarded as a positive step, these findings emphasize the need to consider fully the ecological consequences of restoring historical hydrological regimes to streams within the context of other human induced catchment disturbances. Copyright © 2009 John Wiley & Sons, Ltd.     

Encoding Information on the Excited State of a Molecular Spin Chain

The quantum states of nano-objects can drive electrical transport properties across lateral and local-probe junctions. This raises the prospect, in a solid-state device, of electrically encoding information at the quantum level using spin-flip excitations between electron spins. However, this electronic state has no defined magnetic orientation and is short-lived. Using a novel vertical nanojunction process, these limitations are overcome and this steady-state capability is experimentally demonstrated in solid-state spintronic devices. The excited quantum state of a spin chain formed by Co phthalocyanine molecules coupled to a ferromagnetic electrode constitutes a distinct magnetic unit endowed with a coercive field. This generates a specific steady-state magnetoresistance trace that is tied to the spin-flip conductance channel, and is opposite in sign to the ground state magnetoresistance term, as expected from spin excitation transition rules. The experimental 5.9 meV thermal energy barrier between the ground and excited spin states is confirmed by density functional theory, in line with macrospin phenomenological modeling of magnetotransport results. This low-voltage control over a spin chain's quantum state and spintronic contribution lay a path for transmitting spin wave-encoded information across molecular layers in devices. It should also stimulate quantum prospects for the antiferromagnetic spintronics and oxides electronics communities.     

Controlled Individual Skyrmion Nucleation at Artificial Defects Formed by Ion Irradiation

Magnetic skyrmions are particle‐like deformations in a magnetic texture. They have great potential as information carriers in spintronic devices because of their interesting topological properties and favorable motion under spin currents. A new method of nucleating skyrmions at nanoscale defect sites, created in a controlled manner with focused ion beam irradiation, in polycrystalline magnetic multilayer samples with an interfacial Dzyaloshinskii–Moriya interaction, is reported. This new method has three notable advantages: 1) localization of nucleation; 2) stability over a larger range of external field strengths, including stability at zero field; and 3) existence of skyrmions in material systems where, prior to defect fabrication, skyrmions were not previously obtained by field cycling. Additionally, it is observed that the size of defect nucleated skyrmions is uninfluenced by the defect itself—provided that the artificial defects are controlled to be smaller than the inherent skyrmion size. All of these characteristics are expected to be useful toward the goal of realizing a skyrmion‐based spintronic device. This phenomenon is studied with a range of transmission electron microscopy techniques to probe quantitatively the magnetic behavior at the defects with applied field and correlate this with the structural impact of the defects.     

Kinematic calibration of Orthoglide-type mechanisms from observation of parallel leg motions

The paper proposes a new calibration method for parallel manipulators that allows efficient identification of the joint offsets using observations of the manipulator leg parallelism with respect to the base surface. The method employs a simple and low-cost measuring system, which evaluates deviation of the leg location during motions that are assumed to preserve the leg parallelism for the nominal values of the manipulator parameters. Using the measured deviations, the developed algorithm estimates the joint offsets that are treated as the most essential parameters to be identified. The validity of the proposed calibration method and efficiency of the developed numerical algorithms are confirmed by experimental results. The sensitivity of the measurement methods and the calibration accuracy are also studied.     

Characterisation and removal of recalcitrants in reverse osmosis concentrates from water reclamation plants

Water reclamation plants frequently utilise reverse osmosis (RO), generating a concentrated reject stream as a by-product. The concentrate stream contains salts, and dissolved organic compounds, which are recalcitrant to biological treatment, and may have an environmental impact due to colour and embedded nitrogen. In this study, we characterise organic compounds in RO concentrates (ROC) and treated ROC (by coagulation, adsorption, and advanced oxidation) from two full-scale plants, assessing the diversity and treatability of colour and organic compounds containing nitrogen. One of the plants was from a coastal catchment, while the other was inland. Stirred cell membrane fractionation was applied to fractionate the treated ROC, and untreated ROC along with chemical analysis (DOC, DON, COD), colour, and fluorescence excitation-emission matrix (EEM) scans to characterise changes within each fraction. In both streams, the largest fraction contained <1 kDa molecules which were small humic substances, fulvic acids and soluble microbial products (SMPs), as indicated by EEM. Under optimal treatment conditions, alum preferentially removed >10 kDa molecules, with 17-34% of organic compounds as COD. Iron coagulation affected a wider size range, with better removal of organics (41-49% as COD) at the same molar dosage. As with iron, adsorption reduced organics of a broader size range, including organic nitrogen (26-47%). Advanced oxidation (UV/H₂O₂) was superior for complete decolourisation and provided superior organics removal (50-55% as COD).     

Sizing optimization of a stand-alone street lighting system powered by a hybrid system using fuel cell,PV and battery

Currently commercialised stand-alone street lighting systems based on the classical configuration coupling photovoltaic cells (PV) and battery cannot work all the year round in regions that are far from the equator. To improve the classical system, a hybrid system coupling a PV, a battery and a fuel cell is proposed. However, the sizing method of hybrid systems is a key issue in obtaining the cheapest system. To optimise the system, an original time-saving method is applied. Two optimization methods are used: first the genetic algorithms, then the simplex algorithms. A simulation model is used to evaluate the validity of the different hybrid configurations. After presenting the problem of stand-alone street lighting, the optimization methodology and the simulation model are detailed. Finally, an optimal configuration is obtained and shows that a 60 W street light would cost 7150€ with a lifetime of 25 years. The optimised parameters are also given and analysed.     

Increased throughput for process chromatography using constraineddeconvolution

Signal restoration using Jansson's method of constrained deconvolution was investigated and tested to deconvolve and thereby resolve severely overlapped gas chromatographic peaks. The results of this technique were compared to those obtained with an instrument that uses a longer column that already produces fully resolved peaks. Jannson's deconvolution method enabled significant resolution improvement at a minimal cost in computational time. Thus, for a given amount of peak resolution, this technique increased the instrument's throughput by 10 times. Test results show that Jansson's method provides similar measurement accuracies and variances as those obtained on an instrument using a longer column     

Asbestos corrosion study in a caustic potash solution at several temperatures

Corrosion of chrysotile asbestos tissue (diaphragm material) was determined at 115–200°C in pressure vessels (1–20 bars). These tests have shown the good shape of this asbestos material for 2000/h with an unchanged solution of potash at 200°C under a 20 bars pressure, and a progressive elimination of the silica when potash solution is renewed and partial destruction of the samples.