Aluminum‐enhanced alkali diffusion from float glass to PVD‐sputtered silica thin films

Interdiffusion processes between aluminum enriched PVD‐sputtered silica thin films and industrial float soda‐lime silicate glass substrates are quantitatively studied using SIMS analysis. Heat treatments are performed at temperatures close or above the glass transition temperature of the float glass. Aluminum doping of the film is shown to strongly increase the migration of alkali from the glass substrate to the silica thin film. In particular the final alkali content in the film exhibits a linear scaling with the aluminum concentration. An interdiffusion process is evidenced between bulk alkali ions and protons originating from a significant water content in the as‐deposited silica film. Experimental measurements of sodium concentration are shown to be consistent with a simple thermodynamic model based on the equilibration of the activity of sodium between the film and the glass substrate.     

Non‐Covalent Functionalization of Graphene Using Self‐Assembly of Alkane‐Amines

A simple, versatile method for non‐covalent functionalization of graphene based on solution‐phase assembly of alkane‐amine layers is presented. Second‐order Møller–Plesset (MP2) perturbation theory on a cluster model (methylamine on pyrene) yields a binding energy of ≈220 meV for the amine–graphene interaction, which is strong enough to enable formation of a stable aminodecane layer at room temperature. Atomistic molecular dynamics simulations on an assembly of 1‐aminodecane molecules indicate that a self‐assembled monolayer can form, with the alkane chains oriented perpendicular to the graphene basal plane. The calculated monolayer height (≈1.7 nm) is in good agreement with atomic force microscopy data acquired for graphene functionalized with 1‐aminodecane, which yield a continuous layer with mean thickness ≈1.7 nm, albeit with some island defects. Raman data also confirm that self‐assembly of alkane‐amines is a non‐covalent process, i.e., it does not perturb the sp² hybridization of the graphene. Passivation and adsorbate n‐doping of graphene field‐effect devices using 1‐aminodecane, as well as high‐density binding of plasmonic metal nanoparticles and seeded atomic layer deposition of inorganic dielectrics using 1,10‐diaminodecane are also reported.     

GC/MS profiling of gamma-hydroxybutyrate and precursors in various animal tissues using automatic solid-phase extraction. Preliminary investigations of its potential interest in postmortem interval determination

To quantify gamma-hydroxybutyrate (GHB) and its physiological metabolites, gamma-aminobutyric acid (GABA), 1,4-butanediol (1,4-BD), and gamma-butyrolactone (GBL) in various animal tissues (kidney, muscle, heart, liver, blood, brain cortex, thalamus, hypothalamus, hippocampus, or pons), an original gas chromatographic/mass spectrometric method with a automated solid-phase extraction by Oasis MCX cartridges on a Gilson Aspec Xli was developed. Using such apparatus allowed the limit of detection (LOD) of target compounds to be significantly lowered (LOD: 0.027, 0.025, and 5.7 microg/mL for GHB, 1,4-BD, and GABA, respectively, in 200 microL or microg of sample). After validation of each analytical step, the satisfactory performances of the apparatus in conjunction with the rapidity and ease of the extraction step make it suitable for simultaneous assay of GHB, 1,4-BD, GBL, and GABA. The method was used to test the correlation between GHB levels in tissues obtained at different times after death of male Sprague-Dawley rats and the postmortem interval. Preliminary results show a linear increase of GHB levels in relation to time of death in thoracic blood and central nervous system of animals kept at 15 and 20 degrees C.     

Magnitude and direction of motion with speckle correlation and the optical fractional Fourier transform

The optical fractional Fourier transform (OFRT) in combination with speckle photography has previously been used to measure the magnitude of surface tilting and translation. Previous OFRT techniques used to determine motion have not been able to discern the direction of the tilt and translation. A simple new approach involving use of correlation is presented to overcome this limitation. Controlled variation of the minimum resolution and dynamical range of measurement is demonstrated. It is then experimentally confirmed that if a rigid body's motion is captured by two OFRT systems of different orders, the direction and magnitude of both the tilting and the in-plane translation motion of the body can be independently determined without a priori knowledge. The experimental results confirm the validity of previous theoretical predictions.     

Modelling mechanical properties of spruce and Douglas fir timber by means of X-ray and grain angle measurements for strength grading purpose

This study proposes a model using data from a scanner (X-ray and grain angle measurements) to perform strength grading. The research also includes global measurements of modulus of elasticity (obtained by vibrations and ultrasound methods), static bending stiffness and bending strength of 805 boards of Douglas fir and 437 boards of spruce. This model can be used in an industrial context since it requires low computational time. The results of this study show that the developed model gives better results than the global non-destructive measurements of the elastic modulus commonly used in the industry. It also shows that this improvement is particularly higher in the case of Douglas fir than for spruce. The comparison has been made on both the quality of the mechanical properties assessment and on the improvement of the grading process according to the European standards by using different index.     

Proposition of a New Severity Analysis Based on ‘Shake’ Detection: Example of the Vatry Airport Tarmac

In packaging science, the study of transport is important in determining the viability of a package/product pair. Many load breaks occur (e.g. handling and storage) along a supply chain. Transport also generates various physical stresses (e.g. shocks, shakes and vibrations). These physical phenomena can be recorded using a variety of customized sensors (e.g. tri‐axial accelerometers, temperature sensors and pressure sensors). This study focuses on a transport phase that has not been studied in depth to date. Transportation operations on tarmacs include many handling and transportation machines, which are characterized by typical constraints that are often more stringent than airlift phase constraints. For comparison, acceleration distributions were estimated and analysed for the tarmac phase and road phase. Severity indicators were calculated based on existing methods. The second part of this study addresses the study of shakes. The shake distributions at 90 and 95% were another indicator of the shakes' severity and probability of occurrence. These elements allow us to characterize the impact of the tarmac area during air transport.     

Kinematic calibration of Orthoglide-type mechanisms from observation of parallel leg motions

The paper proposes a new calibration method for parallel manipulators that allows efficient identification of the joint offsets using observations of the manipulator leg parallelism with respect to the base surface. The method employs a simple and low-cost measuring system, which evaluates deviation of the leg location during motions that are assumed to preserve the leg parallelism for the nominal values of the manipulator parameters. Using the measured deviations, the developed algorithm estimates the joint offsets that are treated as the most essential parameters to be identified. The validity of the proposed calibration method and efficiency of the developed numerical algorithms are confirmed by experimental results. The sensitivity of the measurement methods and the calibration accuracy are also studied.     

Local strain measurements of yarns inside of 3D warp interlock fabric during forming process

The final geometry of 3D warp interlock fabric needs to be check during the 3D forming step to ensure the right locations of warp and weft yarns inside the final structure. Thus, a new monitoring approach has been proposed based on sensor yarns located in the fabric thickness. To ensure the accuracy of measurements, the observation of the surface deformation of the 3D warp interlock fabric has been joined to the sensor yarns measurements. At the end, it has been revealed a good correlation between strain measurement done globally by camera and locally performed by sensor yarns. Additionally, sensor yarns located in the two directions of the 3D warp interlock fabric have revealed a different forming behaviour depending on the architecture and the different slope values of the punch.     

Template-assisted synthesis of high packing density SrLi2Ti6O14 for use as anode in 2.7-V lithium-ion battery

SrLi₂Ti₆O₁₄ has been prepared by using mesoporous TiO₂ brookite as a template and reactant. The prepared particles retained the rounded shape of the precursor, leading to high dispersivity and high packing density. The material has been further electrochemically characterized in both half and full cells. It shows good cycling stability and rate capability. A 2.7-V cell has been built by combining a SrLi₂Ti₆O₁₄ anode with a 4-V spinel cathode of LiMn₂O₄. This cell has a higher voltage compared to the 2.5-V LiMn₂O₄/Li₄Ti₅O₁₂ system.