高纯锗探测器的快定时性能及其应用

为了将高纯锗（ＨＰＧｅ）探测器用于快定时的物理实验中，本实验研究厂影响高纯锗探测器定时谱仪时间性能的各种因素，找出了获得谱仪最小时间分辨的各种最佳参数。并建立了分辨时间为４．１９ｎｓ，能量分辨率为２０ｋｅＶ，微分非线性好于±２．０％，计效率可承受１２０×１０￣３ｓ￣（－１）的时间微分扰动角关联谱仪。利用此谱仪，以￣（２０４）Ｂｉ为探针核，研究了Ｂｉ系高温超导的微观机理，取得了较好的结果。     

A polymerizable photoredox initiation system for vinyl photopolymerization

A polymerizable photoredox system consisting of 4-methacryl oxbenzophenone (MABP) and N,N-dimethlaminoethyl methacrylate (DMAEMA) used for the photopolymerization of acrylonitrile (AN) was studied. It was found that the polymerization rate is proportional to the 0.93th power for the AN concentration, the 0.28th power for the MABP concentration, and the 0.25th power for the DMAEMA concentration. The overall activation energy of the polymerization obtained is 30.43 kJ/mol. The recorded ESR spectrum indicates that the excited-state MABP abstraets hydrogen mainly from the methyl group of the dimethylamino moiety. The comparison of the initiation ability of polymeric MABP or polymeric DMAEMA with their monomeric forms has also been done and the results indicate that in good solvents P (MABP) has a much higher initiation ability than that of monomeric MABP, but monomeric DMAEMA and P (DMAEMA) display almost the same initiation ability. In poor solvent, the initiation ability of P (MABP) is not so obviously higher than that in good solvents. The result of UV analysis of P (AN) initiated by the MABP–DMAEMA system indicates that both MABP and DMAEMA not only initiate the photopolymerization of AN, but also enter into P (AN) polymer chains. © 1994 John Wiley & Sons, Inc.