Influence of NaCl on Granulometric Characteristics and Polymorphism in Batch‐Cooling Crystallization of Glycine

The effect of NaCl added in different quantities on thermodynamic properties, granulometric characteristics, and structure of glycine in a crystallization process was investigated. Solubilities of α‐ and γ‐polymorphs in the presence of varying amounts of NaCl were analyzed. In order to examine the impact of the additive on granulometric properties of glycine, crystal morphology was examined by observing crystals under a scanning electron microscope. Crystal size distribution was determined by sieve analysis. By X‐ray diffraction analysis, the critical concentration of NaCl at which the structure of glycine changed, could be defined. The purity of obtained polymorphs was confirmed by Fourier transform infrared spectroscopy.     

Study of the dielectric relaxation of poly(phenylpropyl acrylate) and poly(phenylpropyl methacrylate): effect of slight differences in chemical structure

A comparative study of the dielectric relaxational behaviour of two structurally close polymers, containing aromatic side groups, was carried out in order to analyse how slight differences in the chemical structure affect the molecular responses to perturbation field. Specifically, poly(phenylpropyl acrylate) (P3Ph1PA) and poly(phenylpropyl methacrylate) (P3Ph1PM) were studied using differential scanning calorimetry and dielectric relaxation spectroscopy in the frequency range 10^?2–10⁶ Hz and temperature window of ?80 to 120 °C. Both techniques show one glass–rubber transition for P3Ph1PA and two for P3Ph1PM, which evidence the great effect of the methyl groups on the segmental motions of the polymer. Phenomenological analysis of the data was carried out in order to establish the strength, width and fragility parameters of the glass–rubber transitions. In the case of P3Ph1PA, the strength is found to be larger than for P3Ph1PM, pointing out that the methyl group disturbs the mobility. Conductive processes dominate the dielectric spectra at high temperatures and low frequencies. © 2015 Society of Chemical Industry     

On emulated nonlinear reduced-order observers for networked control systems

We consider a general class of nonlinear reduced-order observers and show that the global asymptotic convergence of the observation error in the absence of network-induced constraints is maintained for the emulated observer semiglobally and practically (with respect to the maximum allowable transmission interval) when system measurements are sent through a communication channel. Networks governed by a Lyapunov uniformly globally asymptotically stable protocol are investigated. Our results can be used to synthesize various observers for networked control systems for a range of network configurations, as we illustrate it by considering classes of immersion and invariance observers which include the circle-criterion observers.     

Influence of thermal treatment on structure and microhardness of Fe75Ni2Si8B13C2 amorphous alloy

Correlation between hardness of amorphous Fe₇₅Ni₂Si₈B₁₃C₂ alloy and thermally induced structural transformations has been investigated by measuring microhardness in a series of samples heated at different temperatures from 25 to 1000 °C. The alloy has a relatively high hardness in the amorphous state, due to its chemical composition involving silicon, boron and carbon. As the alloy begins to crystallize, microhardness increased and reached a plateau in 500–650 °C temperature region, due to formation composite structure involving the small nanocrystals of α-Fe(Si) and Fe₂B phases dispersed in the amorphous matrix. After treatment at higher temperatures, the nanocomposite structure is replaced by a more granulated structure, leading to decline in microhardness.