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21.
Enhanced thermal stability of biomedical thermoplastic polyurethane with the addition of cellulose nanocrystals 下载免费PDF全文
Freeze‐dried cellulose nanocrystals (CNCs) were dispersed in the thermoplastic polyurethane [Pellethane 2363‐55D (P55D)] by a solvent casting method to fabricate CNC‐reinforced nanocomposites. This study demonstrated that the addition of small amounts (1–5 wt %) of CNCs to P55D increased the thermal degradation temperature while maintaining a similar stiffness, strength, and elongation of the neat P55D. CNC additions to P55D did not alter the glass‐transition temperature, but the onset decomposition temperature was shifted from 286 to 327°C when 1 wt % CNCs was dispersed in the matrix. The higher onset decomposition temperature was attributed to the formation of hydrogen bonds between the hydroxyl groups on the CNC surface and urethane groups in the hard block of P55D. The ultimate tensile strength and strain to failure (εf) of the nanocomposites were minimally affected by additions up to 5 wt % CNCs, whereas the elastic modulus was increased by about 70%. The observation that εf was unchanged with the addition of up to 5 wt % CNCs suggested that the flow/sliding of the hard blocks and chains were not hindered by the presence of the CNCs during plastic deformation. The ramifications of this study was that CNC additions resulted in wider processing temperatures of P55D for various biomedical devices while maintaining a similar stiffness, strength, and elongation. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41970. 相似文献
22.
Nerea Burgos María Paulis M. Mirari Antxustegi Mario Montes 《Applied catalysis. B, Environmental》2002,38(4):251-258
Pt impregnated metallic monoliths prepared from anodised aluminium foils were tested to study their catalytic activity in complete oxidation of volatile organic compound (VOC) mixtures. The VOCs oxidised were 2-propanol, toluene, methyl ethyl ketone (MEK), acetone and their mixtures. Complete oxidation was obtained in all cases except for the case of 2-propanol, where acetone was found as an oxidation intermediate. Even if the adsorption of the VOC on the Al2O3 is governed by its polarity, the reactivity is mainly affected by the competition of the oxygen atoms chemisorbed on the Pt particles. 相似文献
23.
Karim Mtalsi Taib Jei Mario Montes Souad Tayane 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2001,76(2):128-138
A series of mixed zinc–aluminum phosphate (ZnAlP) catalysts containing 40–90 aluminum molar % were synthesized by a coprecipitation method and characterized by nitrogen adsorption–desorption, X‐ray diffraction, FTIR spectroscopy, thermogravimetric analysis (TGA), differential thermal analysis (DTA), diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and temperature programmed desorption (TPD) of ammonia. The presence of aluminum greatly affected the surface properties of Zn3(PO4)2 by delaying the crystallization process of Zn3(PO4)2. All amorphous samples were shown to be mesoporous and they contained two types of aluminum surface hydroxyl groups and one type of phosphorus hydroxyl group, as shown by DRIFT spectra. The specific surface area and the acidity of ZnAlP increased on increasing the aluminum content. On the other hand, a great difference in the texture and the concentration of surface acid sites was found by changing the precipitating agent and calcination temperature. Thus these factors also play an important role in the final properties of these catalysts. © 2001 Society of Chemical Industry 相似文献
24.
FAME Production and Fatty Acid Profiles from Moist Chlorella sp. and Nannochloropsis oculata Biomass 下载免费PDF全文
Rui C. M. Alves Sobrinho Laércio Vauchinski Renata Rodrigues de Moura Ednei G. Primel Paulo C. V. Abreu Marcelo G. Montes D’Oca 《Journal of the American Oil Chemists' Society》2015,92(3):423-430
In the present study, we investigated the production of fatty acid methyl esters (FAME) from moist Chlorella sp. and Nannochloropsis oculata biomass using a hydrolysis–esterification process. Additionally, we evaluated for the first time the fatty acid profile before and after this process. Hydrolysis of the lipid fraction was performed on a moist biomass in the presence of differing amounts of an acid catalyst in both 50 and 100 % w/w water relative to the biomass. The esterification of the crude extracts of the free fatty acids (FFA) was then investigated. The experiments show that in the presence of 50 % w/w water relative to the biomass, the hydrolysis–esterification process results in higher FFA and FAME yields. The analysis of the fatty ester profiles did not reveal any degradation of the FFA from the microalgae biomass under the hydrolysis–esterification conditions. The results were compared with both extraction–transesterification and direct transesterification processes using dry biomass. The extraction–transesterification and hydrolysis–esterification processes resulted in similar FAME yields and similar profiles of the fatty esters from dry and moist biomass materials, respectively. 相似文献
25.
Back Cover: Lipopeptide Nanoparticles: Development of Vaccines against Hookworm Parasite (ChemMedChem 10/2015) 下载免费PDF全文
26.
SPEEK/cSMM membrane for simultaneous electricity generation and wastewater treatment in microbial fuel cell 下载免费PDF全文
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28.
FLOCCULATION/COAGULATION OF NATURAL ORGANIC MATTER FOR PRETREATMENT OF WATER AND WASTE WATER 下载免费PDF全文
Characterization of water, waste water and natural organic matter are involved in this paper, and as well as the features of flocculation and coagulation for removing natural organic matter from water and waste water Novel flocculant and coagualant is strongly asked for improving removal efficiency and environment friendly. Enhanced coagulation is introduced to meet the experimental and practical requirement. 相似文献
29.
Martha Cobo Juan A. Conesa Consuelo Montes de Correa 《Applied catalysis. B, Environmental》2009,92(3-4):367-376
2-Propanol and molecular H2 (in methanol (MeOH) and MeOH–water) were examined as reducing agents for the liquid phase hydrodechlorination (HDC) of dioxins over 2 wt.% Pd/γ-Al2O3. Different amounts of NaOH were added to the reaction mixtures. The 2-propanol and H2(g)/MeOH systems presented similar HDC activity. Notwithstanding, Pd sintering and graphitic carbon directly bonded to Pd on catalyst surface was observed on samples used with H2(g)/MeOH. The addition of water to H2(g)/MeOH decreased Pd sintering and favored dissolution of sodium compounds. However, dioxin degradation efficiency diminished. By contrast, 2-propanol acting both as reducing agent and solvent provided hydrogen to the HDC reaction, avoided metal sintering and Pd–C formation. Besides, almost complete dioxin degradation under mild reaction conditions was obtained. Kinetic experiments of dioxin HDC with 2-propanol showed a maximum net reaction rate and turnover frequency (TOF) for a given initial concentration of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). After that value, both reaction rate and TOF decreased. On the other hand, reaction rates and TOFs of dioxin-like polychlorinated biphenyls (DL-PCBs) linearly increased with concentration. 相似文献
30.
O. Gonzlez H. Prez P. Navarro L.C. Almeida J.G. Pacheco M. Montes 《Catalysis Today》2009,148(1-2):140
To obtain a novel, active and selective to diesel catalytic material for syngas processing via Fischer–Tropsch synthesis (FTS), a series of 20 wt.% cobalt catalysts has been prepared by impregnation of a mesoporous molecular sieve based on silica (SBA-15, Al-MCM-41, INT-MM1), and a commercial amorphous silica for comparison purposes. All materials were characterized by several physico-chemical techniques: AAS, BET surface area, XRD, TPR, and H2 chemisorption with pulse reoxidation and finally their reactivity on the FTS reaction was evaluated at 523 K, 10 bar, and H2/CO = 2. Catalytic and characterization results show a great influence of mesoporous support porosity on the structure, reducibility, and FTS catalytic behavior of cobalt oxide species supported over these ordered materials. It was found that the size of supported cobalt oxide species formed during the calcination step increased with the average pore size (Dp) of the mesoporous support. Thus, the catalyst with larger Co oxide species located in wide pore silica showed to be easily reducible, more active and very selective toward the diesel fraction. It seems to be the case of the Co/SBA-15 solid, which showed to be the most active solid (XCO 63%) when the same mass of catalyst was used. Under CO iso-conversion conditions (XCO 40%), Co/SBA-15 was more selective toward the formation of C5+ hydrocarbons (80%, α = 0.76) and less selective to CH4 (15%). On the contrary, when Al-MCM-41 and INT-MM1 were used as supports, a lower selectivity to C5+ and CO conversion and higher CH4 selectivity (20%) were observed due to the decrease of Dp, of the cobalt oxide species size and the reducibility degree of such species. 相似文献