Study of polyaniline polyacrylamide composites by positron annihilation technique

Polyaniline doped with nonoxidizing Bronsted acids is recognized as a conducting material, as its electrical conductivity changes with percentage of doping. In the present work, different percentages of doped polyaniline were blended with polyacrylamide and their electrical conductivities as well as the positron annihilation lifetimes were measured. Analysis of data yielded three lifetime components. It was observed that the value of the short lifetime component remained constant for doping concentration, whereas that of the intermediate component τ₂ decreased. The relative intensity pertaining to τ₂, however, increased with the increase in doped PANI concentration. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 930–933, 2003     

Al2O3─SiC Composites from Aluminosilicate Precursors

Al₂O₃ and SiC composite materials have been produced from mixtures of aluminosilicates (both natural minerals and synthetic) and carbon as precursor materials. These composites are produced by heating a mixture of kaolinite (or synthetic aluminosilicates) and carbon in stoichiometric proportion above 1550°C, so that only Al₂O₃ and SiC remain as the major phases. A similar process has also been used for synthesizing other composite powders having mixtures of Al₂O₃, SiC, TiC, and ZrO₂ in different proportions (all compounds together or selective mixtures of some of them), as desired. The microstructure of hot-pressed dense compacts, produced from these powders, revealed that the SiC phase is distributed very homogeneously, even occasionally within Al₂O₃ grains on a nanosize scale. The homogeneous distribution of SiC particles within the system produced high fracture toughness of the hot-pressed material (K_IC∼ 7.0 MPa · m^1/2) and having Vicker's hardness values greater than 2000 kgf/mm².     

Aspects of poly(p-phenylene sulfide) degradation and stabilization. Part 1. Influence of polymer end groups on exposure induced coloration

In this paper we reviewed some of our work on the photo induced coloration of Poly(p-phenylene sulfide) (PPS) and compared it to recent results obtained from the thermal treatment of resins that varied in molecular weight and ionic content. The results from this study suggest that coloration of amorphous PPS films after UV irradiation is caused by products different from those that cause coloration in semicrystalline PPS after thermoxidation. In addition, we found that polymer end group chemistry and resin molecular weights play important roles in the thermoxidative coloration of PPS, but only nominally influence the photooxidative coloration of the resin. PPS coloration may arise from the accumulation of specific, colored products (e.g., phenyl-phenyl moieties) and the possible presence of intermolecular aggregates. The mechanism and extent by which these structures occur in UV irradiated or heated PPS are likely dependent upon the polymer morphology of the samples tested.     

Victim retention for reducing cache misses in tiled chip multiprocessors

This paper presents CMP-VR (Chip-Multiprocessor with Victim Retention), an approach to improve cache performance by reducing the number of off-chip memory accesses. The objective of this approach is to retain the chosen victim cache blocks on the chip for the longest possible time. It may be possible that some sets of the CMPs last level cache (LLC) are heavily used, while certain others are not. In CMP-VR, some number of ways from every set are used as reserved storage. It allows a victim block from a heavily used set to be stored into the reserve space of another set. In this way the load of heavily used sets are distributed among the underused sets. This logically increases the associativity of the heavily used sets without increasing the actual associativity and size of the cache. Experimental evaluation using full-system simulation shows that CMP-VR has less off-chip miss-rate as compared to baseline Tiled CMP. Results are presented for different cache sizes and associativity for CMP-VR and baseline configuration. The best improvements obtained are 45.5% and 14% in terms of miss rate and cycles per instruction (CPI) respectively for a 4 MB, 4-way set associative LLC. Reduction in CPI and miss rate together guarantees performance improvement.     

Preparation of dibasic acid-containing soy phospholipids by chemical and enzyme-catalyzed transesterification and evaluation of their surface-active properties

The preparation of dibasic acid-containing soy phospholipid was made by transesterification reaction with alkyl ester of diabasic acid with both lipase and alkoxide as a catalyst. The extent of incorporation of a dibasic acid varied with the molecular size of the dibasic acid. The extent of incorporation in soy phospholipids was 4–13% in the case of adipic acid and 9–20% in the case of sebacic acid. The surface-active properties of these modified soy phospholipids were examined and were found to be different from those of the original (unmodified) soy phospholipid. The interfacial properties such as critical micelle concentration (CMC), γ_CMC, surface excess concentration Γ_max, and minimum area per molecule (Å), and thermodynamic parameters such as standard free energy of micellization, were found to depend on the hydrophobic part of the dibasic acids.     

The differential effect of polymyxin B1 on guinea pig lung mitochondrial and microsomal glycerophosphate acyltransferase

The activities of guinea pig lung mitochondrial and microsomal glycerophosphate acyltransferase differed in sensitivity to polymyxin B₁. At an antibiotic concentration of 1 mg/ml, the mitochondrial enzyme activity was stimulated twofold, but the microsomal enzyme activity was completely inhibited. Furthermore, the mitochondrial enzyme activity was stimulated by polymyxin B₁ without the addition of exogenous acyl-CoA. Additional experiments ruled out the possibility of polymyxin B₁ acting as a substrate for the mitochondrial acyltransferase. These results suggest either that the polymyxin B₁ sensitivity of mitochondrial and microsomal glycerophosphate acyltransferase is different or that their accessibility to substrates is different because the two isoenzymes are located differently in the different phospholipid microenvironment of the membranes.     

充实自己,把握未来

正告别"一生",迎来"一世"。新旧交替中,中国车市开启了新的篇章。2013年,在"微增长"的预期下,国内汽车产销双双超过2000万辆,再创全球产销最高纪录,国内私家车保有量进一步提升。在汽车后市场被业内人公认为汽车售后利润增长点的情况下,这     

Insecticidal Effects of Organotin(IV) Compounds on Plutella Xylostella (L.) Larvae. II. Inhibitory Potencies Against Acetylcholinesterase and Evidence for Synergism in Tests With Bacillus Thuringiensis(BER.) and Malathion

Features of pesticide synergism and acetylcholinesterase (AChE) inhibition (in vitro) were studied using a selected range of organotin compounds against the early 4th instar larvae of a highly resistant strain of the diamondback moth (DBM), Plutella xylostella, a major universal pest of cruciferous vegetables.Fourteen triorganotin compounds were evaluated for their ability to enhance the toxicity of the microbial insecticide, Bacillus thuringiensis (BT) and of the commercial insecticide, Malathion to Plutella xylostella larvae. Supplemental synergism was observed with triphenyl- and tricyclopentyltin hydroxides in combinations with Bacillus thuringiensis. Increased synergism was observed with an increase in the number of cyclopentyl groups on tin in the mixed series, Cyp(n) Ph(3-n) SnX, where X = OH, and 1-(1,2,4-triazolyl). The combination of (p-chlorophenyl)diphenyltin N,N-dimethyldithiocarbamate at LD(10) and LD(25) concentrations with sublethal concentrations of Malathion as well as of tricyclohexyltin methanesulphonate at the 0.01% (w/v) concentration with Malathion exerted strong synergistic effects (supplemental synergism) with toxicity index (T.I) values of 7.2, 19.8 and 10.1, respectively.Studies on the in vitro inhibition of acetylcholinesterase prepared from the DBM larvae showed that while most of the triorganotin Compounds tested were without effect on the enzyme, compounds containing the thiocarbamylacetate or the dithiocarbamylacetate moieties demonstrated appreciable levels of inhibition, being comparable in efficacy to commercial grades of Malathion and Methomyl.     

Supramolecular π–π assembly of a neutral [Cu(salen)] complex via the templating effect of an ionic inorganic complex Na2[Cu(mnt)2] forming a framework type material having well-defined channels

A classical ionic inorganic complex Na₂[Cu(mnt)₂] (mnt²⁻ = maleonitriledithiolate = 1,2-dicyanoethylenedithiolate), that acts as a template in assembling neutral [Cu(salen)] (salen = bis(salicylidene)ethylenediamine) complexes forming a framework type arrangement, is accommodated in the channel formed in the crystal structure of a new type of host–guest compound [Cu(salen)]₄ · Na₂[Cu(mnt)₂] (1). The non-covalent supramolecular interactions among [Cu(salen)] complexes and between [Cu(salen)] and [Cu(mnt)₂]²⁻ complexes in the crystal lattice of 1 result in weak antiferromagnetic coupling.     

An expressive framework and efficient algorithms for the analysis of collaborative tagging

The rise of Web 2.0 is signaled by sites such as Flickr, del.icio.us, and YouTube, and social tagging is essential to their success. A typical tagging action involves three components, user, item (e.g., photos in Flickr), and tags (i.e., words or phrases). Analyzing how tags are assigned by certain users to certain items has important implications in helping users search for desired information. In this paper, we develop a dual mining framework to explore tagging behavior. This framework is centered around two opposing measures, similarity and diversity, applied to one or more tagging components, and therefore enables a wide range of analysis scenarios such as characterizing similar users tagging diverse items with similar tags or diverse users tagging similar items with diverse tags. By adopting different concrete measures for similarity and diversity in the framework, we show that a wide range of concrete analysis problems can be defined and they are NP-Complete in general. We design four sets of efficient algorithms for solving many of those problems and demonstrate, through comprehensive experiments over real data, that our algorithms significantly out-perform the exact brute-force approach without compromising analysis result quality.