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121.
David Nistr Karin Keis Sten-Eric Lindquist Anders Hagfeldt 《Solar Energy Materials & Solar Cells》2002,73(4)
In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model. 相似文献
122.
The compaction properties of an investigational drug are studied by the use of a compaction simulator. The effects of punch velocity over the range of 30-640 mm-1 on the compaction properties of the pure drug and a variety of formulas incorporating a high dose of the active compound have been investigated. The data were analyzed by applying the Heckel equation. The pure drug was found to have a high yield pressure at a relatively low punch velocity of 31 mm-1. As the punch velocity was increased there was a decrease in crushing strength, primarily as a result of increasing yield pressure. These findings indicate that the pure drug predominantly consolidated by fragmentation and elastic deformation, with a slow plastically deforming component. The information obtained on the consolidation mechanism of the pure drug and, subsequently, on model formulas were instrumental in the design and selection of a robust formula and granulation process. The advantages of conducting dosage form design and characterization studies during the early phase of tablet formulation using means such as a compaction simulator are emphasized in this investigation. 相似文献
123.
Tamal Bose M. -Q. Chen David A. Trautman 《Circuits, Systems, and Signal Processing》1994,13(5):601-614
A special class of complex biquad digital filters called orthogonal filters are investigated for stability under two's complement
quantization. A sufficient condition is derived for the asymptotic stability of the nonlinear filter. Bounds on the possible
limit cycles are also obtained. Using these bounds, any given filter can be tested for stability. The stability triangle is
then scanned using a dense grid, and each point on the grid is tested for stability/limit cycles. By this method, the stability
region given by the sufficient condition is extended. Regions within the linear stability triangle where various types of
limit cycles are possible are also identified. 相似文献
124.
Two empirical judgment phenomena appear to contradict each other. In the revision-of-opinion literature, subjective probability (SP) judgments have been analyzed as a function of objective probability (OP) and generally have been found to be conservative, that is, to represent underconfidence. In the calibration literature, analyses of OP (operationalized as relative frequency correct) as a function of SP have led to the opposite conclusion, that judgment is generally overconfident. Reanalysis of 3 studies shows that both results can be obtained from the same set of data, depending on the method of analysis. The simultaneous effects are then generated and factors influencing them are explored by means of a model that instantiates a very general theory of how SP estimates arise from true judgments perturbed by random error. Theoretical and practical implications of the work are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
125.
126.
Considerable scholarly effort in social psychology is devoted to the development of techniques that change behavior. In this article, the social and political forces that have guided the development of these techniques are examined. Also, ethical and psychological issues associated with the use of behavior technologies are discussed. These issues arise from the fact that to change behavior, it must first be controlled. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
127.
128.
Maha N Hajmeer Imad A Basheer Dean O Cliver 《Journal of the science of food and agriculture》2006,86(14):2337-2344
Reliability analysis is especially important when critical decisions are to be made involving potentially severe adverse consequences such as foodborne illness. Owing to uncertainty associated with the parameters controlling survival of Listeria monocytogenes in chorizo (a Mexican‐style sausage), the time needed to reduce the count by a certain number (n) of logs (tnD) is probabilistic. In this paper the first‐order second‐moment (FOSM) method based on Taylor series expansion is used to derive the expected value and standard deviation of tnD as function of the operating conditions (random variables) affecting survival, namely initial water activity (aw0) of the sausage batter, storage temperature (T) and airflow velocity (F), along with their uncertainties characterised by their means and coefficients of variation. For any given n the derived tnD probability distribution enables one to determine an estimate of tnD for any desired level of reliability or confidence level, such as 50% (median value), 95%, 99%, etc. Among the conclusions drawn were: (i) the variability associated with T and F has a minor effect on estimating uncertainty in tnD, whereas the reliability of tnD estimation is greatly influenced by the uncertainty in aw0; and (ii) the uncertainty in aw0 has the greatest impact when aw0 of the sausage formulation exceeds 0.90. The approach used and discussed in this paper can be applied to any survival/inactivation study to incorporate the effect of uncertainty in the various extrinsic and intrinsic parameters on the survival kinetics of the pathogen in a food system under evaluation. Copyright © 2006 Society of Chemical Industry 相似文献
129.
DavidKatz TomaszLukasiak RickGentile 《世界电子元器件》2003,(6):27-30
如今的数字信号处理器(DSP)在性能、外围设备集成、功耗和成本方面都具备很多优势,很多系统设计人员希望在原有系统设计中利用DSP获得比传统处理器更好的效益。但其中一个 相似文献
130.
While concerns about the psychological effects of war are not new, only recently has systematic attention been paid to such problems among past and present military personnel. There is increasing recognition that mental health has serious implications for operational performance, retention, and compensation. Although little controlled research exists with this population, preliminary evidence suggests that psychological treatments for posttraumatic stress disorder may be beneficial, albeit less so than for civilian populations. This article reviews evidence for each of several psychological treatment stages: stabilization and engagement, psychoeducation, symptom management, prolonged exposure, cognitive restructuring, and relapse prevention, with particular reference to the clinical issues raised by military personnel. Possible explanations for reduced treatment effects in this population compared with civilians are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献