BashDungeon

We present here the first of a series of video-games designed for teaching fundamentals of computer science to university students. We built the game as an adventure inside a dungeon, which aims at reproducing the topology of a Unix file system. Inside the different rooms, the players can learn how to use several Unix commands, from simple file system actions to complex text manipulations, to complete the quests and win the game. We performed a user test on a class of B.Sc. students at the University of Cagliari. The results show a good acceptance of the game metaphor and its effectiveness in supporting the learning process. We plan to expand this game and to design similar games for teaching object-oriented programming and algorithms and data structures.

     

The current state and future outlook of rescue robotics

Robotic technologies, whether they are remotely operated vehicles, autonomous agents, assistive devices, or novel control interfaces, offer many promising capabilities for deployment in real‐world environments. Postdisaster scenarios are a particularly relevant target for applying such technologies, due to the challenging conditions faced by rescue workers and the possibility to increase their efficacy while decreasing the risks they face. However, field‐deployable technologies for rescue work have requirements for robustness, speed, versatility, and ease of use that may not be matched by the state of the art in robotics research. This paper aims to survey the current state of the art in ground and aerial robots, marine and amphibious systems, and human–robot control interfaces and assess the readiness of these technologies with respect to the needs of first responders and disaster recovery efforts. We have gathered expert opinions from emergency response stakeholders and researchers who conduct field deployments with them to understand these needs, and we present this assessment as a way to guide future research toward technologies that will make an impact in real‐world disaster response and recovery.     

A microservice‐based architecture for (customisable) analyses of Docker images

We introduce Docker Analyser , a microservice‐based tool that permits building customised analysers of Docker images. The architecture of Docker Analyser is designed to crawl Docker images from a remote Docker registry, to analyse each image by running an analysis function, and to store the results into a local database. Users can build their own image analysers by instantiating Docker Analyser with a custom analysis function and by configuring the architecture. More precisely, the steps needed to obtain new analysers are (1) replacing the analysis function used to analyse crawled Docker images, (2) setting the policy for crawling Docker images, and (3) setting the scalability options for obtaining a scalable architecture. In this paper, we also present 2 different use cases, ie, 2 different analysers of Docker images created by instantiating Docker Analyser with 2 different analysis functions and configuration options. The 2 use cases show that Docker Analyser decreases the effort required to obtain new analysers versus building them from scratch.     

Energetic Control of Redox-Active Polymers toward Safe Organic Bioelectronic Materials

Avoiding faradaic side reactions during the operation of electrochemical devices is important to enhance the device stability, to achieve low power consumption, and to prevent the formation of reactive side-products. This is particularly important for bioelectronic devices, which are designed to operate in biological systems. While redox-active materials based on conducting and semiconducting polymers represent an exciting class of materials for bioelectronic devices, they are susceptible to electrochemical side-reactions with molecular oxygen during device operation. Here, electrochemical side reactions with molecular oxygen are shown to occur during organic electrochemical transistor (OECT) operation using high-performance, state-of-the-art OECT materials. Depending on the choice of the active material, such reactions yield hydrogen peroxide (H₂O₂), a reactive side-product, which may be harmful to the local biological environment and may also accelerate device degradation. A design strategy is reported for the development of redox-active organic semiconductors based on donor–acceptor copolymers that prevents the formation of H₂O₂ during device operation. This study elucidates the previously overlooked side-reactions between redox-active conjugated polymers and molecular oxygen in electrochemical devices for bioelectronics, which is critical for the operation of electrolyte-gated devices in application-relevant environments.     

Rheology of cellulose nanofibrils and silver nanowires for the development of screen-printed antibacterial surfaces

Journal of Materials Science - TEMPO (2,2,6,6-tetramethylpiperidine-N-oxyl)-oxidized cellulose nanofibrils (T-CNF) and silver nanowires (Ag NWs) were formulated as active inks. Their rheological...     

Stoichiometric Engineering of Chalcogenide Semiconductor Alloys for Nanophotonic Applications

A variety of alternative plasmonic and dielectric material platforms—among them nitrides, semiconductors, and conductive oxides—have come to prominence in recent years as means to address the shortcomings of noble metals (including Joule losses, cost, and passive character) in certain nanophotonic and optical‐frequency metamaterial applications. Here, it is shown that chalcogenide semiconductor alloys offer a uniquely broad pallet of optical properties, complementary to those of existing material platforms, which can be controlled by stoichiometric design. Using combinatorial high‐throughput techniques, the extraordinary epsilon‐near‐zero, plasmonic, and low/high‐index characteristics of Bi:Sb:Te alloys are explored. Depending upon composition they can, for example, have plasmonic figures of merit higher than conductive oxides and nitrides across the entire UV–NIR range, and higher than gold below 550 nm; present dielectric figures of merit better than conductive oxides at near‐infrared telecommunications wavelengths; and exhibit record‐breaking refractive indices as low as 0.7 and as high as 11.5.     

Ratiometric Nanothermometer Based on a Radical Excimer for In Vivo Sensing (Small 32/2023)

Ratiometric fluorescent nanothermometers with near-infrared emission play an important role in in vivo sensing since they can be used as intracellular thermal sensing probes with high spatial resolution and high sensitivity, to investigate cellular functions of interest in diagnosis and therapy, where current approaches are not effective. Herein, the temperature-dependent fluorescence of organic nanoparticles is designed, synthesized, and studied based on the dual emission, generated by monomer and excimer species, of the tris(2,4,6-trichlorophenyl)methyl radical (TTM) doping organic nanoparticles (TTMd-ONPs), made of optically neutral tris(2,4,6-trichlorophenyl)methane (TTM-αH), acting as a matrix. The excimer emission intensity of TTMd-ONPs decreases with increasing temperatures whereas the monomer emission is almost independent and can be used as an internal reference. TTMd-ONPs show a great temperature sensitivity (3.4% K⁻¹ at 328 K) and a wide temperature response at ambient conditions with excellent reversibility and high colloidal stability. In addition, TTMd-ONPs are not cytotoxic and their ratiometric outputs are unaffected by changes in the environment. Individual TTMd-ONPs are able to sense temperature changes at the nano-microscale. In vivo thermometry experiments in Caenorhabditis elegans (C. elegans) worms show that TTMd-ONPs can locally monitor internal body temperature changes with spatio-temporal resolution and high sensitivity, offering multiple applications in the biological nanothermometry field.