Synthesis and characterization of La2Ti2O7 employed for photocatalytic degradation of reactive red 22 dyestuff in aqueous solution

Perovskite structured La₂Ti₂O₇ catalyst prepared by polymerized complex method was characterized and examined the photocatalytic activity by decomposing an azo dyestuff, Reactive Red 22, in aqueous solutions under UV irradiation. La₂Ti₂O₇ powders prepared by polymerized complex method exhibit higher surface areas, better homogeneity and are more sensitive to solution than those prepared by solid-state method. The first derivatives of UV–vis DRS patterns confirmed the complete crystallization of La₂Ti₂O₇ sintered at temperatures higher than 900 °C. The effects of sintering temperature of catalyst and solution pH of photocatalytic reaction were studied. The photocatalytic decomposition of Reactive Red 22 per unit surface area was found to be higher for experiments using La₂Ti₂O₇ than using TiO₂. However, the electron–hole recombination was found to be more obvious for La₂Ti₂O₇ than for TiO₂ because the network of metal cations constructed within La₂Ti₂O₇ enhances the mobility of photogenerated electrons and holes.     

Study on Microstructure and Mechanical Properties of Hot Rolled Low Silicon Containing Phosphorus TRIP Steel

The effects of final air cooling temperature on the microstructure and mechanical properties of hot rolled 0.2C-1.9Mn-0.5Si-0.08P TRIP steel were studied by utilizing OM, SEM, TEM and tensile tests. Experimental results showed that in the multiphase microstructure of the investigated steel when the finish rolling temperature was about 820 ℃ and the final air cooling temperature was in the range of 630-700 ℃, the grain size of most of ferrite was finer (about 4 μm) and which had higher dislocation density, t...     

Progress in Thermal Contact Resistance

The developments of aeronautics and astronautics require engines of higher quality. The temperature distribution in combustion engine is highly influenced by the thermal conduct resistance. To predict the temperature field of the hot-end assemblies of combustion engine, the thermal contact resistance must be considered. The object of the study is to propose a model of high application including in conditions of high temperature and high pressure. Up to date, many models and empirical or semi-empirical corre...     

离子交换纤维微观形貌特点及结构修饰研究

利用比表面积测试仪、扫描电子显微镜等物理化学方法对颗粒与纤维状离子交换剂的链间交联与微观形貌进行了研究,通过刚性交联剂对聚丙烯-苯乙烯-二乙烯基苯(PP-ST-DVB)离子交换纤维骨架结构进行了修饰改造。结果表明:离子交换纤维由于不能通过交联剂与致孔剂参与下的单体聚合构建具有丰富微孔的高分子骨架,所以不存在丰富孔结构和高比表面积特征,其内部为连续凝胶相结构;外比表面积大、传质距离短、交联键分布均匀是其反应动力学和渗透压稳定性能优异的主要原因;刚性交联剂在PP-ST-DVB纤维上的附加交联反应使其比表面积从原来的0.5 m~2/g提高到200 m~2/g以上,附加交联反应所形成的分子尺度微孔孔径分布窄,具有超高交联树脂的结构特点。     

300 MW机组直接空冷系统凝结水过冷却分析

以包头市第二热电厂300 MW直接空冷系统为例,分析了凝结水过冷却的原因,主要有凝结水回水被外界空气冷却、真空严密性差以及补充水溶氧和补水方式的影响等,提出加装保温、雾化喷嘴和改进补水方式等减小冷却度的措施.     

水泥电杆参数的估算

介绍了架空线路水泥电杆运行参数的估算口诀。分析了估算口诀、估算公式的来源和物理意义。指出了从电气理论和现场条件约束的角度对口诀加以归纳和总结,将实践经验与理论知识有机结合,有利于普及电工口诀的应用;在供配电作业现场进行水泥电杆的安装、运行和维护工作中运用电工口诀可以达到提高工效的目的。     

分相无功补偿装置的研制

为了改善电能质量,研制了一种新型无功补偿装置(SVC),对三相不对称负载的无功功率进行分相补偿,使得电网的无功功率得到大致的平衡。该装置的控制器使用新型ATmega16单片机进行控制,运用了傅里叶快速分解和瞬时无功功率理论[1],采用晶闸管作为开关,循环投切电力电容器组,实现无功补偿,本文对该型无功补偿装置的软硬件基本原理进行了介绍。通过样机运行表明,该装置控制准确灵活、补偿方式安全、效果明显,具有较大的社会效益与经济效益。     

光折变晶体全息存储的图像灰度保真度

提出了用归一化灰度线性度误差来评价体全息再现图像的灰度保真度,并在此基础上实验研究了光折变晶体中全息存储的灰度保真度与记录物参光强比的关系,结果与理论预期符合得很好;研究了全息存储过程灰度线性度误差随记录时间演变,表明只要选择适当的记录物参光强比,即使记录时间较短（衍射效率较低）也能获得较高的灰度保真度。