Solubility parameter estimation and phase inversion modeling of bentonite-doped polymeric membrane systems

Effects of bentonite concentration on morphology and permeation characteristics of bentonite-doped polysulfone membranes were investigated. Solubility sphere for bentonite was constructed to estimate its solubility parameter. Thermodynamic modeling of phase inversion of this system was carried out using Flory–Huggins theory. The trade-off between thermodynamic and kinetic parameters was used to predict the membrane morphology for bentonite concentration varying from 0 to 5 wt %. The porosity of bentonite-doped membranes decreased up to 3 wt % that increased thereafter. Morphological analysis showed dense cross section with finger-like macrovoids at 3 wt % beyond which it changed to honeycomb structure with large circular voids. Permeability of 3 wt % membrane was the lowest (5.6 × 10⁻¹² m/Pa s) with 95% bovine serum albumin rejection. Contact angle of the membranes decreased from 83 to 66° with bentonite addition making the membrane more hydrophilic. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48450.     

Lubrication modes and the IRG transition diagram

The relationship between a Lubrication Mode Diagram (LMD) for concentrated contacts (LCC's) and the ‘IRG transition’ diagram has been studied. In addition, scuffing results, obtained by the IRG (International Research Group) have been analysed, as well as the results of scuffing tests performed by different workers using a two-disc apparatus. It has been found that in Region I of the IRG transition diagram, three sub-regions can be distinguished, representing elastohydrodynamic lubrication, mixed lubrication, and boundary lubrication, respectively. Thus, the IRG transition diagram is not comparable to a ‘lubrication mode diagram’. Furthermore, it has been found that failure of LCC's by scuffing most frequently occurs under conditions of mixed lubrication. Therefore, scuffing criteria based upon the assumption that the load at failure is carried entirely by the micro-contacts are doubtful, and probably wrong.     

Estimation of the effects of an intensive solar intervention in the historical centre of jaén (Spain)

This paper is directed at evaluating the theoretical potential of an intensive solar intervention in the historical centre of the city of Jaén (Spain). Using the outputs of a solar intervention proposal comprising biomass, photovoltaics and solar thermal domestic hot water (DHW) over a 50-building sample (in which those suitable for solar measures have been selected by evaluating each one over a collection of parameters), energy savings, environmental benefits and economic aspects of the envisaged actions are extrapolated over the entire historical centre. A saving of about 70% of conventional source energy annual consumption and a decrease of some 70% and 73% of CO₂ and SO_x annual releases, respectively, could be reached with respect to the present situation. Besides, an amount of conventionally generated electricity equivalent to the yearly photovoltaic-generated electricity would require 131500 m³ of water a year, which is a rather significant feature for a dry climate like that of the city. the unitary cost of energy in the new scenario would be 60.7 pta kWh-¹ for photovoltaics, 329.9 pta m-³ for DHW using solar thermal installations and 4.6 Pta kWh-¹ for biomass heating (1 US$ = 132.7 pta; 1 ECU = 160.9 pta).     

Control of the J-Aggregation Phenomenon by variation of the N-alkyl-substituents

Cyanine dyes ( 1a–d ) with the 5,5′,6,6′-tetrachloro-1,1′-dialkyl-3,3′-di-(3-carboxypropyl)-benzimidocarbocyanine chromophore differing only in the chain length of their alkyl groups in 1,1′-position have been synthesized, spectroscopically characterized, and compared with 5,5′6,6′-tetrachloro-1,1′-diethyl-3,3′-di-(4-sulfobutyl)-benzimidocarbocyanine( TDBC ). In aqueous solution the dyes form J-aggregates which, depending on the alkyl group chain length, exhibit J-bands differing in spectral positions, bandwidth, and in the number of peaks.     

Effect of Temperature and Strain Rate on Dynamic Properties of Low Silicon TRIP Steel

The dynamic tensile test of 0.11C-0.62Si-1.65Mn TRIP steel was carried out at different strain rates and test temperatures. The results show that both temperature and strain rate affect the retained austenite transformation. At high strain rates, the uniform elongation decreases, whereas the total elongation and energy absorption increase. The tensile strength is less strain rate sensitive. With raising test temperature, the tensile strength is reduced and the mechanical properties generally deteriorate, especially at 110℃,However, excellent mechanical properties were obtained at 50℃ and 75℃.     

Structural and Physicochemical Changes of Potato Starch Along Periodate Oxidation

Dialdehyde starches were prepared by oxidation with periodate. The influence of the degree of oxidation of the dialdehyde starch on its microstructural and physicochemical properties such as crystallinity, granular structure, complexing capacity with iodine and lysolecithine and water absorption are discussed. Oxidation appears to cause a gradual decrease of any microstructure, meanwhile water absorption is observed to be maximal at intermediate degrees of oxidation. A structure-swelling relationship has been developed and compared with the washing efficiency during purification.     

生物聚合物的创新应用

描述了生物聚合物的创新应用.探索了两种趋势的原因.首先,最近三年中,原油价格猛涨,各种衍生物的价格也随之上涨,促使人们寻找其他可能的原料.其次,欧洲农业处于重大变革的前夜,环境法律的实施,向世界经济的开放以及补贴的减少,促使农业寻找新的市场.玉米和糖用甜菜可能是未来的出路.     

基于原始套接字的网络安全研究与实现

围绕信息的获取、使用和控制的竞争愈演愈烈,网络安全问题变得日益重要,信息安全成为维护国家安全和社会稳定的一个焦点。如何辨别防御与攻击和增强网络安全已成为网络运营商和技术管理人员、甚至普通网络用户研究的问题。在网络安全方面,利用原始套接字实现网络嗅探可以有效地探测在网络上传输的数据包信息,对这些信息的分析有助于网络安全的维护．