Preparation of rice analogues using extrusion technology

Rice is considered as staple food in many parts of the world. An issue of concern is the breakage of rice kernels in milling processes, and these broken kernels are not generally accepted by consumers. These broken kernels can be mixed with some desired additives to improve their quality and extruded for the preparation of reconstituted rice kernels or rice analogues. Various studies have been conducted for the preparation of the rice analogues in the past few decades, and recently attempts have been made to fortify these analogues with protein, certain vitamins and minerals. The main features such as colour, shape, size, texture, and cooking characteristics and cooking time of these rice‐like grains can be tailored to the requirements of specific applications by modification of the extrusion parameters. Various organisations, such as Wuxi NutriRice Co. (DSM/Buhler) and China National Cereals, Oils and Foodstuffs Corporate (COFCO), Superlative Snacks Inc., Vigui and PATH, have utilised this technique to prepare fortified and reconstituted rice. Studies have shown that it is possible to improve the nutritional quality of rice by fortified rice analogues. This article reviews research results of the many approaches to the formation of fortified rice analogues by extrusion‐based technologies.     

Electrochemical impedance spectroscopic characterization of the oxide film formed over low modulus Ti–35.5Nb–7.3Zr–5.7Ta alloy in phosphate buffer saline at various potentials

Electrochemical impedance spectroscopic characterization of the low modulus Ti–35.5Nb–7.3Zr–5.7Ta alloy has been performed in phosphate buffer saline solution at 37 °C. Measurements were performed at various immersion intervals up to 720 h at OCP and also at various anodic potentials up to 2 V. The alloy exhibits a two time constant impedance response at the OCP and a one-time constant response at anodic potentials in the passive region. The thickness of the oxide film formed has been evaluated and the electrochemical interpretation of the results has been reported. Cyclic potentiodynamic profile of the alloy displays valve metal characteristics and the presence of a wide passive region that extends up to the maximum potential value of 2 V studied.     

Unstructured Polygonal Finite-Volume Solutions of Radiative Heat Transfer in a Complex Axisymmetric Enclosure

Radiative heat transfer in a complex axisymmetric enclosure with participating medium is investigated by using the finite-volume method (FVM). In particular, an implementation of the unstructured polygonal meshes is adopted by connecting each center point of the unstructured triangular meshes rather than joining the centroids of the triangular elements to the midpoints of the corresponding sides to form a polygonal element. Also, typical considerations regarding application of the present polygonal mesh system to axisymmetric radiation are discussed. After a mathematical formulation and corresponding discretization equation for the radiative transfer equation (RTE) are derived, the final discretization equation is introduced with the conventional finite-volume approach by using the directional weights. For validation and comparison, three test examples with complex axisymmetric geometries have been accomplished. The present study shows that not only is the method flexible in treating radiative problems with complex geometries, it is also accurate and efficient for the analysis of axisymmetric radiative heat transfer.     

A ROBUST MART ALGORITHM FOR TOMOGRAPHIC APPLICATIONS

The present work is concerned with the development of a robust reconstruction algorithm for applications involving tomography. In an earlier study it was shown that among the ART family of algorithms, the multiplicative algebraic reconstruction algorithm (MART) was the most appropriate for tomographic reconstruction [1]. In the present work, the MART algorithm has been extended so that (a) its performance is now acceptable over a wider range of relaxation factors, (b) the time requirement for convergence to a solution is lower, and (c) its performance is less sensitive to noise in the projection data. Applications considered for evaluating the proposed algorithms are (1) a circular region with holes, (2) a three-dimensional temperature field in a differentially heated fluid layer, and (3) experimental data recorded in a differentially heated fluid layer using an interferometer. The proposed algorithms are seen to be an improvement over those presently available, for all three examples considered.     

Transistor Paint: Environmentally Stable N‐alkyldithienopyrrole and Bithiazole‐Based Copolymer Thin‐Film Transistors Show Reproducible High Mobilities without Annealing

New solution processable 4‐(2‐hexyldecan)‐4H‐bisthieno[2,3‐d:3′,2′‐b]pyrrole and 4,4′‐dialkyl‐2,2′‐bithiazole‐based copolymers (PBTzDTPs) are synthesized with excellent FET performance. These novel copolymers have considerable potential in printable electronics as they have high charge carrier mobilities, excellent air stability, good solution processibility, and no requirement for post‐deposition thermal annealing, all requirements for this field of application. The thin film transistors fabricated from PBTzDTPs achieve field effect mobilities as high as 0.14 cm² V^?1 s^?1 with current on/off ratios up to 10⁶ without thermal annealing. In addition, the devices exhibit stable performance in air, showing no significant degradation over 60 days. Moreover, the polymers described here provide an excellent example of the systems in which higher mobility performance does not require higher crystalline, long‐range ordered structures. Such a system appears to be particularly promising for rapid fabrication techniques, where kinetic conditions usually prevent the development of long‐range order.     

Study of Temperature Dependence of Electrode–Glass Ceramic Interface Using Impedance Spectroscopy

The electrical behavior of strontium titanate borosilicate glass ceramics (SrO.TiO₂- 2SiO₂.B₂O₃) with additives K₂O, La₂O₃, CoO and Nb₂O₅ was studied by using Impedance Spectroscopy as a function of temperature and composition. An equivalent circuit model having three parallel RC's connected in series with a capacitor C₄ could represent the data well. By comparing the complex modulus plots with simulated ones and looking at the values of the time constants these RC's were attributed to represent crystalline, glassy and glass-crystal interface regions of the glass- ceramic whereas C₄ represented the glass-ceramic sample and contact electrode interface. When the glass ceramic sample contained only SrTiO₃ crystalline phase and the remaining glassy matrix, the interface capacitance showed an Arrhenius type of nature with an activation energy (0.11 ± 0.04) eV and when the glass- ceramic sample contained number of crystalline phases no clear cut trend appeared. These findings are useful in selecting suitable electrodes for applications as well as in deciding upon experimental techniques for measurement of dielectric constants of materials.     

Toward Demystifying the Mohs Hardness Scale

Today, the Mohs scale is used profusely throughout educational systems without any persuasive understanding of the fundamental principles. Why one mineral has a scratch hardness over the next culminating in a scale of 1 (chalk) to 10 (diamond) has no atomistic or structure‐sensitive basis that explains this outcome. With modern computationally based atomistic and multiscale models, there is increasing promise of defining the pressure and rate‐dependent parameters that will allow a fundamental understanding of the Mohs scale. This study principally addresses the combined fracture and plasticity parameters that qualitatively affect fracture at the nanoscale. A physical model wherein the crack tip under a scratch is shielded by dislocations is supported by molecular dynamics (MD) simulations in both ductile aluminum and brittle silicon carbide. Next, this model is applied to nanoindentation data from the literature to produce a ranking of Mohs minerals based on their fundamental properties. As such, what is presented here is a first step to address the flow and fracture parameters ultimately required to provide a figure of merit for scratch hardness and thus the Mohs scale.     

Formulation and validation of a mathematical model for a naturally ventilated greenhouse with shading nets in warm and humid climate of India

A thermal model is developed to investigate the suitability of a simple, inexpensive and naturally ventilated greenhouse with shading nets in warm and humid climatic condition for off-season cultivation of vegetables like okra, cucumber, etc. during winter. These vegetables are generally grown during summer and the rainy season. The study was conducted from November 2011 to February 2012 in OUAT, Bhubaneswar, and Odisha where warm and humid climate usually prevails. Air temperatures inside the greenhouse with shading net were only 1–2°C higher during peak sunny hours and considerably 3–5°C more during night hours compared with ambient air temperatures. Lowering of air temperature during peak sunny hours and increasing during the night due to use of shading nets would become favourable for growing off-season vegetables in naturally ventilated greenhouse. Predicted values of air and plant temperatures were found to be in close agreement with experimental values.